生物质热解制燃料油及化学品的工艺技术研究进展

©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(1.,100080;2.,430073):()-,,4,:;;;:TK6;TQ033:A:0253-4320(2006)04-0010-05AdvancesinstudyontechnologiesoffastpyrolysisofbiomassforliquidfuelsandchemicalsproductionYANGChang2yan1,2,LUChang2bo1,LUXue2song1,YAOJian2zhong1,LINWei2gang1(1.MultiphaseReactionLaboratory,InstituteofProcessEngineering,ChineseAcademyofSciences,Beijing100080,China;2.HubeiKeyLaboratoryofNovelReactor&GreenChemicalTechnology,SchoolofChemicalEngineering&Pharmacy,WuhanInstituteofTechnology,Wuhan430073,China)Abstract:Fromtheviewpointofyieldandqualityofbio2oil,thekeytechnologiesoffastpyrolysisofbiomassforproducingliquidfuelsandchemicalsareintroduced,theresearchstatusandthedifficultiesoftheseconventionaltechniquessuchasfastpyrolyticreactor,feeder,gas2solidfastseparatorandquencherareanalyzed.Anewtechnologyoffastpyrolysisofbiomass,namelyRotatingSievePlatepyrolysissystemisproposedandintroduced.Inaddition,fourprocessesofbiomasspyrolysisforproducingliquidfuelsandchemicalsareanalyzedandtheshortcomingsoftheseprocessesarepointedout.Anewprocess,whichisacombinationofsteam2explosion,solid2statefermentationandfastpyrolysis,isproposedtoo.Keywords:biomass;liquidfuels;chemicals;fastpyrolysis:2005-11-15:(973)(2004CB719700);863(2003AA514023);(20221603):(1969-),,,,,010-62572591,[e-mail]20,,,,[1-2](1215MJ/kg)60%75%1620MJ/kg,[3-4](102104K/s),(3s)(400650),,,2070,,,01Apr.2006264ModernChemicalIndustry20064©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(35%45%)(pH23),[3,5],,11111980,,,:([6-8])[6]()[6]([6,8-9][6][10])[11][12],,;;,,;,,,,;,,,;,,112,,,,,[13][13][13][13-15](9)2005,400,4,:(1),,(2),(3),(4),[1].:[M].:,1987:582.[2]ZengAnping,HannoBiebl.Bulkchemicalsfrombiotechnology:Thecaseof1,32propanediolproductionandthenewtrends[J].AdvancesinBio2chemicalEngineering,2002,74:240-258.[3],,,.[J].,2004,32(3):297-300.1120064:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[7-9,13,16][17][18][19]80%90%[13,16],99%[17-19],,,(),,,,,,,[17]-[20][19],99%-,,114,,,,[21][6,22-23][19][6,22-23],,,,,;,,,,,,,,200300,60100,60100,;,510,,,[20],,(),,115,[19],1,,,;,21264©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(60100)(510),,,,:,;,;,,,2s,30s,45050090%,56%2,[24-25],[12,26-27][28][29](35%45%)(pH23)(1618MJ/kg),,,,,,(),,,,331,,(),CH,2224MJ/kg3120064:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.()/%/MJkg-1pH()5065,1617210315,6070,1617310315,,1718,5622243183(1),(2),,(3),,,[1],,,.[J].,2002,21(8):13-17.[2],.[M].:,2003.[3]OasmaaA,CzernikS.Fueloilqualityofbiomasspyrolysisoils2stateoftheartfortheendusers[J].EnergyandFuels,1999,13(4):914-921.[4].[J].,2003,23(9):13-16,18.[5],,,.[C]//2002,:,2002:136-143.[6]BridgwaterAV,PeacockeGVC.Fastpyrolysisprocessesforbiomass[J].RenewableandSustainableEnergyReviews,2000,4(1):1-73.[7],.[J].,1997,28(4):307-311.[8],,,.[J].,2002(2):1-5.[9],,,.[J].:,2001,27(6):666-668.[10]AguadoR,OlazarM,JoseM,etal.Pyrolysisofsawdustinaconicalspoutedbedreactor:Yieldsandproductcomposition[J].IndEngChemRes,2000,39(6):1925-1933.[11]Krieger2BrockettB.Microwavepyrolysisofbiomass[J].ResearchonChemicalIntermediates,1994,20(1):39.[12],,,.[J].,2001,3(4):63-67.[13].[M]:5.:,1989.[14],,,.[J].,1999,28(5):19-23.[15],,,.[J].,2004,117(5):41-43.[16],,,.[J].,1999,14(3):193-194,199.[17].:,1390915A[P].2002-06-07.[18],,.[J].:,2000,19(2):214-218.[19].:,200510011104.3[P].2005-01-11.[20],,.[J].,2002,2(1):12-16.[21].:,2504273Y[P].2001-11-01[22],,,.[J].,1999(5):17-19.[23].:,1385508A[P].2002-05-22.[24]HayesRD.Biomasspyrolysistechnologyandproducts:ACanadianviewpoint[C]//SoltesJ,MilneTA.Pyrolysisoilsfrombiomass,ACSsymposiumseries:376,WashingtonDC:AmericanChemicalSociety,1988:8-15.[25]CzernikS,ScahillJ,DieboldJ.Productionofliquidfuelbyfastpyrolysisofbiomass[J].JournalofSolarEnergyEngineering2TransactionsoftheASME,1995,117(1):2-6.[26],,,.[J].,2000,21(4):434-437.(16)41264©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[7],,:2050,113%,,,,400t/a(CSTR)(PFR)2[8]:80%,2CSTR,2:,,,,,11,M.J.Haas[9],,,50%,0111/kg,(01480157/kg),,,[10]:,,,()()(),,,[11],2,,[12],,,,211,(Pseudomonasfluorescens)(Candidacylindracea)(14)[27]GrayMR,CorcoranWH,GavalasGR.Pyrolysisofawood2derivedmaterialeffectsofmoistureandashcontent[J].IndEngChemProcessDesDev,1985,24(4):646-651.[28]BrownRC,RadleinD,PiskorzJ.Pretreatmentprocessestoincreasepy2rolyticyieldoflevoglucosanfromherbaceousfeedstocks[C]//BozellJJ.ACSSymposiumSeries:784,WashingtonDC:AmericanChemicalSoci2ety,2001:123-132.[29]SoKS,BrownRC.Economicanalysisofselectedlignocellulose2to2ethanolconversiontechnologies[J].AppliedBiochemistryandBiotech2nology,1999,77/78/79:633-640.61264