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27220102FINECHEMICALSVol.27,No.2Feb.2010:2009-07-14;:2009-09-10:(1954-),,,,:0311-886321638666818913032615198,E-mail:Happyyangfuting@163.com[]20098262888,1,2(1.,050018;2.,100011):,,,,,,,,,18:;;;;;:TQ423:A:1003-5214(2010)02-0105-08SurfactantsandCleanerProductioninPaperIndustryYANGFu2ting1,WANGDa2quan2(1.CollegeofBiologicalScienceandEngineering,HebeiUniversityofScienceandTechnology,Shijiazhuang050018,Hebei,China;2.DepartmentalCommitteeofFineChemicalIndustryunderCIESC,Beijing100011,China)Abstract:Accordingtothecharacteristicsofpulpandpapermakingtechnics,thesurfactantsusedinpulpandpapermakingindustrywereintroducedindetail.Theeffectandthemechanismofthesurfactantsusedatpulpandpapermakingtechnologywerediscussed.Finally,thedevelopmentofthesurfactantsinpulpandpapermakingindustrywasputforward.Lignin,asthesecondabundantnaturalpolymer,hasmanylimitswhenitisappliedbecauseofitscomplexstructure.Accordingtoworldwideliterature,thenovelchemicalmodificationofligninsuchastheaminating,epoxy,phenolicandmethyloletcmodificationmethodswereintroducedinthispaper.Theprospectofthemodifiedligninwasalsointroduced.Thestressislaidonmakingastudyingofdifferentmodifiedwaysandappliedeffectsofcationicandanionicligninflocculants.Ligninhasawideapplicationforegroundforitsabundantsourceandfinephysicsandchemistryproperty.Appliedresearchanddevelopmentshoudbeenhanced,whichwillbeimportantinutilizingsourceeffectivelyanddisposingblackliquidsofpapermaking.Cleanproductionandzerodischargewererecommendedasthemostidealtechnology.Meanwhile,theyaretheimportantresearchfieldinthefuture.18referencesarecited.Keywords:surfactants;lignin;pulpmaking;papermaking;flocculant;cleaningproduction4:,();;,,,,,:()(-)(),,,1,,,,,,,,,,20%35%;15%25%[1][2,3],(),()(G)(GS),(),(H)[1],111111.1,,,60%90%;10%20%[2],,,:,,:[4],?:,,,,11112,,,,[4]:(1);(2)-;(3);(4),,,,111131111311,,;,0105%011%(),1%3%,1111312,,0105%011%(),0153112,50,,11211(),;;,,601FINECHEMICALS27,1%3%11212,,,,,LCC(lignincarbohydratecomplex),,48h63%,60%LCC,35%40%(),;,;22,,1121385%,90%LCC,LCC,,,,11214,,1001h73%;160,1401h,90%;1603%(140)20%25%;(165),60%70%;(165),10%15%:3,[5],,,[6],,,,,[6]11215,,,,,214,212[5],,,SiO2,,,1.3,[6]1,,,,,,,,,,EO,,12211,:,,7012,:,1Table1Influenceofsurfactantontheeffectofwheatstrawpulp()/%/%/%Mn/m01111314718131260111132481113167(BX)01111294812131760111133481613179(5)010811274810131510(10)01081126481713169(JFC)010811214818131011(OS-15)010811154811131612(TX-10)010811124915121611(APEC)010811114818121911(3)010811204811131412(T)0108113449