生物质制燃料乙醇

2007362PETROCHEMICALTECHNOLOGY[]2006-09-22;[]2006-10-16[](1974),,,,:,021-64251001,[e-mail]陈辉,陆善祥(,200237)[],,,,,[];;;;[]1000-8144(2007)02-0107-11[]TQ517.2[]AProgressinProductionofFuel-EthanolfromBiomassResourcesChenHui,LuShanxiang(UNILABofEastChinaUniversityofScienceandTechnology,Shanghai200237,China)[Abstract]Productionoffuel-ethanolfrombiomassresourcesisenvironment-friendlyandisapromisingsubstitutivetechnologyforlimitedcrudeoilresource.Currentcostforproductionofethanolfromcelluloseplantisstillhigh.Theprogressesintechnology,includingpretreatmentofmaterials,removaloffermentationinhibitorsinhydrolysate,hydrolysisandfermentationtechnology,andgeneticallyengineeredstrainsforcellulaseproductionandethanolfermentationwerereviewed.Theworld'simportantprojectsforutilizationofbiomasswerebrieflydescribedandfuturedevelopmentforproductionoffuel-ethanolfrombiomasswasdiscussed.[Keywords]fuelethano;lbiomass;cellulose;geneticengineering;fermentation,,CO2,,,10%~15%,,,,,60%0.2/L,0.3/L,0.48/L[1],4000/t,,,(),,,,,107PETROCHEMICALTECHNOLOGY2007361,,,,,,,,1.2[2],,[3~5][6~9][10,11][12][13][14]2,;,,,;,,,[15][16]2.1:,,,,2.2:,(NaOH)(H2O2)2.2.1,Eyini[17],,,,,Foody[18]V(),,160~280!2.2.2NaOHCa(OH)2(20%~40%)[19],NaOH,,[20]Ca(OH)2,,:,55!28d,87.5%,91.3%51.8%,0.073gCa(OH)2,[21],,(ARP),,50%,92%,ARP:84%,ARP75%,79%[22]2.2.3Lissens[23](185~200!100g0~3.3gNa2CO315min0.3~1.2MPa),79%49%()[8][24][25]2.3,,,(SE)[26],SESE:,,,,1082.,SE(),SE,OCHC[27]SE,SE,95%,,[28],pH160!pH4.0,20min50%(80%,20%),1%,,,[29]SE[14],SE2.55MPa3min,[30]SE,200!5min2%H2SO4,SE4,[31]SE,,5%~20%,50%[32]SE:(180!10min0.5%H2SO4)SE,(200!2min2%H2SO4)SE()[33]Soderstrom[34]SESO2SE,(180!10min0.5%H2SO4),(210!5min3%SO2),66%,(SHF)71%(AFEX)SE,AFEX,16%93%,2.2~2.5[35,36]Fenton(H2O2Fe2+)SE,H2O2(50mmol/L),0.6g/L,95%[37]SE,[38]SE,(185!5min),24%,SE,93%2.4:(Basidiomycete,CSubvermispora,DSqualens,POstreatus,CVersicolor)[39],,,15%[39]Anderson[40],,3,,Martin[41]SE,,,,,3.1,Helle[42]SCerevisiae,Klinke[43],,,Cantarella[44]SE((HMF)),,,,109PETROCHEMICALTECHNOLOGY200736[45,46][47],[48]Weil[49]XAD-4,,1~5g/L0.01g/LCLigniariaNRRL30616[50]TReesi,4,3[51],,,,,Ca(OH)213C[52],,O∀Brien[12]Ca(OH)2(AEN),,AENCantarella[53],,Ca(OH)2,92%,,,,[54],,,[55]3.2,,,Kim[56]ZMobilisZM4ZM4/AcR,31P,ZM4/AcRpH,HMF,SCerevisiaePStipitisHMF2,5--(),[57]44.1,(CBH)-,,(CBD)3,,CBD,Vaaje-Kolstad[58,59],CBD(CBP21)CBP21,CBD,CBD[60](Trichoderma)(Aspergillus)(PenicillumHumicola)(Fusarium)(Streptomyces)(Bacillus)(Cellulomonas),,,,,,,(1/10),0.026~0.053/L[61],,[62],DNA,TReesiCe17ASSerevisiaeTReesiCe17A1102.Bower[63]ACellulolyticusGH5ATReesiCBH,TReesi,ACellulolyticsTReesi,,51.40[64]Hood[65],,4.2,,(10%~20%),,CLusitaniaes,[66]SCerevisiaeTMB3001,CPBCR1,CPBCR2[67]SCerevisiae,,EColi,PStipititis,ZMobilis,,,EColi,pH6.0~8.0,,PStipitis,,,ZMobilis,[68],ZMobilis8b,pH=685%[69],:EColiKO11[70],PStipitisCBS5773[71],PStipitisCBS6054[72],SCerevisiaeEF1014[73],SCerevisiae424A[74,75],SCerevisiaeTMB3400[73];BeckerSCerevisiae;:MIndicus[76],F-71[77],COpuntiae1605[78],TMathraniiA3M3[43]4.3CThermocellum[79],TrichodermaA10[80],KMarxianus[81],3[82],()[83]4.4,,KMarxianusDER-26CECT10875[35,84],[85];ADH6,[86]53:SHF()(SSF)5.1SHFSHF:[87,88],JBCMasadaOxyNolLLCMasadaCESOxyNol[6],,,,,[89],Dowex99(PVP)[90]PVP(111PETROCHEMICALTECHNOLOGY200736)()[91]5.2SSFSSF,,,50!,37~40!:,[92],SSFSSFSHF,SHF,SSF,[93]SSF,SSF[94]5.3,,;,,Clostridia[95]5.4,[96],2.5,3.4[97]SSF20(2.5g/L),,8%,50%,SSF[98],,SE,,,[99],[100]6,,,,,,,[101][102],7(NREL)NRELIogenIITDelhiNREL#∃(DOEBioethanolProgram)NREL(1999)[65],(190!10min),(),,ZMobilis(30!),7d/,,,0.395,,(55!),,,0.248NRELNovozymes,1.320.079,Genencor0.026~0.053[103]Iogen,200340t/d(),Iogen,12~15kt/a(3~4)%106L/a,0.24/L[1]IogenSE,[104],SHFpH=5,50!5~7d,1122.,Iogen,,,[105]IITDelhi[65],70%,,CUtilis()(170!30min),50%(76%)SSFSSFTReesiAWentii-CAcidothermophilumSSF,,0.544/L8,[106],,29%,50%,(57%)[107],,Hamelinck,,35%,60%,48%68%[108],,[109]:,[110][111];,,,25%30%~36%[112]Wilkening[113](CH4[114]),[115][116][117][118][119][120],,[121];,,;,[122]SE,,90%Ligno,[123,124]PureVision[125],SE,,9,,,,:(1),,,(2),95%[126](3),,,[127]1..,2006,(4):26~272..,2006,11(1):106~1203NagataY.AlcoholFermentationfromConstructionWaste.JJapInsEnergy,2005,84(4):290~2924OkudaN,NomuraT,SatoM.AlcoholManufacturefromWasteBuildingMaterials.JpnKokaiTokkyoKoho,JP2004337099.20045OkudaN,SatoM,MiwaH,eta.lManufactureofAlcoholand113PETROCHEMICALTECHNOLOGY200736OrganicAcidfromWasteBuildingMateria.lJpnKokaiTokkyoKoho,JP2004187650.20046JudgeTimothyK.TheOrangeRecyclingandEthanolProductionFacility:BiomassConversionTechnologyinaPublicPrivatePartnership.In:ProceedingsfromWASTECON2002,SWANA∀sAnnualInternationalSolidWasteExposition,40th,UnitedStates:SilverSpring,Md,2002.343~3447MtuiG,NakamuraY.BioconversionofLignocellulosicWastefromSelectedDumpingSitesinDaresSalaam,Tanzania.Biodegradation,2005,16(6):493~4998LissensG,KlinkeH,VerstraeteW,eta.lWetOxidationTreatmentofOrganicHouseholdWasteEnrichedwithWheatStrawforSimultaneousSaccharificationandFermentationintoEthano.lEnvironTechnol,2004,25(6):647~6559WebsterDJ.CESOxyNolAProvenWaste-to-Ethano