有机化学答案于跃芹版第五章

第5章习题答案5-1CCH2CH3CH3CH3CH2O2NOCOONO2OCH3BrOCH3BrCHCH3BrCH=CH2CH2CH2OHOC2H5BrNO2NO2BrBr(1)(2)(3)(4)(5)(6)(7)(8)(9)COOHCOOH(10)5-2（1）．（D）（A）（B）（C）（2）．（B）（C）（A）（D）（3）．（C）（B）（A）（D）5-3.(1)(2)(3)(4)(5)(6)(7)(8)(9)(10)OCH3NO2COOHNO2NH2CH3COCH3BrCF3NO2OHSO3HNO2COOH5-4.CH3CHCH2OHCH3H+CH3CHCH2OH2CH3-H2OCH3CHCH2CH3CH3CCH3CH3重排+CH3CCH3CH3C(CH3)3-H+C(CH3)3(1)第5章芳香烃105重排(2)CCH2CH2CH2ClO+AlCl3CCH2CH2CH2O-AlCl4CCH2CHCH3OOCH3-H+OCH35-51．加入溴水无变化者为甲苯，已反应的两种化合物中加入顺丁烯二酸酐，产生白色沉淀者为1,3环己二烯。2．加入Ag(NH3)2+有白色者为苯基乙炔，余下两者加入KMnO4溶液，使之褪色者为乙苯。3．加入溴水褪色者为苯乙烯，余下两者加入KMnO4溶液，使之褪色者为异丙苯5-6有芳香性5-7.AB(1)AB(2)CH3C2H5CH3C2H5CH3C2H5COOHCOOHCOOHCOOHNO2BrBrCDE5-8.(1)CH3ClCH3KMnO4H+COOHCl2FeCOOHClAlCl3KMnO4H+COOHCH3(2)Br2FeCH3BrBrHNO3H2SO4COOHBrNO2(3)CH3CH2COClAlCl3CCH2CH3OZn-HgHClCH2CH2CH3Br2FeCH2CH2CH3Br有机化学106106