医药工业废水处理现状与发展

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Pharmaceutical&EngineeringDesign2005,26(3)(400042),,,,1,,,22.1(1);(2)SS,,;(3)COD,20006000mg/L,10011000mg/L,;(4),500;(5)25600C2.22.1.1:4000m3/d2.1.2COD+UASB,:(1),2030g/L;(2),,10kgCOD/(m3.d),1540kgCOD/(m3.d),,(3),,,:,(,),,,,,,,,,,UASBSBR,SBR,(),,SBR,,,,,:(1);14Pharmaceutical&EngineeringDesign2005,26(3)(2),;(3);(4),;(5);(6),;(7),,,SBR2.1.3()112.3,,3,,,,SBR:FeCC,,:Fe22eFe2+:2H++2e2[H]H2()O2+2H2O+4e4OH2(),,,,::[H]Fe2+,,,,,COD,:FeC,,,:,,:Fe2+Fe2+Fe3+,,pH,Fe(OH)2Fe(OH)3,,COD,,BOD5/COD0.060.3,COD30%50%24Pharmaceutical&EngineeringDesign2005,26(3),70%,,,pH(SBR),,BOD/COD0.63,SBRCOD1500mg/L,0.5kgCOD/(kgMLSSd)810h,COD200mg/LGB897821996:10min,,,1mol/L10min,,4:,,90%,,,,5%,,,,,,,COD,BOD,100,,,,,,,,,150200m3,,,COD15000mg/l,,350m3,,20004.1,4.1.1,:,4.1.2:(AF)(AFB)(AAFFB)(UASB)(AFB)4.1.3:COD530kgCOD/m312kgCOD/m3,:kgCODIkW5%3050%COD,4.1.44.1.4.1,,,:,,,,,,,,,,,,,,,,300mg/l,H2S,5000mg/l,,,,4.1.4.2:34Pharmaceutical&EngineeringDesign2005,26(3),,,(30kg/m3.),,,2080UASBAFB,5000m3,1000m3,,4.1.4.3:()COD90%,10002000mg/lCOD,,,,(SS):(1):,,,1:40COD2kg/m3.,70%,,(2):,,(3):,,,,,(4):,,1015m,,,,,,BOD5/COD(0.1),,,COD,NH3NPS,NH3N4.24.2.12::480m3/d;COD24000mg/l,COD2000mg/L;BOD20000mg/l,BOD400mg/L;COD91.7%,COD14.1kg/m3.d;BOC98%,BOD12.58kg/m3.d;64%/d4.2.2:480m3/d,25m3/d;COD45833mg/L,COD2000mg/L,5.6%;4.2kgCOD/m3/d;COD2000mg/L,COD200mg/L;90%,2.1kgCOD/m3.dCOD200mg/L,COD60mg/L;70%,0.3kgCOD/m3.d;COD60mg/l,20mg/l,66.6%4.2.334.34.3.1,29.5%COD23000mg/L,,,,,,,44Pharmaceutical&EngineeringDesign2005,26(3),,,,,90,,,,,6kgCOD/m3.d,94%,9310,95,,,,,96,984.3.2()COD1000013000mg/L,,,,30L,,COD93.9%,COD7.49%kg/m3.d,(UASB),974.3.3,,,BOD,,,4.3.42600,2,,,,,,,,,4.44.4.1,,,,,(1),,(2)pHCODBOD5SS,(3),(4)(5)(6)4.4.2,:4.4.2.1,,,,,510,,COD100mg/L10000mg/L,,,,:,,4.4.2.2,,,?,54Pharmaceutical&EngineeringDesign2005,26(3),,CODBOD5,,,,?,,,,(),,,,,,4.4.2.2.1()(),COD,,,,,,0.5mm/s4.4.2.2.2,COD,,,,,,,,,,,,COD25%,,,,,pH,:pH6(,),30m3/m31,2.55%,COD3000mg/L(),,;COD3000mg/L(),,COD,,COD,,COD,,COD3000mg/L,COD3000mg/L,,,,,COD3000mg/L,,64Pharmaceutical&EngineeringDesign2005,26(3)COD,COD,,COD3000mg/L,,,,4.4.2.2.3,COD3000mg/L,,,,,,,H2S,,910,,,,(20),,,,SBR,SBR,,SBR:,4.4.2.2.4,BOD5,COD250300mg/L?(),,,,,,:(1),,,,(2),,COD(3),,,,,5::,5.1,,,2NaOHHCl(60290)5.2,,50100PPM,20PPM,,,20PPM,474Pharmaceutical&EngineeringDesign2005,26(3)45.2.1COD,(COD,),(),pH5.2.2,SS,pH,,(),,,84Pharmaceutical&EngineeringDesign2005,26(3),:,,,,,,,,,,pH,;;,,,,,,,,,,,,,,,,,,,,,5.2.3,,,,PH,,,,5.2.455.2.4.1pH,,,:,,,,,,,,NaOH,5.2.4.2,(SBR),:,,;,100%,319%;,;;,30%,,SBR(SequencingBatchReactor),,SBR,SBR,,,(SBR),94Pharmaceutical&EngineeringDesign2005,26(3)5.2.4.3(),COD,SBR,,,:,,,,,,,1,,(1,1000),,,,10,,,20%6:,COD3000060000mg/L,,,:67,;,,:200520321305

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