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363Vol.36No.320076JOURNALOFSYNTHETICCRYSTALSJune,20071,1,2(1.,541004;2.,541004):,,,,:;;;:O634:A:10002985X(2007)0320705206ActualityResearchofSynthesisandCapacityofSchiffBaseDerivedfromSalicylaldehydeandItsRamificationsJINLi2xia1,LIUZheng1,XIAJin2hong2(1.DepartmentofMaterialsandChemistryEngineering,GuilinUniversityofTechnology,Guilin541004,China;2.DepartmentofElectronicEngineering,GuilinUniversityofElectronicTechnology,Guilin541004,China)(Received8November2006,accepted6March2007)Abstract:ThesynthesisandinfluencefactorsofSchiffbasederivedfromsalicylaldehydeweresummarizedinthearticle.Itsramifications,anditsbioactivity,indicatesthepotentialoflabelingradionueli2des,antibacterial,catalyticactivity,thefreeradicalinhibitionratetoO22,applicationinanalyticalchemistryandappliancechemistryalsopresented.Keywords:salicylaldehyde;schiffbase;complex;capability:2006211208;:2007203206:(D203252):(19822),,,:,E2mail:lisa@163.com1,,,[1],,,N,,[2],[3],,70636,,,22.11960[4],:,,,,2,[5],,,,100,,,,,,,,,,,,,:,d,,,,[6],,,:(a);[7210];(b):,,,[Ni(TSSB)(Phen)(H2O)]4H2O[11],;(c):,,,,[12];(d):,,,,,,,(),,,,[13],[14],,[15],,,:(),,[1],,,,,,,[16]2.2,3:707,,,,,,,,,100,,,,,,33.1Hodnett,,[1],R[H,CH3,CH(CH3)2,CH2CH(CH3)2],,[17],,,,,[2],,,,,,:(1),;(2),;(3),,,,,,[18]2105,,5,,,[19],,,,,,[20]3,53,52(),,[21]3.2L2,L2,L2,L2,L2,L2,L2710-5molL-1,610-4molL-1,pH89,pH9,pH7,,724h7,70836[22]3.3(O-2),,,O-252(),O-2,,,,[23],,,[24]3.4,,,,,:,,,,()(Sal2Ala2Mn),;[25],(Sal2His2Mn),,,(),,50%,,,[26],,:,,..65.38%[27](III)[28]98,[29],,,,:,,,,,,(15%),,,[30],,2,,[31]15,,[32]3.5[33],3:709:,;,[34],,,,,,,4,,:,,[35],,3,5[36]pH[37],,,3,52,,[38]3,52,,pH8.09.0,,,,[39]()3,52,[40]A.Koll72(PSBA)72(ESA),,PSBA[41]ZvjezdanaCimermanN,N2()22,32,N,N2()22,62,Cu(),Mn(),Fe(),Ni()Cr()[42]AsukaOhshima,77K,[43]4:,,,[6]:(1),,,,[44],X2,;(2),,:,,,[1].[M].:,2004:113.[2],,,.Schiff[J].,2004,33(4):26229.71036[3],,,.Schiff()[J].,2005,16(2):15218.[4]ShoichiroYamada.AdvancementinStereochemicalAspectsofSchiffBaseMetalComplexes[J].CoordinationChemistryReviews,1999,1902192:5372555.[5],.[J].,2005,(3):58259.[6],,,.[M]..2000:26227.[7]SamikGupta,AnilKumarBarik,SachindranathPal,etal.Oxomolybdenum(VI)and(IV)ComplexesofPyrazoleDerivedONODonorLigands2synthesis,CrystalStructureStudiesandSpectroelectrochemicalCorrelation[J].Polyhedron,2007,26(1):1332141.[8]JoyChakraborty,BrajagopalSamanta,GuillaumePilet.Tris(2phenoxo)BridgedCd(II)PolymerSynthesisedfromaSymmetricalTripodalLigand:ANovelObservationforHeptadentateMonocappedTrigonalAntiprismaticSchiffBaseComplex[J].InorganicChemistryCommunications,2007,10(1):40244.