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第七章卤代烃习题参考答案1、（1）2-甲基-1-氯丙烷（伯卤代烷）（2）2-甲基2-溴丁烷（叔卤代烷）（3）2，2-二甲基4-溴戊烷（仲卤代烷）（4）Z-2-甲基-1-溴-2-戊烯（烯丙基型）（5）Z（顺）-3-甲基-2-氯-2-戊烯（乙烯型）（6）3-甲基-4-溴-1-丁烯（隔离型卤代烃）（7）对-氯甲苯（乙烯型）（8）1-苯基-1-溴丙烷（烯丙基型）2、（1）（2）（3）（4）CH3-CH-CH-CH3CH3BrBrCH3-CCCH2-CH3ClCH3ClCH3CH=CH-CH2ClCH=CH-CH2Br（5）（6）（7）（8）C=CH3CClCH3HC=CClHHC=CHClHCH3ClCH2Br3、（1）CH3ClCH2ClClClCH3abcdabcdAgNO3醇白：b快a慢无沉淀；c,dKMnO4H+褪色：d不褪色：c（2）CH3-CH-CH-CH3CH3ClCH2=CHClCH2=CH-C-CH3ClCH3abcabcAgNO3醇白：快c白：慢a无沉淀：b(3)CH2=CH-CH-CH3ClCH2=CH-CH-CH3IAgNO3醇先有黄色沉淀：CH2=CH-CH-CH3I先有白色沉淀：CH2=CH-CH-CH3Cl4、（1）CH2-CH-CH2CH3CH3BrCH3-CH-CH-CH3CH3BrCH3-C-CH2CH3CH3Br（2）CH2-CH2-CH2CH3BrCH3-C-CH3CH3BrCH3-CH2-CH-CH3Br（3）CH2-CH2-CH2CH3BrCH2-CH2-CH2CH3ICH2-CH2-CH2CH3Cl（4）CH3-C-CH2CH3CH3BrCH3-CH-CH-CH3CH3BrCH2-CH-CH2CH3CH3Br5、（1）CH3-CH-CH-CH3CH3ClNaOH乙醇，CH3-C=CH-CH3CH3Br2CH3-C-CH-CH3CH3BrBrNaOH乙醇，CH2=C-CH=CH2CH3（2）ClCH2Cl+NaCN乙醇ClCH2CNH2OH+ClCH2COOH（3）CH2Br+Mg无水乙醚CH2MgBr(1)CO2(2)H2OCH2COOH（4）CH-CH3BrNaOH乙醇，CH=CH2HBr过氧化物CH2-CH2BrCH3ONa乙醇CH2-CH2OCH3（5）CH3BrNaOH乙醇，CH3KMnO4H+CH3-C-CH2-CH2-CH2-C-OHOO6、（1）CH2=CH2Br2Br-CH2-CH2-BrNaCN乙醇NC-CH2-CH2-CNH2OH+HOOC-CH2CH2-COOH（2）CH3-CH2-CH-CH3BrNaOH乙醇，CH3-CH=CH-CH3KMnO4H+CH3COOH（3）CH2=CH2HClCH3-CH2ClNaCH3-CH2-CH2CH3（4）CH3-CH2CH2-ClNaOH乙醇，CH3-CH=CH2HClCH3-CH-CH3ClNH3CH3-CH-CH3NH3（5）CH2-CH-CH3CH3BrNaOH乙醇，CH2=C-CH3CH3HBrCH3-C-CH3CH3BrNaCN乙醇CH3-C-CH3CH3CNH2OH+CH3-C-CH3CH3COOH（6）CH3-C=CH2CH3HBr过氧化物CH3-CH-CH2BrCH3NaCN乙醇CH3-CH-CH2CNCH3H2OH+CH3-CH-CH2COOHCH37、CH3-CH-CH-CH3CH3BrNaOH乙醇，CH3-C=CH-CH3CH3HBrABCH3-C-CH2-CH3CH3BrNaOH乙醇，CCH3-C=CH-CH3CH3KMnO4H+CH3-C=OCH3+CH3COOH8、A、CH3CHCH=CH2BrB、CH3CH-CHCH2BrBrBrC、CH2=CH-CH=CH2