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第34卷第3期当代化工Vol.34,No.32005年6月ContemporaryChemicalIndustryJune,2005丁诗宏,王斌(,113008):,(517#),,:;;:TQ423.11+6:A:16710460(2005)03016503,,,,,,11.1(1)C8~C10,:;C6:0~5%,C8:45%~66%,C10:35%~55%,C12:0%~5%;(2),,w(P2O5)98%;(3)(C6H6);(4)(H2O2),w(H2O2)30.0%1.2C8~C10500mL,,,,40,,,,,(),(),1.3:PIC-203022.1,,,,,,11:2005-04-26:2005-05-18:丁诗宏(1963-),工程师,男,1989年毕业于辽阳石油化工专科学校有机化工专业,现为抚顺洗化厂空分车间工程师1Table1Relationshipbetweenthetotalacidityandthedosingration()n(P2O5)/(mgKOHg-1)1.942372.432102.52022.61952.661922.711882.7318631791/P2O5Fig.1Relationshipbetweenthetotalacidityandthemassra-tiooffattyalcoholtoP2O51,,2.5~2.73,202~186mgKOH/g,(185~205mgKOH/g)2.2,,40,,40~50,50~60,60~70,80,100,,50~6522,,:POROOHOH+PO2ROOHOPOOHOR2Table2Effectofreactiontemperatureontheamountofmonoesteranddiester//(meqg-1)/(meqg-1)52.51.7791.44457.51.8841.30162.51.9081.242Fig.2Effectofreactiontemperatureontheamountofmo-noesteranddiester:1;2,,,2.3,3Table3Effectofreactiontimeontheamountofmonoesteranddiester/hm()/(mmolg-1)m()/(mmolg-1)3.51.7501.4184.01.8211.3694.51.8491.3013Fig.3Effectofreactiontimeontheamountofmonoesteranddiester166当代化工第34卷第3期:1;23,(),,,2.42.1-2.3,,,,L9(33),44Table4TheresultsoforthogonaltestA/B/hCR-/PY1/%Y2mmol/gY3mmol/g15332.662.241.6411.51425342.701.451.6801.55235352.731.501.7611.45445832.702.751.7251.57555842.731.981.7981.35165852.661.701.8471.37076332.732.501.8121.30086342.663.061.6411.42896352.701.911.9961.230K15.197.497.00K26.436.496.11K37.475.115.982.282.381.02,:BAC,,,,2.5(1),,,5h,5h(2),,,:1.70~2.0mmol/g;1.45~1.75mmol/g(532)(3),,,,,:n()n()=2.73(4),:5h;53;n()n()=2.73:189mgKOH/g,1.17%,1.78mmol/g,1.55mmol/g,2.6,55Table5Theresultsofstabilitytest/(mgKOHg-1)/%/(mmolg-1)/(mmolg-1)/%1890.721.781.521522160.021891.501.721.621402050.331861.301.711.481452060.021911.451.781.551502090.18,,,2.7(1)R-,,;(2),;,,;(3)50~55,,2030min,,,,(4),,,2min51672005年6月丁诗宏,等:磷酸酯的合成研究40min(5),,,,3(1),,;(2);(3),,;(4),[1].[J].,1991,(4):1-6[2].[J].,1991,(3):1-7[3].[J].,1993,(1):12-16[4].[J].,1992,(9):27-29[5].[J].,1995,(1):8-9[6]U.S.P3,428,481[7]U.S.P4,072,607[8]U.S.P3,235,506[9]U.S.P3,502,587[10],.[M].:,1996ReseachonthePhosphateEsterCompositionDINGShi-hong(PetroChinaFushunPetrochemicalCompanyDetergentChemicalPlant,Fushun113008,China)Abstract:Thepaperintroducesthefunctionsofphosphatesurfactantandthecompositetestonthephosphateoila-gent.Thetestshowsthattheproducthasasoundantistaticcharacteristicandgoodcompatibilitywithotheroila-gents.Keywords:phosphateester;surfactant;composition(上接第161页)(),2000,24(3):50-53[2]GuoShaohuietal.CS2/NMPextractionofimmaturesourcerockconcentrates[J].OrganicGeochemistry,2000,31(12):1783-1796[3]IinoM.,etal.ExtractionofcoalswithCS2-N-methyl-2-pyrrolidinonemixedsolventatroomtemperature[J].Effectofcoalrankandsynergismofthemixedsolvent,1988,67:1639-1647Physical-chemicalStructuralEvolutionofFanZhiBrownCoalDuringHydrorousPyrolysisLINLian1,GUOShao-hui2(1.FushunResearchInstituteofPetroleumandPetrochemicals,Fushun113000,China;2.ChinaUniversityofPetroleum-Beijing,Biejing102294,China)Abstract:Non-chemicalbondassociationstructuresinFanzhibrowncoalandtheirevolutionwerestudiedbytheintegrationofhydrouspyrolysisandCS2/NMPextraction.Abundantnon-chemicalbondassociationinteractionsareexistedinFanzhibrowncoalandtheassociationinteractionswillchangeinthethermalevolution.Suchassocia-tioninteractionshaveagreatimpactontheearlyevolutionoftheorganicmatterandimmatureoilformation.Keywords:browncoal;physical-chemicalstructure;hydrouspyrolysis;evolution168当代化工第34卷第3期