常见有机化学基团英文名及缩写

©2000TobyBroomNopartofthisdocumentmayber[e-mail]meUsesStructuresAcAcetylVerycommonprotectinggroupforalcoholsandphenolsROAdAdamantylProtectinggroupforacids,thiolsandalcoholsRADAsymmetricdihydroxylationOHHONHNOHOOClOsO4+NMO+AEAsymmetricepoxidationSharplessConditionsOHOOHHCO2EtOHEtO2CHOHtBuOOH+Ti(OiPr)4+AIBN?,?'-AzoisobutyronitrileMakesradicalsNCNNCNAldrithiol®2,2'-DipyridyldisulphideThiolatingReagentNSSNAllAllylProtectinggroupforphenols,acidsandalcoholsespeciallycarbohydratesRAllocAllyloxycarbonylProtectinggroupforalcohols,aminesOOR9-BBN9-BorabicyclononaneHinderedreductantBBNBHBMSBorane-methylsulphidecomplexReducingagentBH3SMe2BINAP2,2'-Bis(diphenylphosphino)-1,1'-binapthylLigandforRucatalytichydrogenationandBuchwaldreactionPPh2PPh2BINAPOPhosphinousacid,diphenyl-[1,1'-binapthalene]-2-2'-diylesterLigandforRucatalytichydrogenationOPPh2OPPh2Boctert-ButoxycarbonylProtectinggroupforaminesespeciallypeptidesOORBOMBenzyloxymethylProtectinggroupforalcohols,phenols,acidsandaminesORBOPBenzotriazol-1-yloxytris(dimethylamino)phosphoniumhexafluorophospatePeptidecouplingreagentNNNPNNNPF6©2000TobyBroomNopartofthisdocumentmayber[e-mail]-ClBis(2-oxo-3-oxazolidinyl)phosphinicchloridePeptidecouplingreagentONPNClOOOOBnBenzylProtectinggroupforalcohols,phenols,acids,amides,aminesandcarbonylsRBrBrosylate,BromobenzenesulphonylActivatinggroupforalcoholsBrSOORBTAFBenzyltrimethylammoniumfluorideFluoratingreagentNFBumt-butoxymethylProtectinggroupforamines,alcoholsORBzBenzoylProtectinggroupforthiols,alcohols,phenolsmuchmorestablethanacetateORBHTtert-ButylhydroxytolueneStablizerforethersOHCANCericammoniumnitrateOxidisingagent(NH4)2[Ce(NO2)6]CBSCorey-Bashki-ShibatChiralreducingagentforcarbonylsNOBPhPhHBH3+CbzorZBenzyloxycarbonylVerycommonprotectinggroupforaminesespeciallyinaminoacidsOROCODCyclooctadieneLigandfortransitionmetalcatalystsandusedtomake9-BBNCpCyclopentadienylAsit’sanionaligandfortransitionmetalsandacommonDiels-AlderDienemCPBAmeta-chloroperoxybenzoicacidOxidisingagentusedformakingepoxidesandBaeyer-VilligerreactionOOOHCl18-Crown-6(18C6)1,4,7,10,13,16-hexaoxocyclooctadecanePhasetransfercatalystOOOOOOCSACamphorsulphonicacidChiralresolvingagentOHO3SH2CCysCystineAminoacidNH2OOHHS©2000TobyBroomNopartofthisdocumentmayber[e-mail]™1,4-Diazabicyclo[2.2.2]octaneStronghinderedbaseNNDASTDiethylaminosuphurtrifluorideFluorinatingagentNSFFFdbaDibenzylideneacetoneZ,Z-1,5-diphenyl-1,4-pentadien-3-oneLigandforpalladiumODBN1,5-Diazabicycolo[4.3.0]non-5-eneStronghinderedbaseNNDBU1,8-Diazabicyclo[5.4.0]undec-7-eneStronghinderedbaseNNDCC1,3-DicyclohexylcarbodiimidePeptidecouplingreagentNCNDDQ2,3-Dichloro-5,6-dicyano-1,4-benzoquinoneOxidantOOClClCNCNDEADDiethylazodicarboxylateReagentusedinMitsunobuReaction(inversionofalcohols)NONODHPDihydropyranThereagentusedtomakeTHPprotectedalcohols,acidsandphenols.ODHQDDihydroquinidineChiralligandNHNOHHODIADDiisopropylazodicarboxylateReagentusedinMitsunobuReaction(inversionofalcohols)NNOODIBALDIBAL-HDiisobutylaluminiumhydrideReducingagentfortheselectivereductionofestertoaldehydesAlHDICDiisopropylcardodiimidePeptidecouplingreagentCNNDIPEADIEADiisopropylethylamineProtonsponge,baseNDMDDimethyldioxoraneUsedformakingepoxidesOODMAP4-DimethylaminopyridineWeakbaseNNDMEDimethoxyethaneSolventOODMFN,N-DimethylformamideSolventON©2000TobyBroomNopartofthisdocumentmayber[e-mail]-MartinperiodateFromIodobenzoicacidheatwithAcOHthenAcO2MildoxidizingagentforalcoholstoaldehydesIOOAcOOAcOAcDMPM3,4-DimethoxybenzylProtectinggroupforalcohols(canberemovedinpresenceofMPMselectively)ROODMPU1,3-Dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinoneNoncarcinogenicreplacementforHMPANNODMSDimethylsulphideUsedforquenchingOzonolysisandligandforBH3SDMSODimethylsulphoxideSolventandoxidantSODPPADiphenylphosphorylazideOrganicSourceofAzideOPOONNNEDCI1-ethyl-3-[3-(dimethylamino)propyl]carbodiimideReagentusedinMitsunobuReaction(inversionofalcohols)CNNNEDTAEthylenediamminetetraaceticacidChelatingagentformetalions.NNOOHOHOHOOOOHEE1-EthoxyethylProtectinggroupforaminesandalcoholsORFDPPPentafluorophenyldiphenylphosphinatePeptidecouplingreagentPOPhPhFFFFFFmoc9-FluorenylmethoxycarbonylProtectinggroupforamines,alcoholsandacids(verystabletoacids)OORHATUO-(7-azabenzotrizol-1-yl)-1,1,3,3,tetramethyluroniumhexafluorophosphateN-[(dimethylamino)-1H-1,2,3-triazol[4,5-b]pyridiylmethylene]-N-methylmethanaminiumhexafluorophosphateN-oxidePeptidecouplingagentNNNNNNOPF6HMPAHexamethylphosphoramdeCo-solventOPNNNHMPTHexamethylphoroustriamideCo-solventPNNN©2000TobyBroomNopartofthisdocumentmayber[e-mail]1-hydroxbenzotriazolePeptidecouplingagentNNNOHImImidazoleBaseusedinsilylationsNNHIpcIsopinocampheylC