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31212009-5-2612tτ12tτ1.tτ220031222009-5-26ttttu∫∫===LVvdVudltt00ρ0uu=u0vv=τ====00vVuLttAδ1−⋅hkmol∫==VvdVtt0nRTPV=31232009-5-26RTtntVP=vtV=/13−⋅hm13−⋅smFtn=/hkmol/smol/FRTPV=PFRTv/=∫==VFRTPdVtt0AδAAAxynnn000−=δAAAAAxyFFFxytntntn000000)/(//−=−=δAAAAAAxFFxyFFFδδ00000+=+=∫∫+===VVAAAxFFTPdVRvdVtt0000)(1δ∫+==VAAAxFFdVRTPtt0000δ000RTFPv=000RTPvF=∫+==VAAAxyRTPvRTPvPdVRTtt00000001δ∫+=VAAAxyvvdVRTRT0000001δ∫∫+=+==VVAAAAAAxyvdVxFFdVRTPtt0000000)1(δδFFA31242009-5-26⎥⎦⎤⎢⎣⎡=⎥⎥⎥⎦⎤⎢⎢⎢⎣⎡⎥⎥⎥⎦⎤⎢⎢⎢⎣⎡−⎥⎥⎥⎦⎤⎢⎢⎢⎣⎡AdVAdVAdVAd0)()(=−−+−dVrdFFFAAAAdvrdFAA)(−=)1(0AAAxnn−=)1(0AAAxFF−=[]AAAAAdxFxFddF00)1(−=−=dVrdxFAAA)(0−=∫∫−=VxAAAArdxFdV00031252009-5-26∫−==AxAAAArdxvCVFV0000∫−=AxAAArdxC00τ000//1)1(AAAAAAAAAACdCdxCCxxCxC−=⇒−=⇒−=∫∫−=−==AAACCAAAxAAAArdCCrdxCFV000001τ∫∫−−=−==AAACCAAxAAArdCrdxCt000τP68)(Ar−τV)1(0AAxCA−≠AAAAAxynnxynnn000001/−=−=δRTnPV00=31262009-5-26nRTPV=nnVV00=AAAxyVV001/−=δ)1(00AAAxyVVδ+=AAAAAAAAAAAAxyxCxyVxnVnC0000011)1()1(δδ+−⋅=+−==)()(321nbayyyynabdxxf+⋅⋅⋅+++−≈∫⎥⎦⎤⎢⎣⎡+⋅⋅⋅+++++−≈−∫13210)(21)(nnbayyyyyynabdxxf[])(4)(2)(3)(1312_420−+⋅⋅⋅+++⋅⋅⋅++++−≈∫nnnbayyyyyyyynabdxxf31272009-5-26⎥⎥⎥⎦⎤⎢⎢⎢⎣⎡⎥⎥⎥⎦⎤⎢⎢⎢⎣⎡dVdV{}rHdTCFdTCFdlTTUATrTTaTTTPPtPtPtRtmA()()()()()()(000−∆−+−=−∫∑∫∑+DAπ=mT∑TFdVRt)(TTT∫∑∫∑∫∑+−∆−+−−=−dTTTATrPPtPttTtTPPttRPtRtmAdVrHdTCFdTCFdTCFdlTTU)()()()())(()()()(000∑∑=PPttRPtRtCFCF))(()()(∫∑+−∆−+−=−dTTTATrPPtPtmAdVrHdTCFdlTTU)()()()()(031282009-5-26∫∑+−∆−+−=−dTTTATrPPtPtmAdVrHdICFdlTTU)()()()()(0trDxFAAA∆−=∆)(420π[]dlTTUDrHTCFdTCFCFmAATrPPtPtTTPPtTRPtRt)(4)()()()())(()()(200−=⎜⎜⎝⎛−∆−+∆−−∑∫∑∑πdlTTUlDrHTCFmAATrPPtPt)(4)()()()(20−=∆⎟⎟⎠⎞⎜⎜⎝⎛−∆−+∆−∑π……………T)(,,nAnArx−)(,nAr−∆TTm∆−TAnAnAnnxxxTTT∆+=∆+=++,1,1;)(1,1,1+++−nAnAnrxT[]))(211,,21,++−+−=−nAnAnArrr111,+++∆nnnATTxTT)(2112/1+++=nnnTTTT46146,1,10101010−−+−−+=≤−=≤−TnnAnAnATTxxδδT∑∆=+NlLn11)1(NL=31292009-5-26AAAAAPPPkPkdtdP−+=−0225.11min)/(mmHg)322.1331,1840.41(PammHgjcal==PPχA=0.25CTPA000510=220min4.141min588200mmolmmolvA⋅=⋅⎟⎠⎞⎜⎝⎛=∑∑=PAAPPiPiRPiRiCFCFCF0)()()()()/(278.080.3kmolcalTCPA⋅+=l⎟⎠⎞⎜⎝⎛⋅⋅=−kmcallU233.0min59.11Tm=833KFA0min/10036.94.1410902.07854.0)(4112020molvDFA−×=××==πδA=1.0)1(0AAAxFF−=AAAAAAAAxFFFxyFFFxynnn00000000−=−=−=δ0.1),(00==AAyFF)1(0AAxFF−=AAPxFF02=PxxPFFPAAAA⋅+−=⋅=)1()1()=PA0=760mmHg312102009-5-26dtdxxPdtdPAAA⋅+−=2)1(2AAAAAAkPkdtdχχχχχχ4)1)(1(2)1()1(25.015.15.0−++−+=nRTPvnRTPV=⇒=)1(0AAxFF−=RTxFPvAA)1(0−=PRTxFvAA)1(0−=RTFdlDPvdVdtAA)1(4022χπ+⎟⎟⎠⎞⎜⎜⎝⎛==AAAAATkTkdldχχχχχ225.05.11)1(45.21)1()1(1188−++−=∑−−∆−=−dTCFdVrHdlTTUPPiPiATrmA)()()()()(0AAPAmAdxFHHHdTCFdlTTU03210)()(154)(1510)(⎥⎦⎤⎢⎣⎡∆−+∆−+∆−+−=−[]dldTTTlTdldTAχ150.051.20567350278.080.3)833(633.333.0++++−=−χA=0.01·312112009-5-2603QQ=ϕ01301)1(QQQQQϕ+=+=11300AAfAcQcQcQ=+10000)1(AAfAcQcQcQϕϕ+=+)1(00001ϕϕ++=QcQcQcAfAA∫++−−=AfAfAcccAArrdcQVϕϕ100)(ϕ∞0=ϕ∫−−=AfAccAArrdcQV0)(0312122009-5-26