[9]AymanAhmedH.Physico2chemicalStudiesandCOAdsorptiononZeolite2encapsulatedMnII,MnIII2hydrazoneComplexes[J].JournalofMolecularStructure,2006,27(3):4212428.[10]AliRezaFakhari,AfshinRajabiKhorrami,HosseinNaeimi.SynthesisandAnalyticalApplicationofaNovelTetradentateN2O2SchiffBaseasaChromogenicReagentforDeterminationofNickelinSomeNaturalFoodSamples[J].Talanta,2005,66(4)8132817.[11],,.[Ni(TSSB)(Phen)(H2O)]4H2O[J].,2005,21(9):139221396.[12]NuanphunChantarasiri,VithayaRuangpornvisuti,NongnujMuangsin.StructureandPhysico2chemicalPropertiesofHexadentateSchiffBaseZincComplexesDerivedfromSalicylaldeHydesandTriethylenetetramine[J].JournalofMolecularStructure,2004,701(123):932103.[13],,.ZnO[J].,2006,35(5):102621021.[14],,.[VO(2OCH3)(salen)]2[J].,2004,12(5):4652467[15],,.[Cu3(22dppm)3(32I)2]I[J].,2005,35(4):45248.[16],.[M].:,2003.[17],.()[J].,1996,12(4):4232426.[18],,.[J].,1999,15(4):4932496.[19].210[J].,2003,16(1):57259.[20].Cu()2[J].,2000,26(3):[21],,,.3,52Schiff()[J].,1998,10(2):1792181.[22],,,.7Zn2+99mTc[J].,2003,39:7902795.[23],,,.52Schiff[J].,2004,12(4):4372439.[24],,,.[J].(),1994,28(3):3522354.[25],,,.[J].,2004,21(11):113621140.[26],,,.[J].(),2001,38(2):2302234.[27],,,.[J].,2004,33(4):80283.[28]RukhsanaI.Kureshy,Noor2ulH.etal.DimericchiralMn(III)Schiffbasecomplex2catalysedenantioselectiveepoxidationofnon2functionalisedalkenes[J].TetrahedronLetters.2001,42(15):291522918.[29]C.A.Sureshan,P.K.Bhattacharya.Synthesis,characterisationandhomogeneouscatalyticactivitystudyofMn(II)andFe(III)ternarycomplexes[J].JournalofMolecularCatalysisA:Chemical.1998,136(3):2852291.[30],.[J]..2005,34(11):6642666.[31],,,.2[J].().2005,29(3):13218.[32],,.[J]..2005,25(8):8932901.[33]ZvjezdanaCimerman,NivesGalic,BrankaBosner.TheSchiffbasesofsalicylaldehydeandaminopyridinesashighlysensitiveanalyticalreagents[J].AnalyticaChimicaActa.1997,343(122):1452153.[34]AliAkbarKhandar,SeyedAbolfazlHosseini2Yazdi,SeyedAmirZarei.Synthesis,characterizationandX2raycrystalstructuresofcopper(II)andnickel(II)complexeswithpotentiallyhexadentateSchiffbaseligands[J].InorganicaChimicaActa.2005,358(11):321123217.(718)718362300510512105Pa3050/cmAr36H2SiC3,20mm,,SiC[1],,,.6H2SiC[J].,2003,(5).(710)[35],,.[J]..2004,36(3):52255.[36]Shin2ichiNagaoka,ArinobuNakamura,UmpeiNagashima.Nodal2planemodelforexcited2stateintramolecularprotontransferofo2hydroxybenzaldehyde:substituenteffect[J].JournalofPhotochemistryandPhotobiologyA:Chemistry.2002,154(1):23232.[37]RaafatM.Issa,SamyA.El2Daly,etal.UV