银-铜离子抗菌剂及在ABS中性能研究

18朱伟员周勇冯辉(,,225401)采用水热法制取层状磷酸锆离子交换体,通过控制离子交换顺序交换条件制得含Ag+Cu2+双组份杀菌活性成份的无机抗菌剂,抗菌剂杀菌力达100%防霉等级为0级,应用于ABS中具有较好的加工抗菌力学性能无机抗菌剂银离子交换铜离子交换磷酸锆盐银铜离子抗菌剂及在ABS中性能研究1,;;,2080,2090,,:;Ag+Cu2+Zn2+,Ag+Ag+,ZnOAg+,,,Ag+Cu2+,Cu2+,CuO,ZnO,CuO,,22.12.22B1B3,90e,2~50h,,:NaHZr2(PO4)3#H2O2.3NaHZr2(PO4)3#H2O,,,,80~100e,3h,,2.4,,,60e,4h,,Ag+Cu2+,:Ag0.1Cu0.08Na0.82Zr2(PO4)3#H2O2.5Ag0.1Cu0.08Na0.82Zr2(PO4)3#H2O105e500~1000e2~20h,20016(30)19.ABS33.1(0.8Lm),(0.45Lm),0.3Lm()3.2,,,5M8,Ag+102M83.3,,Ag+(2%)Cu2+(1%)Ag+(3.5%),0.3%,3h,Ag+(2%)Cu2+(1%)99.5%;Ag+(3.5%)92%0.1%,Ag+(2%)Cu2+(1%)85%;Ag+(3.5%)72%3.41%SPVC,GB2423.16-905,J:6,Ag+(2%)Cu2+(1%)0;Ag+(3.5%)23.5Ag+(2%)Cu2+(1%):LD5010000mg/kg;;3.6Ag+(2%)Cu2+(1%)33kg,29kg;Ag+(3.5%)58kg950/kg;24/kg1tAg+(2%)Cu2+(1%)2.34Ag+Cu2+ABS4.1Ag+Cu2+ABSABS,,1201/%/N/(N/cm2)/(kJ/m)/(kJ/m2)101322330580.917.82026j1270333086.718.81831.2%1292325086.517.922.84h8h12h24hA#1.82@1053.63@104(80%)3.24@104(92%)3.65@103(98%)102(99%)B#2.24@1053.55@104(82%)1.54@104(93%)2.03@103(99%)10(99%)C#2.04@1052.42@104(84%)4.55@103(95%)102(99%)10(99%)1.85@1051.64@1051.83@1052.03@1053.23@1052ABS()ŠŠ()1,Ag+Cu2+,4.2Ag+Cu2+ABSN4PLus,Ag+Cu2+A#B#C#,A#D90=1.5Lm,B#D90=0.8Lm,C#D90=0.3LmA#B#C#8jABSSOPSBZ1036-9656,ABS,22,,,,,,,4.3Ag+Cu2+ABSAg+Cu2+3j5j8j1%1.5%ABS,1#2#3#4#5#ABS(3)4h8h12h24h1#2.23@1051.22@105(46%)1.05@105(55%)6.67@104(70%)3.36@104(85%)2#2.04@1051.02@105(55%)6.41@104(68%)3.43@104(83%)1.24@104(94%)3#1.82@1054.92@104(81%)2.05@104(92%)102(99%)102(99%)4#1.86@1053.26@104(82%)1.62@104(94%)102(99%)10(99%)5#2.12@1052.14@104(90%)6.31@103(96%)102(99%)10(99%)1.81@1051.62@1051.42@1052.03@1052.84@105Š()3ABS()Š20016(30)213,,,8j,,Ag+Cu2+,Ag+Cu2+,,,Ag+Cu2+,,,,5,20,20,300,199840t,300,30;1999150t,1200,100;2000200t2005500t,4006Ag+(2%)Cu2+(1%)Ag+,,1黄占杰.材料导报.1999,13(2):352西野敦编著.抗菌剂N科学.Part2,工业调查社.1997:23~453张文征,张羽天.贵金属.1998,19(4):504黄汉生.无机抗菌剂的研究开发及其应用.化工科技动态,1997(10)5化工进展,1990(3):486Kirk-othmer.EncyclopediaofChemicalTechndogy,thirdEd,Vol.21.P922~923(1983)7特开平6-287321994-10-11(上接第15页),,,,,3000t,,,,,,,,WTO,,,,1宁波金海雅宝化工有限公司采购固体粉末造粒机项目国际招标开标评标文件.2001.92宁波市国际招标有限公司.招标公告.2001.73德国卡尔公司投标文件及产品说明书4德国亚历山大公司投标文件及产品说明书5日本细川密克郎公司投标文件及产品说明书6南京粉体研究所产品说明书7常州市合力干燥设备有限公司产品说明书8田稼薇.聚乙烯聚丙烯助剂及复合技术的开发应用,2001.99上海汽巴高桥公司.polyadpreblendspresentation,2001,9(10)10江苏汉光实业股份有限公司.新型塑料复合助剂HGP-103技术塑料11天津市力生化工厂.塑料复合助剂技术及应用研讨会发言提纲.2001,9.ABS