矿物原料基础课程8

11://[SiO4]4-[BO3]3-[PO4]3-[WO4]2-[CrO4]2-[SO4]2-[CO3]3-[NO3]1-[AsO4]3-[VO4]3-[MoO4]2-4Ø[CO3]2-1001.7%ØØFeMgMnZnCuThU35ØCa2+Mg2+Fe2+Mn2+Zn2+Pb2+TR3+Ø[CO3]2-(OH)-F-Cl-(OH)-ØØR2+Ca2+Mg2+0.106nm0.078nmCaMg[CO3]261)[CO3]2-C4+C—O[CO3]2-(0.255nm)2)[CO3]2-R2+Ca2+Mg2+Fe2+Mn2+Ba2+Sr2+Pb2+Zn2+3)Cu2+Zn2+(OH)-Cu2[CO3](OH)2Cu3[CO3]2(OH)24)Na+Na2[CO3]·10H2O47qqqq3CuMnFeCoUq8•••Co2+Zn2+Mg2+…Ba2+()(Ca2+)5910q:Ca[CO3]q:NaClNaClC-3Oq:{1010}{0001}{0112}{0221}{2131}01120001q:(icelandspar).3,{1011}q:3HClCa[CO3](Calcite)61112713Fluorite.Location:Spain14••••815•600CaO:•8008501000120010001200CO2•44CO2101516Ø917q:Ca[CO3]q:,Ca2+(Ca2+)Ca2+(Ca2+)Ca2+9q:(110)q:3.5~4{010}2.94HClq:()Ca[CO3](Aragonite)18q:CaMg[CO3]2q:q:{1011}(0001)(10-10)(11-20)q:3.5~4{1011}2.86q:HClCaMg[CO3]2(Dolomite)31019:20DolomiteLocation:Indiana,USAFluoriteonQuartz1121Mg22q:Cu2[CO3](OH)2q:Cu2+O2-(OH)-cC4+O2-[CO3]2-q:(100)q:3.5~4{201}{010}3.9~4.0q:Cu2[CO3](OH)2(Malachite)1223q:Cu3[CO3]2(OH)2q:q:q:3.5-43.7-3.9q:Cu3[CO3]2(OH)2(Azurite)24ØSS6+O2-[SO4]2-1850.1%Ø20Ca2+Mg2+K+Na+Ba2+Sr2+Pb2+Fe3+Al3+Cu2+(OH)-F-Cl-O2-(CO3)2-(OH)-1325Ø·Ø26q:Ba[SO4]SrCaq:Ba2+[SO4]2-O2-12O2-S6+Ba2+4q:{001}q:3~3.5{001}{210}{010}4.5q:Ba[SO4](Barite)1427ØBaØØØxxØØ28q:Ca[SO4]·2H2Oq:Ca2+[SO4]2-H2OCa2+8[SO4]2-2H2OO2-q:{010}(100)(101)()q:2{010}{100}{011}2.30~2.37q:{010}Ca[SO4]·2H2O(Gypsum)1529•301631321733q:Ca[SO4]q:,(100)(010)Ca2+[SO4]2-(001)[SO4]2-Ca2+[SO4]2-O2-8O2-S6+Ca2+3q:q:3~3.5{010}{100}{001}2.9~3.0q:Ca[SO4](Anhydrite)34•—1835ØØØØØ36q:Ca[WO4]q:,Ca2+[WO4]2-ccCa2+[WO4]2-[WO4]2-cCa2+[WO4]2-O2-8q:{112}q:4.5{101}6.1Xq:Ca[WO4](Scheelite)1937q:Ca5[PO4]3(F,Cl,OH)q:,Ca2+[PO4]8-[PO4]8-O2-Ca2+9q:{0001}q:5{0001}2.9~3.2q:Ca5[PO4]3(F,Cl,OH)(Apatite)38abCa+2F-1O-2P+52039q:Cu(Al,Fe)6[PO4]4(OH)8·4H2Oq:q::q:5~6{001}{010}2.6~2.8q:Cu(Al,Fe)6[PO4]4(OH)8·4H2O(Turquoise)40q:Pb[CrO4]AgZnq:q:c{110}{401}q:2.5~3.0{110}5.99HClq:Pb[CrO4](Crocoite)2141q:Pb[MoO4]q:q:,(001)(100)q:3.0{101}6.5~7.0q:,,Pb[MoO4](Wulfenite)42q:Na2[B4O5(OH)4]·8H2Oq:H2ONa+[B4O5(OH)4]2-c{100}q:{100}cq:{100}2~2.5q:Na2[B4O5(OH)4]·8H2O(Borax)22431.2.3.[SiO4]4-,[Si2O7]6-[Si2O8]8-4.AlSi5.Al(Na[AlSiO4])(Al2[SiO4]F2)KAl2[AlSi3O10](OH)2)Al6.447.8.2:11:19.10.11.12.13.14.15.23451846qqqqqq2447FClBrI100qq48qAXAX2F-Cl-Br-I-VIIA,q2549CaF2NaClKCl{{50•ØF-1525Ø2651q:CaF2CaTR:Ca=1:6q:48q:q:4{111}3.18CaF2(fluorite)52v{100}{111}{110}vv{111}vv{111}H4275354285556295758305960316162ØHFNa3AlF6ØØØ10103mm3ØU235ØØF3263q:Na3AlF6q:560q:{110}q:1.3382~32.97q:Na3AlF6Cryolite64q:NaClq:6q:{100}(hoppercrystal)q:2{100}2.1~2.2NaCl(halite)336566••{100}•{100}H22.53467•NaHClNa68356970367172