纺织品鞋类培训教材

AngelaHao郝明燕[e-mail]isionSPDDept.第2页共17页RevisionRevisionDateDescriptionAuthorA09-09-01InitialreleaseAngelaHAOThisdocumentcontainsguidanceonsafetyoftextile/garments/footwear.However,usersareremindedthattheinformationinthisdocumentdoesnotconstitutelegaladvice.3SPDDept.第3页共17页AdidasA-01主要内容12AdidasA-01(2009)新版本变更第4页共17页134Testing测试TLVTables限值表General/LiabilitiesandResponsibilities基本责任及义务MaterialRequirements材料要求Certification申明25第一部分A01主要内容Part1MaincontentofAdidasA01第5页共17页基本准则1：按照材料类别管控第6页共17页•限用物質–2類產品型控制•EliminationofPVC•EliminationofChemicalsinCementSystemsorFinishes(e.g.Waxes,PolishesorSpotCleaners)andsolventbasedInksandDyes.(14項)–37項管控物質基本准则2：RSL第7页共17页2.2EliminationofChemicalsinCementSystemsorFinishes(e.g.Waxes,PolishesorSpotCleaners)andsolventbasedInksandDyes•三类助剂–CementSystems粘合剂–Finishes抛光剂–Solventbasedinkanddyes溶剂型油墨&染料•管控物质–14类VOCs•测试要求–辅助工艺过程中使用的各类助剂，单独测试。–如过程中使用到粘合、固化、清洗等工艺，则需分别测试粘合剂、固化剂、清洗剂，不可混合测试。第8页共17页AdidasA-01(2009)_RestrictionSubstanceListAdidasA-01RSL(2009)1-10.heavymetals重金属（10项）11.pHvaluepH值12.PCP五氯苯酚13.ΣTeCP三氯苯酚和TriCP四氯苯酚14o-PP邻苯基苯酚15.PCB多氯联苯16.ΣPesticides杀虫剂（纺织类25种、皮革类18种）17.AZO-amines偶氮芳香胺(24种)18.Ozonedepletingsubstance臭氧层消耗物(109种)19.Formaldehyde甲醛20.Dispersedyesanddyestuffs(A)&(B)分散型染料(10种&17种）21.Chlororganiccarriers氯化有机载体(10种)22-27.Organictincompounds有机锡化合物•MBT、DBT、DOT、TBT、TPhT•Σoftrisubstitutedorganotincompounds28.ΣPhthalates邻苯类（6种）29.Flameretardantproducts阻燃剂（9种）30-31.chloroparaffines氯化石蜡（C10-13、C14-17）32.ΣofNP,OPandNPEO33.NP壬基酚34.PFOS/PFOAanditssalts35-36.BaP、ΣPAHs37.DMF37项第9页共17页AdidasA-01(2009)_RestrictionSubstanceListSymbol○:CertificateSymbol●:Testreport1\8\9\10.heavymetals重金属(4项，砷、铜、镍含量、钴)15.PCB多氯联苯20.Dispersedyesanddyestuffs(B)分散型染料B(17种）21.Chlororganiccarriers氯化有机载体(10种)24.DOT二辛基锡27.Σoftrisubstitutedorganotincompounds三取代有机锡29.Flameretardantproducts阻燃剂（9种）30-31.chloroparaffines氯化石蜡（C10-13、C14-17）33.NP壬基酚2-7.heavymetals重金属（6项，镍释放量)11.pHvaluepH值12.PCP五氯苯酚13.ΣTeCPandTriCP三氯苯酚和四氯苯酚14o-PP邻苯基苯酚16.ΣPesticides杀虫剂（纺织类25种、皮革类18种）17.AZO-amines偶氮芳香胺(24种)18.Ozonedepletingsubstance臭氧层消耗物(109种)19.Formaldehyde甲醛20.Dispersedyesanddyestuffs(A)分散型染料A(10种）22\23\25\26.Organictincompounds有机锡化合物•MBT、DBT、TBT、TPhT28.ΣPhthalates邻苯类（6种）32.ΣofNP,OPandNPEO34.PFOS/PFOAanditssalts（防水功能/设备）35-36.BaP、ΣPAHs37.DMF（防腐功能）13项24项10SPDDept.