全绿色化工的进展及前景

2010,20(1)周家贤全绿色化工的进展及前景*200032,,,,,,,,,,,,;,,,,,,,,,,111[1],,2070,,,:12[2],1988,,,350,700MW,2010,13000MW,,,,Battelle(63MW)(6MW)B-IGCC()13[3]H2CO,2050,/,3*:1981,1995:[phone]CHEMICALENGINEERINGDESIGN化工设计2010,20(1);;NHI(BGMS),221[4][6]211,,,,(1),(2),212[5],,,Sakatchewan(SRC)NaturalResourceCanada20075,170kt/a213,(1):,,,,;,,,,,,(2)Stavarache,,,,,22[7],:,,2007441010L,,90%,10,BP105,,,,8000,,23[8][9][10],42010,20(1)周家贤全绿色化工的进展及前景(),,2080,(IEA)Batele,MIT,20,50/,t,,TUBINGEN,2000kg/h,70%,,,,,3[11](PLA),,,,,,:;();()(),(),,Hycail,(HycailXM1020)200,PLA,,,,GargilDow,1068%,,GargilDow,;;,,,200~250kt/a,,,20101100kt/a4,,,41411,,,5CHEMICALENGINEERINGDESIGN化工设计2010,20(1),2007620kt/a,,30kt/a412[12],,,(),,,,CO70%CO,6kNm3/hCO,413,,,,CO2-CH4,414,,,,,100kg/d,TopsoeCO2H2415CO2,CO2,,416(EnhancedOilRecoveryEOR),CO2,,CO2,,,,,CO2WestTexas10/dCO235%,,20088,,42[13]10%,,,(1)(PTT),PTT1,3-,1,3-,,,,,20kt/a,250t/a1,3-1,3-,,(2)5[14],,30%,10%90%,94%,62010,20(1)周家贤全绿色化工的进展及前景:,,6[15][16][17]61,,,,,,,,,,62,,,,,,,,,,,,,,,:;;,(MTOMTP),,,,,,,63,,,,,,,,1,[J],2007(11)2[J],2007(1)3,,,[J],2006(7)4,,[J],2008(1)5,,,[J],2008(3)6,,[J],2007(6)7EEC2008(2)8,,[J],2006(4)9,,,[J],2008(3)10,[J],2008(1)11[J],2007(1)12,O2CO2CO[J],2008(1)13,,1,3[J],2007(1)14,[J],2007(12)15,,,[J]()2007(6)16[J],2007(5)17[J],2009(1)(2009-05-15)72010,20(1)ABSTRACTSOFCHEMICALENGINEERINGDESIGNABSTRACTSDevelopmentandFutureofFullGreenChemicalIndustryZhouJiaxian(ChinaHuangqiuContracting&EngineeringCorp.(Shanghai),Shanghai200032)Fullgreenchemicalindustryprovidesaperfectwaytoresolvetheresourceandenvironmentissues.Fullgreenchemicalindustrytakesbiomassastherawmaterialsandadoptsthecleanprocesstoproducethegreenproducts.Thearticleintroducesthetechnologydevelopmentofthebiomassgasificationandliquefactionaswellasthebiomassplastics,andtheutilizationofthemajorbyproductsofcarbondioxideandglycerinproducedbybiomassduringtransformation.KeywordsbiomassfullgreenchemicalindustryresourceenvironmentStudyonNewTechnologyofNeutralizationandWater-washofCrudeNitrobenzenebyStaticMixerGongJianhua,etal(SinopecNanjingDesignInstitute,Nanjing210048)Selectthestagenumberofthestaticmixerandcomparetheefficiencyofneutralizationandwater-washofthestaticmixerwiththekettle-typemixerunderthesameconditions.Conductthepilotteststudyontheprocessingcapacityandtwo-stagewater-washandapplythetechnologyintheengineeringdesign.Keywordsaciditynitrobenzenekettle-typestaticmixerneutralizationwater-washProcessDesignofOil-waterSeparatorinFischer-TropschSynthesisWangTao,etal(ChengduGeneralEngineeringTechnologyCo.Ltd.,Chengdu610041)Basedonthecharacteristicsofhorizontaloil-waterseparator,analyzethefactorsthatinfluencetheeffectofoilandwaterseparation.Introducetheprocessdesignofoil-waterseparatoranddiscussitsoperationprocess.Keywordsoil-waterseparatorcoalliquefactionFischer-TropschsynthesisProcessDesignanditsCommercialApplicationofCrackingFuelOilComprehensiveUtilizationPlantWuXinjun,etal(PetroChinaDushanziPetrochemicalEngineeringCorporation,Dushanzi833600)Introducetheprocessdesignprinciples,majortechnicalcharacteristicsandprocessof60kt/acrackingfueloilcomprehensiveutilizationplant.Becauseofitsfunctioningproperly,higherproductqualityandlightconstituentyield,itdemonstratesthattheprocessandengineeringdesignofadoptingthecontinuousvacuumdistillation,fractionalcrystallizationandMo-Nitwo-stagecatalytichydrogenationforthecrackingfueloilcomprehensiveutilizationplantaresuccessfu.lKeywordscrackingfueloilvacuumdistillationfractionalcrystallizationpetroleumnaphthalenehydrogenationsolventoilDesignofQuenchOilViscosityDecreasingSystemforSmallEthylenePlantsTongKe,etal(PetroChinaNortheastRefining&ChemicalEngineeringCo.Ltd.JilinDesignInstitute,Jilin132002)IntroducethecommonproblemsexistinginvariousquenchoilviscositydecreasingpatentedtechnologiesofsmallethyleneplantsinChinaandvariousprocessesofquenchoilviscositydecreasingsystemanditsprinciple.Discussthedesignproblems,soastoguaranteethestablerunningofthequenchoilviscositydecreasingsystemandmeettheheavydutyproductionrequirementsofthequenchoiltower.KeywordssmallethyleneplantquenchoilsystemquenchoiltowerviscositydecreaseviscositydecreasingtowerdesignEnergySavingFunctionofCO2forMethanolMadefromNaturalGasPlantXuHuayin,etal(QinghaiZhonghaoNaturalGasChemicalCo.,Ltd.,Geermu816000)IntroducethefunctionofCO2innaturalgastransformationandmethanolsynthesis.ProperlycontrollingtheCO2rechargeandtheCO2contentinsynthesisgascanincreasethemethanoloutputanddecreasetheconsumption.KeywordsCO2water-carbonratiohydrogen-carbonratioOptimizationofProcessConditionsforShapedCoalGasificationYanXin(HunanChemicalIndustryVocationandTechnologyCollege,Zhuzhou412004)Shapedcoalgasificationhasaccountedfor60%incoalbasedsynthesisammoniaandcombining-methanolproductioninChina.Introducethedifferencesbetweenshapedandlumpcoalgasification,gasificationcharacteristics,optimizationofprocessconditionsandtheproblemsremaintobesolvedforshapedcoalgasification,etc.KeywordsshapedcoalsynthesisammoniagasificationtechnologyprocessoptimizationCalculationofReliefCapacityofPSVunderS