《有机化学》试卷(6)答案

1《有机化学》试卷(6)参考答案一、用系统命名法命名或写出结构式1.2,5-二甲基庚烷2.(E)-1,3,5-己三烯3.(3R)-4-甲基-3-氯-1-戊烯4.烯丙基溴（3-溴-1-丙烯）5.反-1,3-二甲氧基环戊烷6.3-羟基丙醛7.CCCH2CH2CH3CH(CH3)2CH3CH3CH28.CH39.HOCH2CH2OCH310.H2NNHC6H511.CH3CH2CNOCH3CH312.OHOOHCH2OHOHOH二、选择题1.A2.B3.D4.A5.B6.D7.D8.D9.A10.C11.C12.D三、完成反应式1.OHCH2CH32.CCH3O3.NO2NO2NO2NO2+4.BrBr5.BrNH2BrBr6.CH2OHCOOH7.O8.CH3CCH3CHCH3BrBr9.Cl10.CH3CH3CH2CNOH四、由指定原料合成目标化合物1.CH3BrBrNO2CH3Cl无水AlCl3+HNO3－H2SO4Br2Fe2.CH3CH2CHCH2CH3CHCHCH2ClBrOHBr2500℃CH3CHCHCH2BrCl2+H2O23.OHOH无水HClOO稀冷KMnO4OH－OOCH3CH-CHCHOHOHH3O+CH3CH-CHCHOOHOHCH3CH=CHCHOCH3CH=CHCH五、以简便化学方法鉴别各组有机化合物1.Br2/CCl4红棕色褪去Ag(NH3)22.甲酸草酸丁二酸Ag(NH3)2+XX草酸丁二酸KMnO4褪色不褪色CHOCOCH3OHH3CCH2OH3.Ag(NH3)2+AgI2+NaOHCHI3FeCl3显色H3C六、推测有机化合物的结构A:O3ZnCH3CH2CCH3OKMnO4冷C2H5CH3OHC2H5CH3OHB:CH3CH2CCCH2CH3CH3CH31.32.CH3CH2CCHCH3CH3O(A)H2PtCH3CH2CHCHCH3CH3OH浓H2SO4CH3CH2CH=CCH3CH3②H2O,Zn①O3CH3CH2CHO+CH3COCH3(B)(C)CH3CH2CCHCH3CH3OH2NOHCH3CCCHCH3CH3(A)NOH+CH3CH2CHOAg(NH3)2+OH-CH3CH2COONH4+Ag+NH3+H2O(B)(C)CH3COCH3CHI3+CH3COONaI2-NaOH