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AX300400A,,,AA(BPA),(epoxideresin)(PC)A,PC,A2004BPA40kt,PC,,,,BPA12004A3600kt:1095kt200kt280kt330kt210kt570kt135kt210kt235kt()230ktBPA[1]A,A11A(%)67156251577187702417513751951912441811,PCBPA90%,PCBPA,PCBPAA,BPA73%,PC14%,,PCBPABPAPC[7]1958A,,,,,,,2004,A50kt/a,40kt,20032,2004183kt[2]A3[34]22003A(t)(/t)36126928295209422838695118640937145809811397185111270936895097473069454131100432006,16(2)AX:,1951:(022)868107973A(kt/a)16162525()1010()50,301997226153:1kt/a,35400kt/aPC,,,ABPA,Bayer100kt/aBPA,100kt/a,50kt/aBPA,BPA,PCBPA,80kt/aBPA,,2004350%125kt/aBPA,200672BPA211BPA[5]BPA,BPA,A,:2OH+CH3COCH3H+HOCCH3OHCH3+H2O4,4-BPABPA2,4-BPABPA,,(Trisphe2nol),BPA,,BPAHOCCH3CH3OHCOHH3CCCH3,,,BPA-,(810):1,BPA,BPA,(),,,BPABPA,,BPA,,,212[6]2121172%74%,3,2:1,374046h,A,,2060,A4CHEMICALENGINEERINGDESIGN2006,16(2)21212HClBPA,19701990BPA90%HCl,216%,(011012)MPa6065,95%90,HClBPA,21213BPA,1960,,1970,19903BPA,50%:(mol)=10:1,75,,1h,50%,10%,91%10kt/aBPA,2001BPA213:GEBAYERDOW(Chiyoda)/Lum2musICSO,490,90A,10kt/a,20012003,,16kt/aBPA2002A25kt/a,200311,,199810kt/aBPA,2003,BPA,GEDOW(MCC)ICSO21311(MCC)[1011]MCCA,2001MCC,14-PETBPABPA,3,,(3),(2),(1)BPA,,-1(MCC)A52006,16(2)A,,BPA,-,,BPA,,BPAMCC44MCC(kt/a)ShinNipponBisphenol()951991TaiwanProsperityChemicalCorp1251995()1001998()1002002252003100kt/aMCC,(1),:4PET,4,4-BPA;,2,115,,,,BPA;/(2)BPA,-,:;,;BPA(3),:CleavagereactionScavengerreactionHOCCH3CH3OHOH+HOCCH3CH2HOCCH3CH3OH2,4-BPAisomerP-isoprophenylphenolPIPH4,4-BPA:;,21312(Lummus)/ICSO[8]LummusBPA2:(1)1BPA,,,,(2)(3)(4),,BPA(5)BPA,99186%(wt),1kgBPA0105kgLummus/ICSO,BPA:;;;BPA;;;;6CHEMICALENGINEERINGDESIGN2006,16(2)2/ICSO3/ICSO3/ICSO52021313(Dow)BPA4[14]5/ICSO(kt/a)BlachowniaChemicalWorks101978NanyaPlastics201991101992KesarPetroProductsLtd51992LuckyAdvancedMaterialsInc3072006,16(2)A4BPABPA:(1)BPA(DowexÒ)(2),(3)BPA,,(4)BPA,BPA(5)BPADow/KelloggBPA66Dow/KelloggBPADowUSAFreeport,Texas1972DowEuropeStade,Germany1977DowEuropeStade,Germany1987DowUSAFreeport,Texas1991DowEuropeStade,Germany()1993DowBPAHCl,90BPA,KelloggShellChem2icalGrassrootsBPA120kt,1992DowBPAHCl,8021314GE[13]GE:4,5()5GE1:1070,Amberite-118,50%10%,BPA91%,200mmHg,,,,,BPA,,76,40,BPA(:1:1),,(8CHEMICALENGINEERINGDESIGN2006,16(2)BPA:1:1),130,,1235mmHg316,253,,3840,,,BPA,,BPA,,,200mmHgNaOH,p-iso2prophenylphenol(PIPH)PIPHBPA,,BPABPABPA,BPA019,108kt/a27kt/a10%12%GEUCC,BPA,6080,(4),,,,,,,,,GEBPA200kt/a,BPAPCAlabamaBurkevilleGEBPAPC3[810][1214]31120kt/aBPA7720kt/aBPADowGELummus/ICSO,t/t01860187801865()01879,t/t01267012890127501279,t/t