确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.白炭黑在绿色轮胎中的应用ApplicationofsilicainGreenTireQ&C介绍Q&Cprofile结论Conclusion确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.含量,%Silica(drybasis)90-9398BET/CTAB1.0-1.21.0-1.1,2.0-2.4邻苯二甲酸二丁酯吸收值,cm2/gDBP,cm2/g2-3.53-3.5初生粒子的粒径Diameterofelementaryparticle10~30nm≥45nm团聚体的粒径Diameterofaggregates30~80nm0.3~30um凝胶含量Gelcontent120粒/10g15-25粒/10g分散度,%Dispersion,%70-8085以上确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.(logD),ml/gNewsilHD165MPNewsilHD165GR团聚体内部孔隙体积intra-voidvolumeofaggregates团聚体间孔隙体积inter-voidvolumeofaggregates团聚体间孔隙体积inter-voidvolumeofaggregates孔径Poresize,nm白炭黑粒子Silicaparticle产品发展Productdevelopment确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.分散性:传统-高分散Dispersibility:Conventionalvs.HDSilicaGranulometryafterUltrasonicdisruptionTEMinrubbercompound产品发展Productdevelopment确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.沉淀法白炭黑,起源于德国;1948年工业化生产;1970S德国深入研究了白炭黑在轮胎中的应用,1993年米其林推出“绿色轮胎”,推动了白炭黑在轮胎行业的迅猛发展。全球白炭黑消耗量,万tSilicaConsumptionoftheworld,×104tPrecipitatedsilica,originatedinGermanyandstartedindustrialproductionin1948.TheresearchofsilicaapplicationIntirewasstartedin1970S,Michelinlaunchedfirst-generationsilicatreadenvironmentalprotectioncalledGreenTirein1993,andpromotedtherapiddevelopmentofsilicaintireindustry确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.×104t国外白炭黑70%用于橡胶工业,特别是绿色轮胎。全球主要的白炭黑供应商有Evonik、Rhodia、Q&C、J.MHuber、PPG等。市场分析Marketanalysis70%ofsilicaareusedinrubberindustryabroad,especiallyinGreenTire.Evonik、Rhodia、Q&C、J.MHuber、PPGetalaregloballeadingvendorsinsilica.确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.年,我国建立第一套白炭黑生产装置,历经半个世纪的发展,工艺技术和应用技术日渐成熟,Q&C自主研发的低聚高分散白炭黑已达到国际水平,促进了国内白炭黑在轮胎行业的迅速发展。中国白炭黑产量及消耗量,万tSilicaProduction&ConsumptionofChina,×104t市场分析MarketanalysisThefirstsilicaplantofChinawassetupin1958.Theprocessingandapplicationtechnologymaturedinpasthalfacentury.LPS/HDSofQ&Chasreachedtheinternationallevel,andpromotestherapiddevelopmentofsilicaintireindustry确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.年国内外白炭黑消费情况,%2011consumptionofsilicadomesticandoverseas,%市场分析Marketanalysis确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.概况Q&CprofilePosition确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.、5生产线WuxiNo.4、5stproductionline安徽NO.1、2生产线AnhuiNo.1、2stproductionline确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.年产3万吨30000tcapacity/yearQ&C产能发展Capacityofdevelopment2013.0920152020年产7万吨70000tcapacity/year年产18万吨180000tcapacity/year年产25万吨250000tcapacity/year确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.米其林:白炭黑填充绿色轮胎Michelin:GreenTirefilledwithsilica横滨:橘油配方轮胎Yokohama:tireswithorangeoilformulatire邓禄普:ENR技术Dunlop:ENRtechnology韩泰:静音轮胎Hankook:silenttire节能(Energyconservation)安全(Safety)环保(Environmentalprotection)确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.℃,TanδAbrasionresistance60℃,TanδWetgrip0℃,TanδSilica魔幻三角Bizarretriangle确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.轮胎性能Tireproperties确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.带束层/胎体Belt/carcassTBR胎面TBRtreadPCR胎面PCRtread撕裂性Tearresistance抗崩花Chunkresistance滚动阻力Rollingresistance抗湿滑性Wetskidresistance增粘Improveadhesion滞后损失Hysteresis确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.高分散白炭黑(HDS)Si-69、Si-75、NXTSSBR/BR滚动阻力降低20%(F级)Rollingresistancedecreased20%(F)抗湿滑性好Goodwetskidresistance粘度高、难加工Highviscosity&difficulttoprocess耐磨性差Badwearresistance30-40phr传统白炭黑(CS)Si-69SSBR滚动阻力降低35%(B级)Rollingresistancedecreased35%(B)抗湿滑性好Goodwetskidresistance粘度低、易加工Highviscosity&difficulttoprocess耐磨性变化不大Wearresistance轿车胎PCR初始Initial目前Now确成硅化学股份有限公司QuechenSiliconChemicalCo.,Ltd.