纳米材料在食品有害污染物检测中的应用进展-张帆

3212201312FENXICESHIXUEBAOJournalofInstrumentalAnalysisVol.32No.121523～15282013－04－272013－08－012010bx01CX2012B3322013IK1602012BAK08B01*[e-mail]121*2331．4100042．4100043．410004、、、、。、。、。O572.21F407.82A1004－4957201312－1523－06doi10.3969/j.issn.1004－4957.2013.12.022ProgressonApplicationofNanometerMaterialinDeterminationofHarmfulPollutantinFoodZHANGFan12LIZhong-hai1*XIHui2ZHANGYing3HUANGZhi-qiang31．FacultyofFoodScienceandEngineeringCentralSouthUniversityofForestryandTechnologyChangsha410004China2．ChangshaEnvironmentalProtectionCollegeChangsha410004China3．HunanAcademyofScienceandTechnologyforInspectionandQuarantineChangsha410004ChinaAbstractWiththeiruniquephysicalandchemicalpropertiesnanometermaterialsplayamoreandmoreimportantroleinmanyfieldsofsciencemoreattentionswerepaidforharmfulpollutantsinfoodsuchasheavymetalpesticideresidueandveterinarydrugresidueandharmfulsubstancesinpackagingmaterialbutthecurrentmethodfordeterminationoftheseharmfulpollutantsinfoodlacksofrapidnesssensitivityandeconomy．Theapplicationsofnanometermaterialsinanalysisoftheseharmfulpollutantsinfoodhavesolvedtheproblemandbecometheresearchfocusofanalyticalchem-istry．Inthisarticlethebasiccharacteristicsofnanometermaterialsweredescribedandthecate-gorysourceandharmfulnessoftheharmfulpollutantsinfoodwereanalyzed．Furthermorethere-centprogressontheapplicationofthenanometermaterialsindetectionoftheseharmfulpollutantsinfoodwasalsosummarized．Keywordsnanometermaterialfoodharmfulpollutantapplication。“”、“、、、”。、、、、、、、、、。、－、、－、、、－、1－4、。2080。、、32。5、6、7、84。、、、、、。、、、。1、1.1。、、、、5g/cm3。、、、。。、、、、、、9。1.2。。“”、、。、、、、、、、、、。10。1.3、、、。、。、、、、、。、。、。、、、11。1.4。A、、、。425112。、。、、、。22.11985KrotoSmalleyC6012。、、。Tuzen13CuⅡ6。Zhao14QuEChEＲSPSA－、303071%～110%15%、、、。Zhao15Lidia16。17－－。、678.6%～89.9%10%、－。18、2424-2、。、。Su19。SPE。、20－21。2.2200422。、。23。1～100μmol/L0.5μmol/L。Guan244、2870.5%～100%13%GPC、。Wang25C18、、。Ｒafal26525132、、C18、。。MSPD、27。。2.3、、。28Fe3O4ELISA。Shishehbore29Fe3O4SiO2、。Zhou30Fe3O4ELISA88%～105%0.377～14.07mg/L、。31Fe3O4@Si－C8/C18Fe3O4@Si－C8/C18。32－AFe3O4。Saravanan33GumkondagoguGKMNPGK－MNP60emu/g。pH5.0±0.1、30.0±1.0℃GK－MNP＞＞＞＞＞106.8mg/g35.07mg/g。、。2.4、。Hu3410。35。、、。Siriwan360.02、0.3ppm。Forouzan37———。2.5、。、、。Chen38。39PVP－CdS625112、、。Carolina40CdSe/ZnS、、6min。GPCSPEZhou41Mn－ZnS、、。pH、。2.6、、。、、、、42。。Ai43。。Jin44ELISA10μg/L。3、、、、、、、。、、。、、、。1HuangZQZhangYWangLBDingLWangMLYanHFLiYJZhuSH．J.Sep.Sci.20093291294－1230．2LiuLBHashiYQinYPZhouHXLinJM.J.Chromatogr.B200784561－68．3LiBLiJYZhouXZYangYJNiuJＲWeiXJLiJSZhangJY.AnimalHusbandry＆VeterinaryMedicine．