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0920513820092013518-I-,,-II-Nitrogen-containingflameretardantepoxyresinisconsistentwithhalogen-free,lowtoxicity,lowsmoke,andenvironmentaltrends,andhasbecomethemainstreamoftoday'sfireretardantdevelopmentofthefield.Comparedtoaddaflameretardantepoxyresin,flame-retardanteffectofthereactiveflameretardantepoxyresinshowsmoredurable,flame-retardantefficiency.Thesignificance,thedevelopmentintheworldandthesituationofnitrogen-containingflameretardantepoxyresinarebrieflyintroduced,andphosphorusflameretardantshavebeenclassifiedandalsothemechanismofphosphorusflame-retardantindetailsisstatedinthearticle.Thearticlefocusesonthesynthesismethodtosynthesizenewphosphorus-containingepoxyresinthroughthesynthesisofnitrogen-containingepoxymonomersandnitrogencuringagent.Finally,thenitrogen-containingflameretardantepoxyresinislookedaheadto.nitrogen;flame-retardant;epoxyresin;researchprogressResearchprogressofnitrogen-containingflameretardantepoxyresinAbstractKeywords:Abstract123..........................................................................................................................................I.........................................................................................................................................II................................................................................................................................11.1......................................................................................11.2.................................................................................21.2.1...............................................................................21.2.2...............................................................................21.3...............................................................................................................31.3.1...................................................................................................31.3.2...................................................................................................31.4......................................................................................................5..................................................................................62.1..........................................................................................62.2..............................................................................................................62.2.1....................................................................................................62.2.2........................................................................................................82.3................................................................................................13...............................................................................................15.......................................................................................................................................16.......................................................................................................................................17.......................................................................................................................................19()-1-11.1(EP)(LOI)19.8[1-2][3-4]()-2-1.21.2.1A(PBDF)[5-6][7-8]AA1-1E511-1AWU[9]/DDM1601.2.2[10]NHNNNNH2NHH2COHCH3OHCCL()-3-FR-4[11]3%~5%1.31.3.1[12]melammelemmelom[13]1.3.21.3.2.1[14][15]246——MFP1-2FDEDMFPFD()-4-EDUL94V—085027%313.31-2MFP[16]A10G?[17]m—PDA44—(DDM)MeTHPADDMLOI25.2V—2Wu[18]20084——Tg1414OHH2CHNNNNNHCH2NHCH2OHOH()-5-4—DDSTg=131TG5%328315DDS1.3.2.2[7]AZNaOHDGEAZ1-2DSCTGAUL-94A80043.55%UL-94V-01-3DGEAZLiuMPGEDDMDICY//LOI38.0[19]1.4()-6-22.12.22.2.12.2.1.1AzomethineAzomethine[20]NaOHDGEAZ()-7-A[21]2-1DGEAZ1[22]250ml12.2g0.1mol20ml1.5h5.41g0.05mol30ml4hAZ1500ml7.95gAZ10.25mol46.25g0.5mol180ml1.5h48%4.17g4hDGEAZ12-1()-8-2-2DGEAZ2250ml12.21g0.1mol11.03g0.1mol100ml10h-11AZ2DGEAZ110.65gAZ20.05mol92.5g1.0mol10ml1.5h48%8.33g2hDGEAZ22-22.2.1.2WQF-410FT-IR,KBrUNITY-200NMR2.2.22.2.2.12,4,6—[N-(-2)]-1,3,5—[23]300ml33.9g12g()-9-60%50ml5h18.4g150ml12h—2,4,6—[N-(-2)]-1,3,5—2-62-42,4,6—[N-(-2)]-1,3,5—abA24401620—32EPLOI50%60—702h40%—50%8010min1305min60Kg/cm21701h2008h7.9×1013?/cm4.93200500h49.3Kg/mm2V-02.2.2.2[24]pH=97530min9524hNaOHMFP12-5NNNN(CH2)5CON(CH2)5CONC(H2C)5OMFP()-10-2-4MFP1MPFPFpH=8.5754050minMFPFpH=8.59095PFMF5hMFP22-52-5MFP22.2.2.3,,,,:()-11-,0.81,,,,,,,100,,lh,4h1202h1201802h,,,(),1104h,1702h,,10141015O·m:,,,,,,,()2.2.2.4(()-12-),,,,2,4-M[24],:2-5(a)+R'CH2R'(b)+(c)2-5,.,,2,4-EMI,R3NCONCNCNCRRROOORNCONCH2ONCHROCOR'CHCH2ONCNCNCORRROOH2CCHNRR'OCO()-13-,PISPOXI/E1.22,2.2,1H·HO·23,,WU[9](TPSO)CNE200,()-14-PF5110LOI27,27.7%MPFN1931,Tg23.6%,70018.2%LOIMPFN,,LOI()-15-3Intel“”IntelHalogenFreeSymposiuma,bcd()-16-1.2.,3.N-CN()-17-[1],.[M].:,2004,219-220.[2]LuSY,HamertonI.Recentdevelopmentsinthechemistryofhalogen-freeflameretardantpolymers.[J]ProgPolymSci,2002,27(8):1661-1712.[3].[J].2006,34(6)78-82..[4](I)[