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1515200291ChemicalProductionandTechnology111121.2002372.300072EyringEyringMcAllisterEyringj+k,3jk=1j+k[1]EyringEyringMcAllister1McAllisterMcAllisterEyringEyringEyringMcAllisterMcAllisterMcAllister[2]lnv=,3i=1[xi3ln(viMi)]-ln[,3i=1(xiMi)]+3[xj2xkln(vjkMjk)]6-3i=1xiln(v123M123)(1)lnv=x13ln(v1M1)+x23ln(v2M2)+x33ln(v3M3)-ln(x1M1+x2M2+x3M3)+3x12x2ln(v12M12)+3x22x1ln(v21M21)+x12x3ln(v13M13)+3x32x1ln(v31M31)+3x22x3ln(v23M23)3x3x22ln(v32M32)+6x1x2x3ln[v123(M1+M2+M3)/3]Mjk=(2Mj+Mk)/3,M123=(M1+M2+M3)/3v123=(,3jk=1vjk)/6116v12v21v13v31v23v3232Eyring[3]η=vLhVmexp(Φ/α)2v-L-Avogadroh-Planck++2001-09-21.///////.//.///////.//16UV0Ф1Ф2ART(Ф1+Ф2ξ)V0Ф1Ф2A12Ф1+Ф2ξV0Ф1Ф2ART(Ф1+Ф2ξ)-∂S∂As∂U∂As∂U∂As∂S∂As+①00②1x1molVm,12x2molVm,21molV0=x1Vm,1+1molVm1x1mol+ΔmixUmΔmixUmid+1mol0x1ΔvapUm,111x2ΔvapUm,21ΔvapUm01x1molVm,11molVm2x2mol2x2molVm,2Vm-Φ=PiVm/RTPiRTα=1/1-T(T,P/()T,P2[3]η=vLhVmexp[ΔvapUmαRT]3ΔvapUm-Vm,1Vm,212ΔvapUm,1ΔvapUm,212ΔmixUidmΔmixUmΔvapUm=x1ΔvapUm,1+x2ΔvapUm,2-ΔmixUmΔvapUmαRT=x1ΔvapUm1αRT+x2ΔvapUm2αRT-ΔmixUmαRT(3)lnηVm=x1lnη1Vm,1+x2lnη2Vm,2-ΔmixUmαRT42①12②2①②①2[3]ΔmixUm=ΔU1+ΔU2=+a12(1V0n-1Vmn)(5)Ф1Ф212A12a12ξ3n=(x1Vm,1+x2Vm,2ξ)/Vm54ln(ηVm)=x1ln(η1Vm,1)+x2ln(η2Vm,2)-aRT(1V0n-1Vmn)(6)A=A12/α,a=a12/αVm2VEVm3x1Vm,1+x2Vm,23Vx1m1Vx2m26lnη=x1lnη1+x2lnη2-=x1lnη1+x2lnη2-[Vm1Vm2ARTx1Vm1+x2Vm2ξ]x1x2(12=Vm2ART)12=(Vm,2/Vm,1)ξ-1lnη=x1lnη1+x2lnη2-(12x1x21+)12x277lnη=x1lnη1+x2lnη2+x3lnη3-(12x1x21+)12x2-(23x2x31+)23x3-(13x1x31+)13x38186(12(13(23)12)13)2333Eyring8McAllister16381212Eyring88McAllister184McAllisterEyringEyringMcAllister1717200291ChemicalProductionandTechnology(MV)200192011%20%199620t/a98%97%HClMV1644444444444444444444444444444444444444444444444444444444444444444444444EyringMcAllister341I-ChienWei,RLRowley.Binaryliquidmixtureofvis-cositiesanddensities.JournalofChemicalandEngineeringData,1984,29(3)332～3352RAMcAllister.Theviscosityofliquidmixtures.AIChEJournal,1960,6(3)427～4313.EYRING.,19984I-ChienWei,RLRowley.Binaryliquidmixtureofvis-cositiesanddensities.JournalofChemicalandEngineeringData,1984,29(3)336～3405SKouris,CPanayiotou.Dynamicviscosityofmixturesofbenzene,ethanol,andn-heptaneat298.15K.JournalofChemicalandEngineeringData,1989,34(2)200～2036LSerrano,JASilva,FFarelo.Densitiesandviscositiesofbinaryandternaryliquidsystemscontainingxylenes.JournalofChemicalandEngineeringData,1990,35(3)288～2917MDlzechi,EMarschall.Viscosityofsomebinaryandternaryliquidmixtures.JournalofChemicalandEngineeringData,1982,27(3)358～3638KNoda,MOhashi,KIshida.Viscositiesanddensitiesat298.15Kformixturesofmethanol,acetone,andwater.Jour-nalofChemicalandEngineeringData,1982,27(3)326～328[],1968,1989,//K/%McAllister--29298.152.091.33[4]--24298.152.963.27[5]p--m--o-3298.150.350.58[6]--12298.155.917.00[4]--12298.154.345.62[4]--12298.151.101.19[4]--12298.151.921.82[4]--12298.152.002.47[4]--2-12298.151.161.89[4]--2-12298.153.556.97[4]--2-12298.153.971.21[4]--12298.153.775.83[4]--12298.151.892.49[4]--2-12298.150.936.13[4]--12298.151.301.76[4]--1-24303.150.800.39[7]--23303.152.0212.36[7]-1--24303.153.3010.76[7]-1--24303.153.1723.33[7]--28298.154.9417.04[8]2.575.671