《有机化学》试卷(13)答案

1《有机化学》试卷(13)参考答案一、用系统命名法命名或写出结构式1.1,1-二氯环庚烷2.反-1,2-二氯环丙烷3.反-1,3-二甲基环己烷4.1-苯-4-溴-1-丁烯5.反-1,2-环己二醇6.对甲基苯甲醛7.8.CHCCH2CHCH3CH39.H3CNO10.CH3CHCH2COOHBr11.OOHOHOHOHCH2OH12.CH3CH2COCH2CHO二、选择题1.B2.A3.C4.C5.A6.D7.B8.A9.C10.D11.B12.C三、完成反应式1.CH2Br2.CH3CHCCH3BrCH3OH3.N(CH3)3Cl4.ClHOOCNO25.CH2OHNNHC6H5HCNNHC6H56.COOCH3H2O18+7.CH3CH2CCH3CHCH2CH38.OCH3CH3NO29.CH3CHCHOCl10.CH2OH+HCOONa四、由指定原料合成目标化合物1.(CH3)2CCH2(CH3)3CCOOHHBr(CH3)2CBrCH3Mg干醚(CH3)3CMgBr①CO2②H2O/H+2.2C2H5CHCH3OHHBrC2H5CHCH3BrMg干醚C2H5CHCH3MgBrCH3OHCuHCHOC2H5CHCH2CH3OMgBrH3O+C2H5CHCH2OHCH33.CH3COCH2CH3CH3CHCCH2CH3CH3CH3CH2MgBrH3O+CH3CCH2CH3OHCH2CH3H2SO4五、以简便化学方法鉴别各组有机化合物SO2ClNaOH溶分层固体析出1.NH2N(CH3)2NHCH32.CH3CH2CH(OH)CH3CH3CH2CH2CH2OH(CH3)3COHZnCl2/HCl加热出现混浊立刻出现混浊静置数分钟出现混浊CHOCOCH33.Ag(NH3)2+AgI2+NaOHCHI3CH3CHOCH3CH2CCH2CH3OAgI2+NaOHCHI3六、推测有机化合物的结构1.(CH3)2CHCHCH3OH[O](CH3)2CHCCH3OH2O(CH3)2CCHCH3[O]CH3COCH3+CH3COOH32.CH3CCCHOHHA:CH3CCHCHOHA与溴的加成产物CHOHBrCH3BrH,CHOBrHCH3HBrCHOHBrCH3HBr,或CHOBrHCH3BrH