-纤维素纳米纤维增强聚合物复合材料研究进展

49820138SCIENTIASILVAESINICAEVol.49No.8Aug．2013doi10．11707/j．1001-7488．201308182012－11－102013－03－06。DL12DB01NCET－10－0313。*。*150040cellulosenanofiberCNF。CNF、CNF、CNFCNF、、、CNF。O636.1A1001－7488201308－0126－06CelluloseNanofiberReinforcedPolymerNanocompositesAShortReviewLiQingChenWenshuaiYuHaipengLiuYixingKeyLaboratoryofBio-BasedMaterialScienceandTechnologyofMinistryofEducationNortheastForestryUniversityHarbin150040AbstractCellulosenanofiberCNFhasrapidlydevelopedinreinforcingpolymertofabricatenanocompositesduetoitsuniqueweb-likestructureandspecialproperties．InthispaperthepreparationandthecharacteristicsofCNFwerebrieflyintroduced．ThentheresearchesonthesurfacechemicalmodificationofCNFincludingsurfacederivatizationsurfacegraftingandadditioncouplingagentwerepresented．ThecharacteristicsofCNFaftermodificationwerealsointroduced．NexttheresearchadvancesofthepolymernanocompositesthatderivedfromPVAPLAepoxyandPFreinforcedwithCNFwerereviewedrespectively．LastthefutureresearchdirectionsofCNFreinforcedpolymernanocompositeswereprospected．KeywordscellulosenanofiberpolymercompositecellulosenanofiberCNFTurbakTurbaketal．1983Herricketal．19831983microfibrillatedcellulose。CNF“Microfibrillatedcellulose”“Nanofibrillatedcellulose”“Cellulosenanofibril”“Cellulosenanofiber”Eichhornetal．2010Habibietal．2010Siróetal．2010Klemmetal．2011Moonetal．2011。CNF2～40nm100～1000cellulosenanowhiskerSamiretal．2005、、、。CNFCNF、。CNF、、、CNF、、、。CNF、CNF。1CNFCNF8Huangetal．2009、、Chenetal．2011a、Leitneretal．2007、Youssefetal．2009CNF。bacterialcellulose、tunicateCNF。CNFCNF。CNF、20102012。refinerPS1CNFS2high-pressurehomogenizerCNFTurbaketal．1983Herricketal．1983。grinderCNFIwamotoetal．2005。Chakraborty20051μm。Henrikssonetal．2007bJanardhnanetal．2006Pkketal．2007。//CNFAbeetal．20072010Chenetal．2011b。。2CNFCNF。CNFCNF。CNFCNF、3。2.1CNFCNF、。CNF。CNFCNFIfukuetal．2007。CNF、CNF。CNF。2.2CNF、CNFCNFCNF、、。Lnnberg2008CNFCNF。Stenstad2008、、、CNF、CNF。CNFCNFCNF。2.3CNF2CNF。CNFCNF。CNF、。Goussé2004、Andresen721492006Lu20082010CNFCNFCNF。Lu2008CNFCNF。3CNF3.1CNFPVA、、PVA、。CNFPVACNFPVA。CNFPVACNFPVACNFPVACNFPVA。Lu2008、Cheng20072009Chakraborty2006CNFPVACNFCNFCNFPVATgTm。CNFPVAChoetal．2011、CNFPVA。3.2CNFPLA、、。PLA、。CNFPLAPLA。YanoIwatakeetal．2008Nakagaitoetal．2009CNFPLAPLACNF。Nakagaito2009CNFPLA。Okubo20052009CNFPLACNFPLA/CNF/PLA。CNFPLAPLA、、、CNF。CNFPLASuryanegaraetal．2009。3.3CNFepoxy、、、、、。CNF。Lu2008aCNFCNFCNF。CNFCNF。CNFCNFCNF。Yano2005CNF。3.4CNFPF、、、。PFPF。8218PF。CNFPF。CNFCNFCNFPF。Nakagaito200420052008a2008bCNF、CNF、CNF、。CNFPFCNF、。PFCNFPF。3.5CNFCNFPVAPLAPF。CNF、、Siróetal．2010。CNFSehaquietal．2010Liuetal．2011、Laaksonenetal．2011、Kettunenetal．2011、Huetal．2013Huangetal．2013、。Hendrickson2007aCNF、。CNFCNF、CNF。、CNF。16.6GPa142MPa。López-Rubio2007CNF。、CNF5℃·min－190℃CNF。CNFCNF。Seydibeyoˇglu2008CNF。CNFCNFCNF。CNFCNF16.5%500%3000%。CNF、。CNF、、、CNFCNFCNFCapadonaetal．2007Moonetal．2011。4CNF。、、CNF。CNFCNF。1、、CNF2、CNF3、、CNF4CNF、CNF、、、、、、、、。92149．2010．．41111320－1326．．2010．．22102060－2070．．2012．．487145－152．AbeKIwamotoSYanoH．2007．Obtainingcellulosenanofiberswithauniformwidthof15nmfromwood．Biomacromolecules8103276－3278．AndresenMJohanssonLSTanemBSetal．2006．Propertiesandcharacterizationofhydrophobizedmicrofibrillatedcellulose．Cellulose136665－677．CapadonaJRVanDenBergOCapadonaLAetal．2007．Aversatileapproachfortheprocessingofpolymernanocompositeswithself-assemblednanofibretemplates．NatureNanotechnology212765－769．ChakrabortyASainMKortschotM．2005．Cellulosemicrofibrilsanovelmethodofpreparationusinghighshearrefiningandcryocrushing．Holzforschung591102－107．ChakrabortyASainMKortschotM．2006．Reinforcingpotentialofwoodpulp-derivedmicrofibresinaPVAmatrix．Holzforschung60153－58．ChenWSYuHPLiuYXetal．2011b．Individualizationofcellulosenanofibersfromwoodusinghigh-intensityultrasonicationcombinedwithchemicalpretreatments．CarbohydratePolymers8341804－1811．ChenWSYuHPLiuYXetal．2011a．Isolationandcharacterizationofcellulosenanofibersfromfourplantcellulosefibersusingachemical-ultrasonicprocess．Cellulose182433－442．ChengQZWangSQRialsTGetal．2007．Physicalandmechanicalpropertiesofpolyvinylalcoholandpolypropylenecompositematerialsreinforcedwithfibrilaggregatesisolatedfromregeneratedcellulosefibers．Cellulose146593－602．ChengQZWangSQRialsTG．2009．Polyvinylalcoholnanocompositesreinforcedwithcellulosefibrilsisolatedbyhighintensityultrasonication．CompositesPartA-AppliedScienceandManufacturing402218－224．ChoJMParkDB．2011．Tensileandthermalpropertiesofnanocellulose-reinforcedpolyvinylalcoholnanocomposites．JournalofIndustrialandEngineeringChemistry17136－40．EichhornSDufresneAArangurenMetal．2010．Reviewcurrentinternationalresearchintocellulosenanofibresandnanocomposites．JournalofMaterialsScience4511－33．GousséCChanzyHCerradaMLetal．2004．Surfacesilylationofcellulosemicrofibrilspreparationandrheologicalproperties．Polymer4551569－1575．HabibiYLuciaLRojasO．2010．Cellulosenanocrystalschemistryself-assemblyandapplicationsChemicalReviews11063479－3500．HenrikssonMBerglundLA．2007a．StructureandpropertiesofcellulosenanocompositefilmsContainingMelamineFormaldehyde．JournalofAppliedPolymerScience10642817－2824．HenrikssonMHenrik