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BRICCBRICC1ccriwpccriwp2008.32008.3llBRICCBRICC21.1.2.2.3.3.4.4.5.5.BRICCBRICC31.1.??CHCH3OHOH32.0432.04????10ml10ml30ml30ml0.05ml/l0.05ml/l?????????(?(V%V%):):5.55.5~~44.044.0BRICCBRICC42.2.??C1C1100100MTBEMTBEBRICCBRICC5MTBE9%medicine8%pesticide6%methylamine5%other25%aceticacid7%formaldehyde30%fuel10%vvvBRICCBRICC6????C7H15CH4O9932MJ/kg42.519.7KJ/MJ856.4KJ/kg293-841116795110CO273.370BRICCBRICC7????BRICCBRICC83.3.??COCO2H22H2CH3OHCH3OH90.8kJ/mol90.8kJ/molCO2+3H2CO2+3H2CH3OH(g)+H2O(g)CH3OH(g)+H2O(g)--49.5kJ/mol49.5kJ/mol????11COCO3H2=CH4+H2O3H2=CH4+H2O2CO+5H2=C2H6+2H2O2CO+5H2=C2H6+2H2O222CO+4H2=C2H5OH2CO+4H2=C2H5OH33CO+H2=HCHOCO+H2=HCHO442CO+4H2=CH3OCH3+H2O2CO+4H2=CH3OCH3+H2O552CH3OH2CH3OHHCOOCH3+2H2HCOOCH3+2H2BRICCBRICC9??BRICCBRICC10uZnO/Cr2O3310-40025-35MPa1966CruCuO/ZnO/Al2O3,210-2905-15MPABRICCBRICC11/MPA/375270335.518.2202.412.4100.65.850.22.5BRICCBRICC12mmCuOZnOAl2O3Cr2O3V2O5MPaICI51-148.7524.08.42--?5.43.65.021027051-245.4124.948.72--?5.43.65.010.021027051-3BASFS3-8535.444.252.68--?555.0220280S3-8670.04.010.0200300LurgiCL10457.1928.631.73-5.04?555.0210270Tops?eLMK-236.037.0-20.0-?4.54.55.015.0210290CHM-15254262856--?555.0210280CHM-238.018.73.822.8-?55.992532250280CNJ20250254-3?555.010.0210280C301?555.0210280BRICCBRICC134.4.BRICCBRICC144.14.1??6060--100kg100kg1kg1kg20207070??202019231923BASFBASFZnZn--CrCr30MPa30MPa300300//??2020606019661966ICIICICuCu--ZnZn--AlAlICIICI??19711971LurgiLurgiCuCu--ZnZn--AlAl--VV——LurgiLurgiBRICCBRICC15???90ICILurgi??--BRICCBRICC164.24.2??303050Mpa50Mpa300300400400??5515MPa15MPa2102102902908080BRICCBRICC17????30MPA10-15MPA5-10MPA340-380270210-260Zn-CrCu-Zn-CrCu-Zn-AlBRICCBRICC181.1.ICIICI2.2.LurgiLurgi--3.3.CasaleCasale4.4.5.5.6.6.7.7.TECTECMRFMRFZZ8.8.9.9.10.10.JJDJJD11.11.GCGCBRICCBRICC19ICIICICasaleCasaleTECTECMRFMRFMGCMGCSPCSPC4.34.3BRICCBRICC20??BRICCBRICC21nICInICI7023152061034BRICCBRICC22BRICCBRICC23ICIICIBRICCBRICC24?ICI???62000t/d30100m312001650ICIICIBRICCBRICC25????BRICCBRICC26????????????BRICCBRICC272.Lurgi2.Lurgi•Lurgi1971•2304MPa5BRICCBRICC28nLurgi504.5455-7nn1500t/dLurgi371460t/aBRICCBRICC29LurgiLurgiBRICCBRICC30LurgiLurgi--MegaMega•LurgiMegaLurgiLurgi•23BRICCBRICC31BRICCBRICC3205010015020025030000,20,40,60,81CatalystHeightTemperatureReactionCoolingGasGasCooledReactorBRICCBRICC3324024525025526026527027528000,20,40,60,81CatalystHeightTemperatureReactionCoolingWaterSteamRaisingReactorBRICCBRICC34Lurgibar5090225260CuZnAlVt/m3.hCO172.5~1BRICCBRICC355000t/dLurgiBRICCBRICC36??BRICCBRICC37BRICCBRICC38??LURGILURGI2005.22005.2MarketShareLurgi27%MGC,Other12%ICI61%1969-19921992-2001Lurgi55%MGC,Other20%ICI17%actuallyLurgi70%MGC,Other13%BRICCBRICC393.Casale3.CasalennCasalennnBRICCBRICC40uuCasaleCasaleTopsfeuuCasale165000t/duBRICCBRICC41CasaleCasale??UUICIICI??30302.8m2.8m8MPA8MPABRICCBRICC42CasaleIMCCasaleIMC??CasaleIMCCasaleIMCICIICILCMLCM??220220--25025055--10MPA10MPACuCu--ZnZn--AlAl--VV??BRICCBRICC43??3.53.5????460t/d460t/d1375t/d1375t/d60607000t/d7000t/dIMCIMC(())CasaleIMCCasaleIMCBRICCBRICC444.TopsfeuTopsfeCasaleuTopsfe3-40.05-0.1MPA1416uTopsfe5000t/d2000/BRICCBRICC45uuBRICCBRICC46uu,mm4700,mm14100,t420,MPa0.05,MJ/h2.61052500t/dMRFBRICCBRICC476.SPCSuperconventer?MGCMHISPC-LURGI?25014%25BRICCBRICC48?SPC75mmLurgi?24?32500/2500t/d2009BRICCBRICC497.Linde7.Linde??LindeLinde19801980??BASFBASFS3S3--858555--15MPa15MPa??????750t/d750t/dBRICCBRICC50JWJWGCGCJJDJJDBRICCBRICC51BRICCBRICC52BRICCBRICC53BRICCBRICC54?Lurgi,?BRICCBRICC55?Lurgi-megaBRICCBRICC56BRICCBRICC57?1/3???38%0.05MPa1.2?UBRICCBRICC58JWJW??2020??13133030(())2020//2020//1515//??6060//??://Ø1800Ø1800??25m25m33C306C3065.3Mpa5.3Mpa7.57.5t/at/aBRICCBRICC60GCGC??2200mm,2200mm,??20052005441515t/at/a1616t/at/a????BRICCBRICC61GCGC??GCGC??????13132800mm2800mm5.0Mpa5.0Mpa2007200711BRICCBRICC62~7kg/L·h0.6=0.92.7MPakg/tCH3OH1000MPa0.15MPa0.3MPa4.74.85.4%6.5BRICCBRICC63JJDJJD????BRICCBRICC64??2800350t2303.2~3.8MPa58m3BRICCBRICC65?;10%~30%.?10~20t/aBRICCBRICC66????????????BRICCBRICC67ICIICIICILCMCasaleLurgiCasaleCasaleIMCTopsoeJWJWGCGCJJDLurgi-MegaSPCMRFBRICCBRICC684.44.4??252535MPA35MPA5515MPA15MPA??ZnZn--CrCr350350420420210210290290260260290290??H2H2--CO2CO2//CO+CO2CO+CO2=2.05=2.05--2.15CO2.15CO??H2H2COCO3.53.566BRICCBRICC69??5000500010000h10000h--11??2020303015152525??50ml/m50ml/m330.1ml/m0.1ml/m33BRICCBRICC704.54.5??H2H2COCOCOCO22????DMEDME5%5%,,BRICCBRICC71GB338GB338——20042004(—)=510(20)g/cm30.7910.7920.7910.793(0101325Pa)(64.60.1)=64.065.50.81.01.5min=503020-=0.010.15-(HCOOH)=0.00150.00300.0050(NH3)=0.00020.00080.00015(CH2O)=0.0020.0050.010=0.0010.0030.005BRICCBRICC72??BRICCBRICC73??0.560.560.6MPa0.6MPa404060604040BRICCBRICC743240t/t122740.6MPat/t1.721.03380VKWh/t8.310.5BRICCBRICC75??????1010ttaa??BRICCBRICC765.5.????BRICCBRICC772001400206151.14357.142002480256179.91435.912003650384135.1519.12004755520132.6652.62005956652130.7782.72006136588693.7979.7BRICCBRICC782008.13100-35003400-35002350-26502007.123200-35503500-36802350-26002007.114000-