第10页共17页September1st,2009September1st,2008AdidasGroupPolicyfortheControlandMonitoringofHazardousSubstances.Version07AdidasGroupPolicyfortheControlandMonitoringofHazardousSubstances.Version06第二部分AdidasA01新版本变更Part2ThedevelopmentofAdidasA01September1st,2007AdidasGroupPolicyfortheControlandMonitoringofHazardousSubstances.Version05第11页共17页NO•Remark“511”新增有害物质新增有害物质TLV变更TLV变更•Antimony(循环聚酯10ppm)•Cadmium(total)(50ppm变为40ppm)•Lead(total)(60ppm变为40ppm)•Azo-Amines(30ppm变为20ppm)•FormaldehydeinLeather(100ppm变为20ppm)•NP(新增100ppm)•PFOA(新增1μg/m3)•DOT•DMF•Σoftrisubstitutedorganotincompounds•Deca-BDE•DMFA•ΣPesticides(6项)•TPhT•C14-17Chloroparaffines•BPA•PAHsVersion07(2009)Version07(2009)Version06(2008)Version06(2008)ComparisonofAdidasA-01V07&V06第12页共17页变更1：新增有害物质•有害物质共37项–新增3项•Dioctyltin(DOT)•DMF•Σoftrisubstitutedorganotincompounds•ΣTeCPandTriCP–TLV，0.05/0.5ppm–阻燃剂•阻燃剂中新增Deca-BDEΣTeCPandTriCP13SPDDept.第13页共17页变更2：新增材料类别511•NewMaterialGroup511forappliedsurfacecoatings–“Paintandothersimilarsurface-coatingmaterialsmeansafluid,semi-fluid,orothermaterial,withorwithoutasuspensionoffinelydividedcoloringmatter,whichchangestoasolidfilmwhenathinlayerisappliedtoametal,wood,stone,paper,leather,cloth,plastic,orothersurface.Thistermdoesnotincludeprintinginksorthosematerialswhichactuallybecomeapartofthesubstrate,suchasthepigmentinaplasticarticle,orthosematerialswhichareactuallybondedtothesubstrate,suchasbyelectroplatingorceramicglazing.”–Thismeanse.g.thatifaprintorgraphiccanberemovedbyscrapingwithoutliftinguptheunderlyingsubstrate,theprintorgraphicwouldbeconsideredtobeanappliedsurfacecoating.定义：涂层、覆盖层不包括：印刷油墨及其与基材结合非常牢固的物质，如塑料中的着色剂、电镀层、彩釉等如果印字或图案可以被刮涂分离而不会连带到基材，此类的印字或图案属于表面涂层。14SPDDept.第14页共17页其他变更ModificationsUpdatedmethodsforAs,Sb,Cd,Cr,Pb,Cu,Ni,Co.Updatedpre-treatmentforPb-totalandmaterialgroups400and404now○insteadof●.ΣPesticidesmaterialgroups300and301now○insteadof●ΣTeCPandTriCPinsteadofTriCP;(inreturn:TeCPandTriCPwereremovedfromthegeneralpesticidelistsfortextileandleather)Newpre-treatmentforchloroorganiccarriersFormaldehyde:newmethodforwoodandleatherTestrequiredforBaPandPAHandmaterialgroup300andupdatedMethod.ConditionsforDMFandFormaldehydetobemeasuredincaseofOekoTex100Certificate.Parameterdispersedyesaddedtotextinchapter4.6.1TextchangedforBisphenolA(BPA)Textchangedinchapter4.5TextchangedinChapter1.2ChangedwordinginAppendix1ChangedwordinginAppendix2方法变更请参见PartⅢ15SPDDept.第15页共17页EcoTextileTestingFlammabilityTestingCTIInordertocomplywiththeeverchanginggovernmentregulationsandtheincreasingconsumerdemandsforhighqualityallovertheworld,regulatorytestingisessentialtominimizetheriskandprotecttheinterestofbothmanufacturersandconsumers.CTImakeseveryefforttokeepstepswit