有机化学练习题-完成反应式上

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2019-10-07

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1有机化学练习题（上）（完成反应式）500~600oC()1.CH2CH3Cl2()2.CH3CH=CHCH3NBS,(C6H5COO)2CCl4,+()CH3HBrROOR3.+()C=CCH3HCH3HBr24.()()CH35.CH3CO3HNa2CO3H+,H2O()6.H2C=CHCH2CH2CH=CH2Hg(OAc)2NaBH4H2O()7.CH3CH3HOCl+8.()HCl（）CH3CH=CHCH2CH=CHCCl3Cl29.CH3B2H6H2O2/OH-12()10.冷OH-KMnO411.（）12.COOHCOOH+13.()OOONH+2()14.+CH3CHO（）15.HCH3BrBrCH3CH2CH3Zn()16.CCH3CH3CH2CH2CNa/NH3(l)18.17.()CH2=CHCH2CH2CCH1molH2CH2=CHCCHH21mol()()19.CCH3CH2=CHCHCOHPd/BaSO4喹啉（）20.ClCH3COClOAlCl3()21.+AlCl3()22.+CH3COClNO2AlCl323.()()CH2=CCH=CH2CH3+CH2=CHCHONaBH4()NO2Br2Fe24.+()()25.CH3CH3CH2CH2CClOAlCl3ZnHgHCl()26.CH3CCH3CH3CH2OHZnCl2/HCl()27.ClCH2CH2CH2CH2OHNaOH3()H+28.CH3CH=CHCH2CH2OH()29.CH3ClCH3NaOHC2H5OH()30.CH3BrC6H5OHHHC2H5ONa()31.BrBrKOH/C2H5OH()32.DHNaI丙酮HOCCH2CH3TsCl吡啶()33.CH3BrCDHNaI丙酮34.()+CH3BrCH3CH2CH2CH3CCNaCH3C（）35.HHBrC2H5CH3CH3NaI丙酮36.NO2ClClO2NNaOCH3CH3OH（）OHOHH+37.CH3OH()H2SO438.()39.（）12O3Zn/H2OO4()OHCH3H3CC6H5CH3OHH+Fisher投影式40.()12OHCH3HHH3+OCH3Li41.()42.C2H5CHOCH=CHCH3（）43.H+OHHOO（）44.CH3CH2CH2NH2+OH2/Pt（）45.（）（）CH3CCH(CH3)2OLDATHF,H2O-78C。C6H5CHO（）46.12CH3COHC6H5CHC2H5MgBrH3+O()47.OCF3CO3H（）48.H+H2OOCH3CH3O49.H3+OOO（）CH3CH3C=CHCH2OCH=CH2Ph3P=CHOCH3H3+O()()()50.（）12H3+OCH3LiO51.52.（）O(CH3)2CuLi553.（）H2Ni()54.+CH3CONH2OHH+()55.+CHOC2H5OH/H2ONaOHCH3CH2CC(CH3)3O()CHOKMnO456.57.（）CCH2OHHCCrO3,H2SO4H2O()58.CrO3,H2SO4H2OOHHCH3COCH3,()59.OC6H5OHCHC6H5(C5H5N)2.CrO3CH2Cl2()60.HOCH2CH2CH2CH2CCH3OCH3CH2MgBr+()61.+CH3CCH2CH2CH2COOHOCH3MgBr()62.+CCH2CH2CH2CHOHCMgBr()63.CCH3OCH3CHOHI2,NaOH()64.+ONHCH3SO3H苯，()65.+C6H5CC6H5ONaHSO3()饱和6()66.CHCH3CH3CH=CHOH[(CH3)3CO]3AlCH3COCH3,()67.CH3CCH3OMg/C6H6H2OAl2O32()()68.()CH3CCH3OMgHg/THFTiCl4H3O+ZnHgHCl()110oC()H+69.NOHHH70.()CHOCHONaOH71.OOCH(CH2)5CCH3OOCH(CH2)5CH2CH3O()H+/H2O()72.CHOCHONaOH()H+/H2O()C2H512H2OH2SO4()73.CH3CH2CCH3OCl2(mol)H2O,HOAc+1()74.(CH3)3CCCH3OBr2,NaOH过量()75.2CH3OBr2,NaOHmol()76.+CHOO2NCH3CHONaOH()77.OHOHCH3CCH3OHCl干+()78.+OCNaCH3CH2C()79.CH3CCH(CH3)2OLDATHF,CH3CH2CHOH2O-78()7()80.HI()过量O81.()()(CH3)2CHONa(CH3)2CHOCH3HI浓1mol+()()82.CH3CH3OHBr83.()+CHOOCH=PPh3()84.OHOHCH3COOHH+()OCH3O2NHI1mol85.