学院 医学院系班级 留学生06临床医学班 学号 姓名NAME.

扬州大学试题纸（2006—2007学年第一学期）医学院课程/COURSE医用有机化学（A）卷班（年）级留学生06临床医学班学号姓名/NAME题号一二三四五总分得分PartINamethefollowingcompounds1、2,5-dimethylhexane2、(Z)-4-ethyl-2,3-dimethyl-3-heptene3、4,5-dimethyl-1-cyclohexene4、propylbenzene学院医学院系班级留学生06临床医学班学号姓名/NAME-----------------------------------------------------------------------------------------装--------------------------------订-------------------------------线-------------------------------------------------------------------(CH3)2CHCH2CH2CH(CH3)2C=CCH3(CH3)2CHCH2CH3CH2CH2CH3CH2CH2CH35、3，3-dimethyl-2-butanone6、1-hydroxy-5-nitrobenzoicacid7、m-ethoxybenzoylchloride8、Cyclopentanecarboxamide9、ethylacetate10、ClCH3Cltrans-1,2-dichloro-1-methylcyclobutane11、(CH3)3CCCH3OHOCOOHNO2COClOC2H5CONH2CH3CH2CO2CH2CH5OHCl1-phenyl-5-chloro-1-pentanol12、Dibutylether13m-methylphenol144-phenyl-3-butenol154-methyl-2-cyclohexen-1-ol(CH3CH2CH2CH2)2OOHCH3CH=CHCHCH3OHOHCH313、1、4-methyl-4-phenyl-3-oxohexanoicacid2、1-hydroxy-5-nitrobenzoicacid3、2,5-dimethylhexanedioicacid(2,5-dimethyladipicacid)4、（R）-2-hydroxypropionicacid5、3-hydroxycyclopentanecarboxylicacid6、学院医学院系班级留学生06临床医学班学号姓名/NAME-----------------------------------------------------------------------------------------装--------------------------------订-------------------------------线-------------------------------------------------------------------CH3CCOCH2COOHCH2CH3HOCOOHNO2HOOCCHCH2CH2CHCOOHCH3CH3HOHCOOHCH3OHCOOHCOClOC2H5m-ethoxybenzoylchloride7、cyclopentanecarboxamide8、ethylacetate9、benzoicanhydride1、(R)-1-bromo-1phenylpropaneCH2CH3PhHBr2、(4R,2E)-4-bromo-3-chloro-2-hexeneCONH2CH3CH2CO2CH2CH5COOOCCH2CH3HBrCCClHH3C3、trans-1,2-dichloro-1-methylcyclobutaneClCH3Cl1、2-pentanol2、2,3,4-trimethyl-3-pentanol3、4-methyl-1-cyclopentanol4、1-phenyl-5-chloro-1-pentanol5、6-bromo-3-heptanolCH3CH2CH2CHCH3OHCH3CHCCH(CH3)2OHCH3H3COHH3COHClOHBrOHCH36、4-methyl-2-cyclohexen-1-ol7、1,3-propanediol8、1,2-cyclohexanediol9、4-phenyl-3-butenol10、Ethyl2-chloro-4-nitrophenylether11、Dibutylether12、Isopropylpropylether13、m-methylphenol14、m-ethoxyphenol15、1,3,5-benzenetriolHOCH2CH2CH2OHOHOHCH=CHCHCH3OHOCH2CH3ClNO2(CH3CH2CH2CH2)2OCH3CH2CH2OCH(CH3)2OHCH3OHOC2H5OHHOOH16、2-methoxy-1,4-benzenediol1、2-pentanol2、2,3,4-trimethyl-3-pentanol3、4-methyl-1-cyclopentanol4、1-phenyl-5-chloro-1-pentanol5、6-bromo-3-heptanol6、4-methyl-2-cyclohexen-1-ol7、1,3-propanediolOHOCH3OHCH3CH2CH2CHCH3OHCH3CHCCH(CH3)2OHCH3H3COHH3COHClOHBrOHCH3HOCH2CH2CH2OH8、1,2-cyclohexanediol9、4-phenyl-3-butenol10、Ethyl2-chloro-4-nitrophenylether11、Dibutylether