2010年煤制油大会-中科合成油

中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaCTLDevelopment:FromfundamentaltoindustrialpracticesSynfuelsChinaLtD.NationalEngineeringLaboratoryofIndirectCoalLiquefaction(NDRC)StateKeyLaboratoryofCoalConversion(MOST)InstituteofCoalChemistry(CAS)Building18,MinzhuangRD3,HaidianDistrict,Beijing,ChinaTel/Fax:[phone]Email:[e-mail]中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaPhilosophicalremarksCoalisonlyreliableresourcesafteroilSolar/windenergyisonlyreliableenergyresourcesafterfossilfuelsBiomassisonlycarbonresourcesforchemicalsafterfossilfuels50-60yeardevelopmentPetroleumoilsupportedpetroleumrefiningandchemicaltechnologyCoalÎpowergenration50-60yeardevelopmentCoal&oilsupportedcoalconversionandcoalchemicaltechnologyheavyoilrefiningbiomasstechnologyemergingnewenergy50-60yeardevelopmentandpracticesSolarenergy/biomasssupportedenergytechnologyandsystembiomasssupportedchemicalsystemfullrecyclingsystemsupportedbysolarenergyWeareinthebeginningoftheessentialrevolutionoftheenergysystemthatmustbecompletedintheaboutnext100year.中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaPhilosophicalremarksCTLisarouteforfuels/chemicalsinthetransitionalperiod(±50years)HeavyoilmayjoinCTLrouteforincreasingefficiencyCTLsystemwillfinallyturntobiomassfeedstocktodeliverchemicalsRefineriesPetroleum-chemicalsectorfuelsChemicalsoilC/BTLblockHeavyoilCoal/gasbiomassFeedstockchangeÎtechnologydemandsWedevelopthekindtechnologytotransfercoal/biomassintofinalproductswithasmuchaspossibleuseoftheresultsfromoil-basedtechnologysystem中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaSynfuelsChinashareholders:YitaiGroup40.0%SynfuelsStaff32.2%*ICC-CAS12.94%LuanGroup8%XuzhouMing4%ShenhuaGroup2%Linksun0.86%Totalcapital:1.0billionRMBSynfuelsChinaHistory1980-1997:CTLresearchanddevelopmentinInstituteofCoalChemistry(CAS)1997-2005:PilotplanttestofslurryFischer-Tropschsynthesis(ICC-CAS)2006:CASteam+facilityÎSynfuelsChinaÎTechnologytransfer2009:Three4000b/ddemonstrationplantcommissioningÎHTSFTP2010:Summarizingthedemonstrationprojects,initializing80000b/dprojectsSynfuelsChinaorganization(Taiyuan)SynfuelsChinaResearchTaiyuan/BeijingInnerMongoliaSynfuelsChinaEngineeringLtDBeijingSynfuelsChinaCatalystsLtDAnhuiThreeinvestmentprojectsforfinechemicals,CTLequipmentmanufactureandCTLprojectdevelopment中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaSynfuelsChinaResearchProfessors12Associateprofessors15Researchers/lab-staff55Ph.Dstudents25MSstudents10•Theoreticalcatalysis•Fischer-Tropschsynthesis•Hydrogenation•Engineeringfundamentals•Analytical&instruments•Coalchemistry•MaterialsynthesisFundamentalresearchLaboratorydevelopmentProductdevelopment&evaluationBasicdata中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaSynfuelsChinaEngineeringLtDSiteserviceengineers25senior(8)inchargeofpilotplantrunningProjectmanagementteam50Designteam130Fullequippedfacilityforprojectmanagementandengineeringdesign&in-housedevelopment•PDP/BasicEngineeringDesign•Plantdesigntodetailedengineering•VesseldesignincludingF-Treactordesign•EPCtoLSTK•OperationtrainingforCTLprojects•Projectexecutionmanagement中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaSynfuelsChinaCatalystLtDStaff80Facilities2000ton/acatalystproduction5000tonmetalsaltproductionPurewaterproductionAdditiveproductionEquipmentmanufactureInnerMongoliaJointventureformanufacturingCTLequipmentLargestvesselsupto12mID(inhouse)中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaC/G/BTLCore:Fischer-TropschSynthesiszFischer-Tropschsynthesispractices‡Sasoleffortssince1950¾LTFT-Fixedbed,ironascatalystat230-240oCheavyproductdominant1950-¾HTFT-Fluidezed,ironascatalystat320-350oClightolefinsdominant1950-¾LTFT-Slurry,ironascatalystat230-240oCheavyproductdominant1993-¾LTFT-Slurry,cobaltascatalystat190-220oCheavyproductdominant2006-‡Shelleffortssince1990¾LTFT-Fixedbedcobaltascatalystat190-220oCheavyproductdominant1993-‡SynfuelsChina¾LTFTprocess(excludedforcommercialization),ironcatalyst1980-2005¾HTSFTPprocessdemonstrationscale(4000b/d),ironcatalystcommissionedin2009¾HTSFTPcommercialscaleplanned(80000-90000b/d),ironcatalyst,(2011-)‡Severalotherorganizations¾LTFT–typetechnologydevelopmentuptopilotplantHistorically,HTFTisanoptionforlargescaleproduction,butithaslowenergyefficiencyduetoselectivityandtheproductrecoveryfromgaseousstream.ThenewtechnologythusfocusesonlowertemperatureF-Tsynthesisusingtypicallyslurrysystemforlargerscale.中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaC/G/BTLCore:Fischer-TropschSynthesiszFischer-Tropschsynthesisfundamentals‡Chemicalreactions2222COkJ/mol41.3-HHCOOHCO=Δ+→+-)(-CHkJ/mol-165HOnH-)n(-CH2nHnCO2222=Δ+→+MaterialEnergyreleaseTheoreticalPracticalfactorof0.85~0.93factorof0.85~1.3208.33g/Nm3(CO+H2)2434.84-2075.51=359.33kcal/Nm3(CO+H2)Productoilsteam中科合成油技术有限公司中科合成油技术有限公司SynfuelsChinaSynfuelsChinaC/G/BTLCore:Fischer-TropschSynthesiszFischer-Tropschsynthesisfundamentals‡CatalysisActivity500-6000Nm3(CO+H2)/hconvertedon1m3catalystSelectivityC1-21.5~25%;C3-43~60%;C5+15~95.5%StabilityIronshorterthan3000hours,Cobaltlongerthan4000hoursMe