201244582－86．4LiuSC.StudyonDeterminationTechniquesforAnalyzingHarmfulOrganicChemicalＲesiduesintheFieldofFoodSafety.TianjinTianjinUniversity．．2007．5WangYX.ApplicationofFunctionalizedMagneticNanopaticlesinＲemovalandAnalysisofEnvironmentalPollutants.ShaanxiNorthwestAgricultureandForestryUniversity．．2012．6KangYChaiXJ．WestLeather．2010321533－39．7ZhuSDZhouGSCaiＲHanYTianW.HeatTreatmentTechnologyandEquipment．20103131－526．8LiYJWangJSTianL．J.GansuLianheUniv.Nat.Sci.Ed.．200317354－56．9LuoXZ.FujianQualityInformation．2010639－4349．72513210HuangZQ．GuidelinesfortheDetectionofPesticideＲesiduesinFood.BeijingStandardsPressofChina．．2010．11LiＲYLiuYL.Chin.J.Veter.Med.．2010461274－76．12SongX．SynthesisPurificationandＲamanSpectroscopicStudiesofSingle-walledCarbonNanotubes.BeijingCapitalNormalUnversity．、．2007．13TuzenMSaygiKOSolyakM.J.Hazard.Mater.20081522632－639．14ZhaoPYWangLZhouLZhangFZKangSPanCP.J.Chromatogr.A2012122517－25．15ZhaoHXWangLPQiuYMZhouZQZhongWKLiX.Anal.Chim.Acta20075861/2399－406．16LidiaMＲaveloPJavierHBMiguelAＲD.J.Chromatogr.A2008121133－42．17WuXHDingLLiZHZhangYLLiuXXWangLB.Chin.J.Chromatogr.．201028111094－1098．18PengXJWenQJPangJSDengAHLiangWHLiangYZ.J.Instrum.Anal.．201231111373－1378．19SuＲXuXWangXHLiDLiXYZhangHQYuAM.J.Chromatogr.B20118793423－3428．20GuanYJiangCHuCFJiaL.Talanta201383337－343．21MoraleCGFeketeASimonetBMLehmannＲCardenasSZhangXMValcarcelMSchmittK．Anal.Chem.2010822743－2752．22ZhangXQ.FunctionalizationofGrapheneandItsOptoelectronicProperties.TianjinTianjinUniversity．．2011．23LuoSXZhangHYWuYHZhangF.Sci.Technol.FoodInd．．2012331873－7478．24GuanWBLiZNZhangHYHongHJＲebeyevNYeYMaYQ．J.Chromatogr.A201312861－8．25WangYKGaoSTZangXHLiJCMaJJ.Anal.Chim.Acta2012716112－118．26ＲafalSBeataZEwaM．TrACTrendsAnal.Chem.2013doi10.1016/j.trac.2013.05.011．27AnnaLCChiaraCPieroGＲiccardoGＲobertoSAldoL．J.Chromatogr.A201012172521－2532．28HuY．ImmunoassayforTypicalPesticideandVeterinaryDrugsＲesidueBasedonMagneticNamopaticles.ShanghaiShanghaiJiaoTongUniversity．．2011．29ShishehboreMＲAfkhamiABogherimH.Chem.CentralJ.2011511－10．30ZhouHLHuYJiangGXShenGQ.Eur.FoodＲes.Technol.20112335881－887．31ZhangHYangCLLüJZTangMJLiuQSWanZGXieLQYueZFLiLS.FoodSci.．20123318108－112．32WuXHDingLXiaoJYLongYJXuZLiZHWangLB.Chin.J.Chromatogr.．2011295399－403．33SaravananPVinodVTPSreednarBSashidharＲB.Mater.Sci.Eng.C2012323581－586．34HuJSZhongLSSongWGWanLJ．Adv.Mater.200820152977－2982．35TanLLuXXBaiHPYangGMYangYH.Phys.Test.Chem.Anal.Chem.Anal．．2009455567－570．36SiriwanSProespichayaKPunneeAChusakLBooncharoenWPanoteT．Bi