清洁汽柴油加氢工程技术及进展

201020101010212121.1.2.2.3.3.4.4.5.5.6.6.7.7.8.8.3194919491950195019591959196319631.1.419691969(())197719771984198421211.1.521212l2l1.1.62121FeFeVVNiNi1.1.72121l992l992““2l2l””1.1.821212l2l1.1.91.1.101.1.111.1.12999999991.1.13202020204.34.32.02.020202020221.1.14202020205050PXPX780078001.1.15RFCCRFCC1.1.16VGOVGOLCOLCOLCGOLCGO1.1.17VGOVGOLCOLCORDS/RFCCRDS/RFCC1.1.18HydrotreatingHydrotreating10%10%10%10%HydroCrackingHydroCracking10%10%2.2.19VGOVGO(())2.2.20————2.2.21„„„„„„FCCFCC„„SS--ZORPZORP„„„„„„„„„„„„3.3.22FCCFCCnn--PPii--PPNNOOAA3.3.23FCCFCCC5~120C5~12060%60%15%15%120~175120~17525%25%25%25%175~220175~22015%15%60%60%3.3.24FCCFCCFCC3.3.25FCCFCCSCANfiningSCANfiningPrimeGPrimeG(+)(+)CDHDSCDHDSFCCNFCCNRSDSRSDSOCTOCT--MMFCCNFCCN3.3.26FCCFCC----SCANFingSCANFingFCC9295(R+M)/21~1.53.3.27FCCFCC----PrimePrime--G/GG/GHDSHDSFCCFCC95951001003.3.28FCCFCC----PrimePrime--G/GG/G3.3.HCNHCNDesulfurizedDesulfurizedHeavyFCCcutHeavyFCCcutSSpplliitttteerrSelectiveSelectivehydrogenationhydrogenationFCCgasolineFCCgasolineSelectiveHDSSelectiveHDSUnit(PrimeG+)Unit(PrimeG+)LCNlightFCCcutLCNlightFCCcut29FCCFCC----PrimePrime--G/GG/G0.21w%0.21w%Mo/Ni/CoMo/Ni/Co66LCNLCNOATSOATSRONRON1.51.53.3.30FCCFCC----CDHYDRO/CDHDSCDHYDRO/CDHDSCDtechCDtechCDhydroCDhydro/CDHDS/CDHDSCriterionCriterion(CD(CD--module)module)CDHYDROCDHYDROCDHDSCDHDS3.3.31FCCFCC----CDHYDRO/CDHDSCDHYDRO/CDHDSCDHydroCDHydroCDHydroCDHydroLCNLCNHCNHCNCDHDSCDHDSCDHDSCDHDSCDHDSCDHDSCDhydroCDhydroCDhydroCDhydroLCNLCNCDHDSCDHDSHCNHCNH2SH2SPolishPolish1010g/gg/g3.3.323.3.FCCFCC----CDHYDRO/CDHDSCDHYDRO/CDHDS33FCCFCC----CDHYDRO/CDHDSCDHYDRO/CDHDS¾¾¾¾RONRON0.90.9¾¾0.15w%0.15w%¾¾(99.73w%)(99.73w%)¾¾¾¾¾¾CDCD--hydro/CDHDShydro/CDHDS77¾¾¾¾CDtechCDtech3.3.34FCCFCC----RSDSRIPPFCCNFCCNLCNLCNHCNHCNLCNLCNHCNHCNHCNHCN3.3.35FCCFCC----RSDSRIPP3.3.36FCCFCC----RSDSRIPP3.3.37FCCFCC----OCTOCT--MFCCMFCCFRIPPFRIPPOCTOCT--MFCCMFCC9090FCCFCC8585909015152525RONRON2.02.0(R+M)/2(R+M)/21.51.598983.3.38FCCNFCCNOCTGAINOCTGAINISALISALOATSOATSFCCNFCCNRIDOSRIDOSFCCNFCCN3.3.39FCCNFCCN----ISALISALUOPUOPFCCFCC99999090--7%7%6%6%3.3.403.3.FCCNFCCN----ISALISAL41FCCNFCCN----OCTGAINOCTGAIN2800ppm2800ppm100ppm100ppm--1.8%1.8%3.3.42FCCNFCCN----RIDOSRIDOSRIDOSRIDOS3.3.43FCCNFCCN––OATSOATSBPBPOATS(OATS())95%95%1010g/gg/gOATSOATSOATSOATS1%1%——4%4%OATSOATS99.5%99.5%00——223.3.44FCCNFCCN----RIDOSRIDOSRIDOSRIDOSFCCFCC200ppm200ppm20v%20v%RIDOSRIDOSCC33CC44RIDOSRIDOS3.3.45FCCNFCCN----RIDOSRIDOSRIDOSRIDOSFCCFCC200ppm200ppm20v%20v%RIDOSRIDOSCC33CC44RIDOSRIDOS3.3.46OTAOTAOTAOTAFCCFCCSHTSHTOTAOTASHTSHTOTAOTA//3.3.47OTAOTAOTAOTAFCCFCC1.01.0500500800ppm800ppm303050%50%200ppm200ppm20%20%500ppm500ppm303050%50%100ppm100ppm20%20%95%95%0.050.050.20%0.20%3.3.48SS--ZORPZORPSS--ZorbZorbConocoPhillipsConocoPhillips20072007887777SS--ZorbZorb3.3.49SS--ZORPZORPSS--ZorbZorbSSZorbZorbH2SH2SSSZorbZorb(())3.3.503.3.SS--ZORPZORP51SS--ZORPZORP¾¾¾¾¾¾¾¾3.3.52SS--ZORPZORP¾¾3.1MPa3.1MPa419419511511¾¾H2SH2SSO2SO2¾¾¾¾RONRON0.70.73.3.53¾¾SS--ZorbZorb¾¾SS--ZorbZorbSS--ZorbZorb¾¾SS--ZorbZorb3.3.54¾¾3.3.55¾¾IVIV((5050g/g)g/g)VV((1010g/g)g/g)¾¾3.3.56¾¾1700ppm1700ppm50ppm,50ppm,IVIV¾¾15ppm,15ppm,¾¾3.3.57¾¾RFCCRFCCRDS+RFCCRDS+RFCC10%10%,,¾¾HCNHCNLCNLCNHCNHCN8080LCNLCN1010--50ppm50ppm10ppm10ppm3.3.58T953.3.593.3.603.3.61--TKTK--574574TKTK--573573--KFKF--848848NebulaNebulaHRHR--462462HRHR--448448FHFH--UDSUDSRSRS--100010003.3.62------RTSRTS3.3.63------RTSRTS3.3.64------RTSRTS3.3.653.3.66,,NiNi--Mo/Mo/3.3.673.3.68FRIPPFRIPPFDAFDA3.3.69RIPPRIPPNiNi--WW3.3.70RIPPRIPP8.0MPa8.0MPa3.3.71SOxSOxFCCFCCFCCFCC::SOxSOx3.3.723.3.FCCFCC::VGO(2.5m%S)HT(0.15m%S)VGO(2.5m%S)HT(0.15m%S)FCCFCC::(3.0m%S)(0.2m%S)(3.0m%S)(0.2m%S)(2000ppmS)(50ppmS)(2000ppmS)(50ppmS)73RIPPRIPPFRIPPFRIPPCriterionCatalystCo.CriterionCatalystCo.DNDN--190190DNDN--200200DCDC--150150CC--447447AKZOAKZOKFKF--859859NiMoNiMoKFKF--902902NiCoMoNiCoMo3.3.743.3.753.3.763.3.M773.3.783.3.793.3.803.3.81VGOVGO3.3.82BTXBTXAPIAPI3.3.83ISOCRACKINGISOCRACKING19591959CHEVRONCHEVRONUOPUOPUNOCALUNOCALGULFGULFSHELLSHELLIFPIFPBASFBASFBPBP3.3.84UOPUOPCLGCLGSGSSGSUOPUOP19951995UNOCALUNOCALUNICRACKINGUNICRACKINGHCHC--UNIBONUNIBONUOPUOP3.3.85CHEVRONCHEVRON19861986GULFGULFISOCRACKINGISOCRACKING19931993ChevronChevronLummusLummus20002000ChevronChevronLummusLummus50%50%CLGCLGCLGCLG3.3.86SGSSGS3.3.873.3.8819661966196519653.3.8990903.3.90FRIPPFRIPPRIPPRIPP3.3.913.3.926.5MPa6.5MPa13.0MPa13.0MPa5405403.3.933.3.94195919593.3.953.3.963.3.973.3.983.3.99HyCycleHyCycle3.3.1003.3.1013.3.1023.3.HyCycleHyCycle103HyCycleHyCycleHyCycleHyCycle3.3.1043.3.105200710119255.X200710119255.X150x10150x1044t/at/a900900558.6558.6//57545754//47044704//3.3.106SEISEI20072007663.3.107200200//465MJ/t465MJ/t11.1kg11.1kg/t/t390MJ/t390MJ/t9.3kg9.3kg/t/t3.3.108H2SH2SH2SH2S320320//3.3.109¾¾¾¾3.3.110¾¾200200//3.3.111¾¾¾¾3.3.112----¾¾¾¾¾¾3.3.113----¾¾¾¾¾¾¾¾3.3.11419851985FisherFisherPRoVAXPRoVAXDCSDCSDCSDCSDCSDCS4.4.115¾¾¾¾¾¾4.4.116¾¾¾¾¾¾4.4.117¾¾¾¾DCSDCSDistributedControlSystemDistributedControlSystem4.4.118¾¾4.4.119¾¾4.4.120¾¾4.4.„5-2-3121¾¾4.4.122¾¾4.4.123¾¾00100%100%4.4.12