12、Isopropylpropylether13、m-methylphenol14、m-ethoxyphenol15、1,3,5-benzenetriol16、2-methoxy-1,4-benzenediolOHOHCH=CHCHCH3OHOCH2CH3ClNO2(CH3CH2CH2CH2)2OCH3CH2CH2OCH(CH3)2OHCH3OHOC2H5OHHOOHOHOCH3OHPartIIWritethestructuresforthefollowingcompounds.1、2,3-dimethyl-2-penteneCH3C=CCH2CH3CH3CH32、p-dinitrobenzene3、p-hydroxybenzoicacid4、o-aminophenol5、4-ethyl-2-propyloctanoicacidCH3CH2CH2CH2CHCH2CHCOOHCH2CH2CH3CH2CH36、3-chloro-3-ethyl-2,4-dimethylhexaneCH3CH2CCH(CH2CH3)CH3ClCH(CH3)27、5-bromo-1,3-cyclohexadiene8、N-phenylacetamideNHCOCH39、p-acetylbenzoicacidCOCH3COOH101,3,5-trichlorocyclohexaneBrClClCl1、(E)-3-hexen-5-ynoicacid2、3-methoxybutyramideCH3CHCH2CONH2OCH33、N-phenylacetamideNHCOCH34、4-ethyl-2-propyloctanoicacidCH3CH2CH2CH2CHCH2CHCOOHCH2CH2CH3CH2CH35、p-acetylbenzoicacidCOCH3COOH1、3-chloro-3-ethyl-2,4-dimethylhexane2、CH3CH2CCH(CH2CH3)CH3ClCH(CH3)2Br5-bromo-1,3-cyclohexadiene3、1,3,5-trichlorocyclohexane4、2-chloro-4-methylpentane1、3-penten-2-ol2、diphenylether3、o-aminophenol4、ethylo-hydroxyphenylketone1、3-penten-2-ol2、diphenylether3、o-aminophenol4、ethylo-hydroxyphenylketoneClClCl(CH3)2CHCH2CHClCH3PartIIIDecidewhetherthefollowingstatementsaretrueorfalse.1、AmongE-3-hexene,Z-3-hexene,2-methyl-2-pentene,1-hexene,and2,3-dimethyl-2-butene,2,3-dimethyl-2-buteneismoststable.(T)2、Configurationalisomerscanbeseparatedandaredifferentcompoundswithdifferentproperties.(T)ListthefollowingcompoundsinthedecreasingorderofsolubilityinwaterEthylmethyletherbutaneisopropanolglycerol3、(F)4、(F)5、6、PartIVChoosethesuitableanswer(s)fromthefourchoicesinthefollowingquestions1.Whichcompound(s)is/arearomatic?(b,d)a.b.c.d.2、Whichcompoundhasthehighestboilingpoint?(c)a.formaldehydeb.ethyletherc.1-butanold.butane3、Themoststableconformationforbuataneis(b)a.gaucheconformation,b.anticonformation,c.eclipsedconformation,d.staggeredconformation4.．Inthefollowing4compounds,whichoneismostacidic?Malonicacid(COOH-C-COOH),2-hydroxypropionicacid,2-chloropropionicacid,propionicacidMalonicacid＞2-hydroxypropionicacid＞2-chloropropionicacid＞propionicacid5．Inthefollowing5compounds,whichoneisthemostacidic?Whichoneistheweakestacidic?2-nitrobutyricacid,3-nitrobutyricacid,4-nitrobutyricacid,butyricacid,2-methylbutyricacid2-nitrobutyricacid＞3-nitrobutyricacid＞4-nitrobutyricacid＞butyricacid＞2-methylbutyricacid6、Inthefollowing4compounds,whichonehasthehighestboilingpoint?Whichoneisthelowestboilingpoint?FormicacidethanoldimethyletherpropaneFormicacid＞ethanol＞dimethylether＞propane1、2、Inthefollowing3compounds,whichoneisthemostacidic?Whichoneisthewe