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1201910050H1Li7C12N14O16Na23S32Cl35.5Ar40Fe56I12776421ABCD2ABCD1,3-3XYZ10XZYXYZAXYBXZCXZZXDYZ4AB3NO24SOCl-C2DH++OH-H2O5NApH=2H3PO4AH+0.02NABc(H+)=c(42HPO)+2c(4HPO)+3c(34PO)+c(OH-)CpHDNaH2PO46ACl2BMnO2CD7Zn3D-ZnZnO3D-ZnNiOOHZn(s)+2NiOOH(s)+H2O(l)ZnO(s)+2Ni(OH)2(s)AZnZnOBNi(OH)2(s)+OH-(aq)-e-NiOOH(s)+H2O(l)CZn(s)+2OH-(aq)-2e-ZnO(s)+H2O(l)DOH-438-1011-1238814FeAlMgZnNiSi3[c0(Mn+)=0.1mol-1]pHMn2+Fe2+Fe3+Al3+Mg2+Zn2+Ni2+pH8.16.31.53.48.96.26.9pH10.18.32.84.710.98.28.911S______________________________________________________________________________2MnO2________________________3pHpH_______~641Zn2+Ni2+3______________52MgF2Mg2+Mg2+_____________________________________________________________________6___________________________________________________7LiNixCoyMnzO2NiCoMn+2+3+4x=y=13z=___________914/157~159-72~-74135~138/gcm31.441.101.35138102180100mL6.9g10mL0.5mL70.4100mL50mL5.4g1__________ABCD2______________________3______________________________________4____________________________5____________6_________%10151Deacon4HCl(g)+O2(g)=2Cl2(g)+2H2O(g)c(HCl)c(O2)114171HCl5K300____________K400HClc0c(HCl)c(O2)=11K400=____________c(HCl)c(O2)____________2DeaconCuCl2(s)=CuCl(s)+12Cl2(g)H1=83kJmol-1CuCl(s)+12O2(g)=CuO(s)+12Cl2(g)H2=-20kJmol-1CuO(s)+2HCl(g)=CuCl2(s)+H2O(g)H3=-121kJmol-14HCl(g)+O2(g)=2Cl2(g)+2H2O(g)H=_________kJmol-13HCI______________24____________________1mol__________L15211315LiFePO4FeCl3NH4H2PO4LiCl1Li________M_________2FeCl3FeCl3________Fe_____________3__________-5.9184.4-95.0110.66___________4NH4H2PO4______P_______O2p_______5NH4H2PO4LiFePO4____________nP12[5]15WHeckW1A___________2___________3___________W___________4/%1KOHDMFPd(OAc)222.32K2CO3DMFPd(OAc)210.53Et3NDMFPd(OAc)212.44DMFPd(OAc)231.25DMAPd(OAc)238.676NMPPd(OAc)224.5________________________5XDX________________6211molXNa2gH26Heck________________81C2D3B4A5B6A7D8141SiO2MnO2+MnS+2H2SO4=2MnSO4+S+2H2O2Fe2+Fe3+34.74NiSZnS5F-H+HFMgF2Mg2++2F-6Mn2++23HCO=MnCO3+CO2+H2O7139141A2BD345660101512240(0.42)(0.42)(10.84)(10.21)cO2Cl2HCl211634Fe3++e-=Fe2+4Fe2++O2+4H+=4Fe3++2H2O5.6113151Mg92434Osp35(PnO3n+1)(n+2)-12[5]15113-23C14H12O4456