消泡剂的研究现状与展望

Sum156No.9ChemicalEngineer20089:2008-07-27:(1973-),,;,:1002-1124(2008)09-0026-03消泡剂的研究现状与展望王芸,吴飞,曹治平(,210028):,,3:;;;:TQ423.95:APresentstudysituationandprospectofantifoamWANGYun,WUFe,iCAOZhi-ping(NanjingSixinScientific-TechnologicalApplicationResearchInsituteCo.,Ltd.,Nanjing210028,China)Abstract:Kindsofantifoamandbreakingfoammechanismoforganicsiliconeantifoamwereintroduced,andstudyconditionsofthreekindsofantifoams,organicsiliconeantifoam,polyether-antifoamandmineraloil-antifoamwereanalyzed,anddevelopmenttendencyofthreekindsofantifoamwasproposed.Keywords:antifoam;mechanism;presentsituation;forecast,,,,,;,[1],1,,,[2]:;[3],,;,220,80[4],[5],,DenkovND[6],,Bridging-Spreading(-)ArnaudovL[7],,,,DippenaarA[8]Bridging-Dewetting,20089王芸等:消泡剂的研究现状与展望,,,,Bridging-Dewetting,,,Bridging-Spreading,[9],,,Bridging-Dewetting,Bridging-Spreading,,Spreading-FluidEntrainment[10],,3,[11],[12],,,,,44.1,,,,,DenkovND,(EntryBarrier),,,,[13],DenkovND(EntryBarrier),,,[14],,,GoldschmiftAG[15],[16,17]4.2C-O-C,O-HN-H(EO)(PO)(BO)[18]EO,,,,,,,,,,,,27王芸等:消泡剂的研究现状与展望20089,,,[19]4.3,,,,,,,,,,[20]5,,,,3:(1),,;(2);(3);(4),[1],.[M].:,2000.[2].[M].:,2004.[3],,,.[J].,2005,(5):20-23.[4],,.[J].,2007,136(14):23-25.[5]JoshiKS,JeelaniaSAK,BlickenstorferbC,NaegeliI,WindhabEJ.Influenceoffattyalcoholantifoamsuspensionsonfoamstability[J].ColloidsSur.f,A:Physicochem.Eng.Aspects.,2005,263(1-3):239-249.[6]DenkovND.Mechanismsoffoamdestructionbyoil-basedantifoams[J].Langmuir,2004,20(22):9463-9505.[7]ArnaudovL,DenkovND,SurchevaI,DurbutP,BrozeG,MehreteabA.Effectofoilyadditivesonthefoamabilityandfoamstability.1.Roleofinterfacialproperties[J].Langmuir,2001,17(15):6999-7004.[8]DippenaarA.Thedestabilizationoffrothbysolids,I:Themechanismoffilmrupture[J].Int.J.Miner.Process,1982,9(1):1-14.[9]GarrettPR.Preliminaryconsiderationsconcerningthestabilityofaliquidheterogeneityinaplane-parallelliquidfilm[J].J.ColloidInterfaceSc.i,1980,76(2):587-590.[10]RobertA,BernardP,BinksPDI,FletcherTP,PeterRG.Entryandspreadingofalkanedropsattheair/surfactantsolutioninterfaceinrelationtofoamandsoapfilmstability[J].J.Am.Chem.Soc.,1993,89(2):4313-4327.[11],,.CS-500[J].,2007,19(3):35-37.[12]:Q/3201SKY01-2006.[13]MarinovaKG,DenkovND,BranlardP.Optimalhydrophobicityofsilicainmixedoil-silicaantifoams[J].Langmuir.2002,18(9):3399-3403.[14]DenkovND,TcholakovaS,MarinovaKG.Roleofoilspreadingfortheefficiencyofmixedoil-solidantifoams[J].Langmuir,2002,18(15):5810-5817.[15]HeilenW.,KarminskiH.,KeupM.,KlockerO.,etalPolysiloxane-polyoxyethylene-polyoxy-propyleneriblockcopolymersanddefoamingcompoundscontainingthem[P].U.S.:5804099,1998-09-08.[16]FeiWu,ChunCa,iLiangWang,Zhi-pingCao,Wen-binY.iBreakingandinhibitingfoamperformanceofmodifiedsiliconeoilsinoil-basedsystem[J].JournalofDispersionScienceandTechnology,2008,2(5):792-795.[17]FeiWu,ChunCa,iWen-binY,iZhi-pingCao,YunWang.Antifoamingperformanceofpolysiloxanesmodifiedwithfluoroalkylsandpolyethers[J].JournalofAppliedPolymerScience,2008,109(3):1950-1954.[18].[J].,2001,(2):1-6.[19],,.CS-500[J].,2007,19(3):35-37.[20],,,.[J].,2007,46(8):31-33.28