111310801061108501911189010611075015121290106110950111211921111()(),,21112,;,;,;,-(11),212,,,21211(),,,,,2%[7](),O2H2O2O2/H2O2O3/H2O2,(pH),(,),(),(),[7]21212,(),72%,,,,,C[7],,,(UA)mol11511157mol,,,,801FINECHEMICALS27,,510[7]2133:,;;,21311,,,,Mannich[8]Mannich,,,,,,,[9]Mannich,,,,1,32[10]21312,,,[11]KOH,19%49%,,()0101011mN/m:,,11,6060h,,Reas85A1g/L40mN/m,CMC01084g/L[7]21313,,,pH=810,40[12]pH=12101215,3d[13],,,OH-,,,,-3,,COD,,,,,,,,,:,,;,,,9012,:,(YPM),(PAC),YPM,pH=58,YPM6085mg/L;PACYPM,pH=715,PACYPM500mg/L6mg/L,CODCr96188mg/L(78138%),3813(86118%)CODCr,311MannichMannich,,,,Mannich,,,50100Mannich,--,,[14],,30120Mannich,,,40100,,,COD312,,[14],,N2(32222),,(),,,313,,,90%(),,314,,;,;,;,,,[15],,,,,ESRX,,,,Amber2biteXAD-4[16]4411:,,,,;,,[17]412,:(1),;(2)();(3),011FINECHEMICALS27;(4);(5),,,[18]1t:35m3,01350180t,7519m3,112118t,17002000kWh1t:20056515m3/t,COD2815kg/t;20047119m3/t,COD3410kg/t;20037410m3/t,COD3515kg/t;200011517m3/t,COD10112kg/t,,,,:;;200771;;;;:():(1)(m3/t):90(),100(),120();(2)CODCr(kg/t):160(),200(),250();(3)BOD(kg/t):45(),60(),75();(4)SS(kg/t):60(),80(),100();(5)AOX(kg/t):115(),215(),310()413,,,,,,:-,90%,;,5,,,,,,,,,,,,,,,,,:[1],,,.[J].,2004,19(1):218-221.[2],.[J].,2007,38():3296-3298.[3],ChenCL,GratzlJS.[J].,2001,16:119-122.[4],,,.[M].:,1992:58-76.[5].[J].,2007,26(12):71-73.[6],,,.[J].,1995,12(S0):21-23.[7].[J].,2003,22(5):47-51.(116)1112,:LiNi015Mn115O463Fig.6ACimpedancesforsamplesatroomtemperatureaftercycling3timesforactivation3(1)LiNi015Mn115O4-xFx(x=0,011)(2)F,LiNi015Mn115O4,LiNi015Mn115O4,Li+,,LiNi015Mn115O4(3)012CLiNi015Mn115O319F01114718mAh/g,80010068%015C210C012C9412%8318%:[1].[J].,1996,26(6):286-290.[2]AmineK,TukamotoH,YasudaH.Anewthree2voltspinelLi1+xMn115Ni015O4forsecondarylithiumbatteries[J].JElectrochemSoc,1997,68:604-608.[3],,,.Li1+xMn2-xO4[J].,2004,14(9):1525-1529.[4],,,.LiNixMn2-xO4[J].,2003,13(1):8l-84.[5]XiaoJ,ZhuHL,ChenZY,etal.PreparationandpropertyofspinelLiMn2O4materialbyco2dopinganti2electricityions[J].TransactionsofNonferrousMetalsSocietyofChina,2006,16:467-472.[6]KosovaNV,UvarovNF,DevyatkinaET.MechanochemicalSynthesisofLiMn2O4cathodematerialforlithiumbatteries[J].SolidStateIonics,2000,135(1/4):107-114.[7],,,.LiMn2O4[J].,2004,35(1):21-24.[8],,,.[J].,2006,47(6):371-374.[9],,,.LiFexMn2-xO4[J].,2008,13(6):36-38.[10],,,.LiMn2O4[J].,2004,28(2):88-96.[11],,,.LiMn2O4[J].,2004,20(8):790-794.[12],,,.MgCdLiMn2O4[J].,2009,28(2):20-22.[13],,,.LiNi015Mn115O4-xFx[J].,2008,24(1):165-170.[14]StrobelP,AnneM,TarasconJM.Characteristicsofthe4VplateauinLiMn2O4-xFxstudiedb