TOC原理及使用

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TOCWilsonYu:GE (TOC)       2/GE/    !GEAI#$%&'.GE3/GE/  324/GE/32  32 ’ !#$ 5/GE/!#$%&'()*+ ,-./0123'( 456  18921006/GE/1892100GE  500GE18791927 1941 1960XIII1972CTX-1992!1998F4147/GE/1998F4142002INNOVA#$%&'(!)*20033.6+,-./02003H1/020042VCT-3456#7)* •4 100 …125•30•20071730•4 100 …125•30•20071730GE  GENBC8/GE/•••  •••••!•!•!•#$%•&'()•*)•+,!•-.•/012   !  #$%&'() *+9/GE/'() *+,-./01234567()*+,-.89:; . (TOC) 10/GE/(TOC)  =?@ABC3@A!DEF@GHC3@IC3@TOC11/GE/IC3@JDEK@LMNOPQRASTUAVWXYZ[\U@8!#$%&'()!*+,-TOC12/GE/       USP(23-30)/EP2.2.44 :]^_`abc13/GE/TOC]^_`abcUSP(23-30)/EP2.2.44JapanP15d/16dChinaP2005d/2010dTOCefagh  / 0123456ijkFlfmnopqrs+tuvwxyz{+tuw|}xa~lf]^€�m‚ƒ„v…USP(23-30)/EP2.2.4414/GE/†‡lf]^ˆ‰Š‹GŒj�…Ž‰G�a�‘’“€ ]^yJDEK]^�”€~•+–—˜™:…   7899:;=8?@AB?!USP(23-30)/EP2.2.4415/GE/!CDE/F4G0HIGABJKLMNOP ./0123456789:;=??@ABCBDEFGHIJKLMUSP(23-30)/EP2.2.4416/GE/NOP)!QRSTUVW4KLMX??ACBDYZF8[\]^_`aGHGHGHuQ!LRSTUVWXYu78999;4=Z[\0F]F]336^Q!L_`a USP(23-30)/EP2.2.4417/GE/78999;4=Z[\0F]F]336^Q!L_`a u_`a 7b;c=ABdefg8999;h=iG)EFjjjG USP(23-30)/EP2.2.4418/GE/  !#$ ]  19/GE/(TOC) TC(%&)IC('(&)TOC(%)(&) 20/GE/TOC(%)(&)TC=IC+TOCTOC=TC-IC*+,+-./0123+-2+-klm13]4n.klm58j]4n+-.014#&5/021/GE/+-.014#&5/03+-&678+-&68 0o0o22/GE/CO29:#;=#?5@A6B# 23/GE/?5@A6B#CDE@A6B#CDE#CDE4#F#pOqr$sZtuvw9:GHIJ/O2+K(Pt)L#MN680-950oC24/GE/NOdxyzNO{|pOqr$sZtuvwtu}!~qf€�‚ƒ„…†‡ˆ‰Š‹ŒSupercriticalfluid--NotagasoraliquidSpecialproperties--Fastreactions:•Nonpolarsoorganicmaterialsdissolve•Rapidtransportofreactantsbecauseoflowviscosity,highdiffusibilityTiReactor375°C3,200psiThickFilmHeaterSupercriticalfluidcriticalpointpressureliquidgassolidSupercriticalfluidcriticalpointpressureliquidgassolidSCWO25/GE/Supercriticalwateroxidation(SCWO)Organic+S2O8-2→CO2+H2O+SO4-2Measuredwithinfrareddetector3,200psiHighpressurevalvesHeatertemperaturetemperatureAdvantagesforInnovOx:1.Rapidoxidationofevenhard-to-oxidizeorganics2.Avoidsbuildupofsaltsorparticulatesinreactor�Ž|PNO��‘STOrganic+S2O8-2→CO2+H2O+SO4-226/GE/�Ž|PNO��‘STNO’“NO Pˆ!7y”•O&P‡ˆ‰Š‹Œ�–y—˜NOH2O+hνννν(185nm)ààààOH.+H.27/GE/™~q™pOq$sš›œ�!7žŸ �USP¡¢!£�–y—˜NOz¤‡¥1F]ll¦�Ž|PNOr‡��§¨w©ª+hν(184nm)→CO2+H2O28/GE/H2O+hν(184nm)→ΟΗ·+H·ΟΗ·+Organics→CO2+H2O!H2O+hνννν(185nm)ààààOH.+H.H2O+hνννν(185nm,TiO2)ààààOH.+H.29/GE/™~qš›œˆ!7žŸ �USP¡¢!£�–y—˜NOz¤‡¥5ll¦�Ž|PNOr‡��§¨w©ªpOq$s S2O82_+(90-130oC)→2SO4_SO4_+H2O→SO42_+OH30/GE/NOdxy™pOq�©ª�!7«¬­®�¡¢!£r¯J°±²O&PŽ|NOr‡��§O³~q´-µ¶·¸¹P H2O+hν(185nm)àOH.+H.S2O82_+hν(185nm)à2SO4_.SO4_.+H2OàSO42_+OH.+H+31/GE/  ¡¢!£!#$%&'()*+,-./   32/GE/  €º33/GE/CO2CO2  !#$%&'()*+,-./0.123434/GE/567#$89:;=?@ABC9 DEF=GH*IJ@KLM&'()*+,-./0.1234NOPQ ;=RSTUV'WX4YZ[\ R]^_ `ab c^_ `defbgSh91iabGEInnovox –LaboratoryTOCAnalyzer•RobustSampleHandling• –Samplesuspension–Sampleagitation–No-CarryoverSampleremoval •:TC,TIC,TOC,NPOC•PatentedSCWO(SuperCriticalWaterOxidation)Technique 35/GE/WaterOxidation)Technique –Completesampleremovalaftereveryrun•NDIRDynamicRangeNDIR–0-1000ppm–100–5000ppm–5000–20000ppm–20000–50000ppm•UnprecedentedSystemUpTime 36/GE/!#$%&'( CO2+H2OH2CO3H++HCO3-»¼ PNO*½¾¿»BÀÁÂÃÄŸÅÆUV37/GE/H3PO3H++H2PO4-HClH++Cl-HNO3H++NO3-H2SO42H++SO42-R-ClR-NR-SR-P%TOC(ppb)TOC(ppb)!#$%&101801,700'$%&104754,650(#$%&102232,130!#$%&'38/GE/(#$%&102232,130$#(%&102482,380'(%&103022,9201,1,1,-'$)&1003,4563,3561,2,3,-'$*&1002,8762,776+,-.1001,2781,178  /0123456789 :;= ? @A4=B!#$39/GE/ CDEFGHIJKL6MKNOP3QRST CAUVWXQR Y Z[\]Q^_`abcdeHfghJCiSTP3GECheckPoint)•Technology•Fluidics40/GE/•AnalysisModes•DataStorage -()41/GE/  jkl1mno'pNlqr9'st&ut& %&#$42/GE/vwx9:;=?@ABC9 DEF=GH*IJ@KMJ@Kyz{|/LJ@Kyzz}/LJ@K~€}/L�‚ƒEF„AJ…†Sy€{‡ˆ‰Š‹KA/LŒ�LOP†S=… TOC*

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