31010142113186(MPHP),m3/t270267320330,kWh/t30036040034634,312BPA[12]:31211,ICSO,A,,,,,MCC4PET,,,MCCBPA31212,,ICSO,;MCC4PET,,,,;,,31213MCC,92006,16(2)A,MCC;IC2SO;GP,;31214,MCC3312154PC,MCCICSO,2,4-BPA,1500ppm(wt)4,,MCC4,PC,HClHCl,Hastelloy(),HCl,,,,,,BPA[6][12]411BPA,,,,,,,,2002BPA4PET,,,115,,,,412BPA,,,,,,,,,,,,,,,1020,,GEDow,BPA,413BPA,,BPABPA,GE,,,10kt/a5[4][1516]BPAA2004BPA50kt,35kt,BPA,,2000A6517kt,200418215kt,2911%01CHEMICALENGINEERINGDESIGN2006,16(2)10,20%,52003,,20kt/a20kt/a20kt/a15kt/a,2004,(510)kt/a,10kt/a,20kt/a;20kt/a40t/a,20kt/a40kt/a,15kt,A,A,,,200472918kt,200020043A,2004A,PC1117%,715%,312%,1315%,PC815%,419%,613%,714%,2004A1484kt,130kt,6%,93%,,200483kt,125kt,PC,A,2005,A,A,A2005100kt/aA;100kt/aA2005A300kt,3,1/3,2007500kt,BPA300ktBPA,,200418215kt,BPA/,,200kt/a/2005,Sunoco/UOP/,,/1700kt/a1000kt/aBPA,BPA,,BPA400kt6[4][1516](1)WTO,BPABPA,,BPA,,(2)BPA,/BPA,PC,PC,BPA,BPAPC/,112006,16(2)APC,BayerPCMakrotol/LP209,,PC,BPA,/,(3)BPA,,,,,,,,,BPA,Lummus,(4)BPA,,BPA(5)BPA,,PC,PC,2009PC27%Peppin&Associats,PC,PC,BPA,,,1A[J]1,2004(11):3621A[J]1,20041318(9)A631A[J]1,2003(9)4A[N]1,200581051A[M]1:,1981:1411886,1A[J]1,2004(7)7HPIConstructionBoxscore[J]1HydrocarbonProcessing,2004June8TheLummus/ICSOProcessforBPAProductionANewGenerationofBPATechnology19929InstituteofHeavyOrganicSysthesisPoland1BisphenolATech2nology,199610ChiyodaCorporation:AdvancedProcessforProductionofBPA1CT-BISAProcess,199611BisphenolA[J]1HydrocarbonProcessing,2003March:80121A[J]1,1998(12):121413BisphenolAandAlkylatedPhenols1PEPReportNo11921988Dec1141996InternationalChemicalIndustryFairBeijing,ChinaM1WKelloggCompany,Houston,USA151[J]1,2001(11):505316[J]1,2003(10):545666(2005-12-31)(40),,,,,,,,11[J]1,2004(12)211[C],2004(8):18018331[J]1,2001(2):5052(2005-11-24)21CHEMICALENGINEERINGDESIGN2006,16(2)ABSTRACTSCurrentSituationandProspectofBisphenolAProductionProcssTechnologyXueZuyuan(TianchenChemicalEngineeringCorporationofChina,Tianjin300400)IntroducethegeneralsituationofbisphenolAproduction.Evaluateandcomparetheprocesstechlologycharacteristicsamongseveralcompanies.Prospectthedomesticmarketdemandandgivesomesu2perficialviewsoftheBPAdevelopmentinChina.KeywordsbisphenolApolycarbonateadditionalphenolacetoneexpoxyresinSimulationCalculationandAnalysisofMethanolDistillationProcessTangJinwen(LanzhouPetrochemicalEngineeringCorporation,Lanzhou730060)ByusingchemicalsimulationsoftwarePRO/,maketheprocesssimulationcalculation,analysisandcomparisonfortwodifferentpro2cessesofbi-towerandtri-towermethanoldistillation.Keywordsmethanoldistillationsimu