橡胶工业环保和节能问题的思考_一_

34220072WorldRubberIndustryVol.34No.2:44~49Feb.2007()谢忠麟(北京橡胶工业研究设计院,北京100039):从实际出发,全面分析了我国橡胶行业在环保和节能方面的现状和面临的问题,与发达国家的差距,提出了切实可行的改进措施:环保;毒性;有害物质;节能:TQ330.9:C:16718232(2007)02004406:(1941),,,(EV),200671,RoHS,,,,,,,[1~4],1环保:,1.1,,,1.1.1,,,(EEC)(EC),(Regulations)(Directive)(Decisions)(Recommendationsandavice),(EUD):!EUD67548EEC,;∀EUD76769EEC,(RoHS);#EUD9462EC,,;∃EUD200053EC,(ELV);%EUD200295EC,(EEERoHS),200671&EUD2003113EC,,∋(TRGS552TRGS615TRGS905,∋(,(OECD)GLP(GoodLaboratoryPractice),1.1.2,(),1(IARC)1mg)kg-1()(Pb)**EUD67548EECEUD76769EECEUD200053ECEUD200295EC1000();();(LMDLDDLPD);();()(Cd)**100;(CEDCPD);();();();(Hg)**1000[()];()[Cr(VI)]**1000();;;()*EUD67548EEC[Pb+Cd+Hg+Cr(VI)]:100(Ni)EUD9462EECEUD76769EEC1000;NBC(As)100(PBB)**(PBDE)**EUD76769EECEUD200295ECEUD200311EC10001000()(PAHs)**,16EUD67548EECEUCOM2004(98)30s:(a)20,16PAHs200;30s:(a)1.16PAHs20(,);(SBR1712);;;;;)45)342.()()mg)kg-1()*,24EUD200261EC∋OekoTexStandard100((200220042005)30()(,)();PU(4,4∗)2()EUD67548EECEUD76769EEC100DA4100BLE100NTRGS552TRGS615TRGS905;EUD9311EEC;∋((20010227)N(DTDM)(TMTDBZ)(NBC)(NA)*EUD76769EECEUD83478EEC1000;()()*EUD67548EEC∋GefsoffV(:0.1:1000*(Mortrelprotocol)+ECRegulation20372000(R11R12R22)PU(PCB)*EUD76769EECEUD2002371ECEUD2006199EC,()(Cl3)*∋(*(C10~13)EUD76769EECEUD67548EECEUD76769EEC5EUD67548EEC,)46)2007()mg)kg-1()[(TBT)(TPT)]*EUD67548EEC1000,()!EUD76769EEC∀EUD2003113EC1000,,(DBP)(2)-DEHP(DOP);EUD67548EEC:5()PVCCRSBRNBR:1)***,**;2)1mgkg-1=1ppm=1,10-63),1.1.31.1.3.1,(2),2mg)kg-1(−)GBT381592.370500-1400.----GBT349483.-12002000-.-200500-.---5000GBT244992.1100-500HGT252593,(,NBC),(3),,2005,[5],()[4[6]()[7,8]],,)47)342.()3ETAD*mg)kg-1(Hg)(Cd)(Se)(Sb)(As)(Pb)(Cr)(Ba)420205050100100100(Ag)(Ni)(Sn)(Cu)(Co)(Mn)(Zn)(Fe)100200250250500100015002500*ETAD+ELVEEERoHS200371200671,,(1)TCY(2,4,6)CaMg(),BaCO34mg)kg-1AsBaCdCoCrCuFeHgMnNiPbSbSnZn----24.826.46265.23-9.248.33---15.74-----7.835.32-0.79----24.33-----11--24-34--44101090---19-3--19--1090,XL21(2,3)Ca(OH)2,NA22Pb3O4,;(2)(CSM)(),(CM)CSM,CM(3),+++TPX(41)(4)(220250252),(6000EF),1.1.3.2(1),(PBB)(PBDE),EUD200295EC(EEERoHS)200671,(PBB)(PBDE),,,,20051013,200295EC,,,+++A,,()1.1.3.3(PAHs)(PAHs),PAHs16(5),PAH(a),,PAHsPAHs?,,,)48)2007,516PAHsCASNo.CASNo.185018956553(a)22089681021801938332911205992(b)48673712207089(k)5850181350328(a)612012714193395(1,2,3Cd)72064401553703(a,h)812900016191242(ghi):1)CASNo.+CA();2)+Acenathylene,+Acenathene.,PAHs,,PAHs,,PAHs,()[:]:2006101320071.2,,1.2,,20074000~5000,20072008,20004000,2000~3000500,5,(梁金兰)2008,340460,,6,(扬子江)50%2006,Flexsys50%Flexsys,1000,20056PRW,20061219(钱伯章)MRFMRF,2580~700,340~50,(Puducher)(Arakkonam)10,(Medhak)20~30,2006MRF22%,4.65,,,65(扬子江))49)342.()