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第四章环烃4.1C5H10不饱和度Π=1a.环戊烷b.c.d.e.1－甲基环丁烷顺－1,2－二甲基环丙烷反－1,2－二甲基环丙烷1,1－二甲基环丙烷cyclopentane1－methylcyclobutanecis－1,2－dimethylcyclopropanetrans－1,2－dimethyllcyclopropane1,1－dimethylcyclopropanef.乙基环丙烷ethylcyclopropane4.3a.1,1－二氯环庚烷1,1－dichlorocycloheptaneb.2,6－二甲基萘2,6－dimethylnaphthalenec.1－甲基－４－异丙基－1,4－环己二烯1－isopropyl―4－methyl－1,4－cyclohexadiened.对异丙基甲苯p－isopropyltoluenee.２－氯苯磺酸２－chlorobenzenesulfonicacidf.CH3NO2Clg.CH3CH3h.2－chloro－4－nitrotoluene2,3－dimethyl－1－phenyl－1－pentenecis－1,3－dimethylcyclopentane4.4完成下列反应：a.CH3HBrCH3Brb.+Cl2高温Clc.+Cl2ClClClCl+d.CH2CH3+Br2FeBr3C2H5Br+BrC2H5e.CH(CH3)2+Cl2高温C(CH3)2Clf.CH3O3Zn－powder,H2OCHOOg.CH3H2SO4H2O,CH3OHh.+CH2Cl2AlCl3CH2i.CH3+HNO3CH3NO2+CH3NO2j.+KMnO4H+COOHk.CH=CH2+Cl2CHCH2ClCl4.51.24.6CH3CH3CH3CH3+Br2FeBr3CH3CH3CH3CH3+BrBr+Br2FeBr3CH3CH3CH3CH3+BrBrCH3CH3+Br2FeBr3CH3CH3Br4.7b,d有芳香性4.8a.ABC1,3－环己二烯苯1－己炔Ag(NH3)2+C灰白色无反应ABBr2/CCl4无反应褪色BAb.AB环丙烷丙烯KMnO4无反应褪色AB4.9a.b.c.d.e.f.ClCOOHNHCOCH3CH3NO2COCH3OCH34.10a.Br2FeBr3BrNO2HNO3H2SO4Brb.HNO3H2SO4NO2Br2FeBr3BrO2Nc.CH32Cl2FeCl3CH3ClCld.CH3+Cl2FeCl3CH3ClKMnO4COOHCle.CH3KMnO4COOHCl2FeCl3COOHClf.HNO3H2SO4NO2CH3H3C2Br2FeBr3BrCH3BrNO2g.Br2FeBr3CH3CH3BrKMnO4COOHBrHNO3H2SO4COOHBrNO24.11可能为orororororor……即环辛烯及环烯双键碳上含非支链取代基的分子式为C8H14O2的各种异构体，例如以上各种异构体。4.12H3CC2H54.13BrBrA.4.14A.BrClBrClBrBrClBrBrClBCD4.15将下列结构改写为键线式。a.b.c.d.e.OOOHor第五章旋光异构5.4a.CH2CH2CH2CH3OHBrCH2OHHBrCOOHHBrCOOHHBrCH2CH3(R)(2R,3R)CH2OHBrHCH2CH3(S)b.HOOCCHCHBrCOOHBr(meso-)COOHHBrCOOHBrHCOOHBrHCOOHHBr(2S,3S)c.H3CCHBrCHCOOHBrCOOHHBrCH3HBrCOOHBrHCOOHBrHCOOHHBrCOOHBrH(2S,3R)(2R,3S)(2S,3S)(2R,3R)COOHBrHCH3HBrd.CH3C=CHCOOHCH3(无)5.6COOHHCH3CH2CH3(R)COOHH3CHCH2CH3(S)C5H10O25.7Π=1C6H12ACH2=CHCHCH2CH3*CH3BCH3CH2CHCH2CH3CH35.10(I)COOHHOHCH3(R)纸面上旋转90oOHHOOCCH3H(S)离开纸面旋转COOHHOHCH3(S)(对映异构)(对映异构)