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()JournalofXinyangNormalUniversity17120041(NaturalScienceEdition)Vol.17No.1Jan.20041,2,3(11,464000;21,464200;31,464000):,.,.,.65.:;;:O657131:A:100320972(2004)0120119206(atomicabsorptionspectroscopy,AAS).1955,.,.,.,.1968,Christian[1].,[211],AAS.,AAS.,VB12,240.7nmVB12[12,13].30[14],AAS.,,AAS.,,.,AAS.[15],[16].[1719].,.11.1,.,.,,.,,.[20]1610.:2003209210::(19642),,,,,1911©1995-2006TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.95.0%105.0%,0.03%.[21]HNO3:HClO4(41)SeGeCuZnFeMn6,.CuZnFeMn4,.3CuZnFeMn,SeGe.[22,23](FAAS)10..[24]NaMgCuZnMnCd6.[25,26]10.[27]..,FAAS415[28,29].,,,.[30]CaMgFeCuZn5,CaöMg,CuöZn,CaMgFeCuZn.[31]HNO3HClO4(41)I-V9,CuZnNiCoMnCrMoFeCaMgCdPb12.[32],FAAS,.[33],FAAS(),.,[34]FAAS,CuZnFe.,.,[35][36]7[37].,[38]HNO32HClO4CCuZn10.,CaMgFeZnMn.,[39],HNO3SrCl2CaMg..,,..[40].,,.,,;;95%106%96%105%.,[41]-AAS12,GBW08501.[42]-.AAS:.[43]()CuZnFe.,,..t,HNO3+H2SO4+HClO4,.[44].-[45,46].,.021171()20041©1995-2006TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved..,.[47,48]..,..-[49][50].,.,18LgöL,0.42LgöL,165.,10,94.2%104%.,,.[51][52].(FIA),AAS.FIA-AAS,AAS[8,9,53].,.[54]--,,.0.095LgöL,97.3%103.3%,.[55]APDCöMIBK,-,.3.74%,(3R)3.210-12g,93%99%.1.2,.,,[56]...-,12[56].,,(),.,,(),[57].[58],3FeZn.,Zn,20.26%,Fe13.06%,FeZn,.,[59]Fe.2,..[60],,.,97%101%,1.1%..[61]Zn(SCN)2-4,,,2.910-5molöL.,[53,6264].MnO2B6,-Mn2+,121,:©1995-2006TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.B6[53].,.-pH,AAS[62].10100mgöL(C=0.9992),98.5%101.6%.[63]().,Cu2+Cu+,[64]FI-AAS.Cu+SCN-,,AASCu2+.2100mgöL,97.15%99.5%,100h-1.,,,..,[65].3,,AAS.AAS.,,.,,.,,,.,,AAS:(1)AAS;(2)AAS.,,,;(3)(),,,.:[1]CHRISTIANGD,FELDMANFJ.Determinationofnonmetalsbyatomicabsorptionspectrophotometry[J].AnalChimActa,1968,40(2):1732179.[2]BONDAM,WILLISJB.Enhancementofzirconiumatomicabsorptionbynitrogen2containingcompoundsanditsuseinthedeterminationofammonia[J].AnalChem,1968,40(14):208722089.[3]ROSESA,BOLTZDF.IndirectDeterminationofSulfurDioxidebyAtomicAbsorptionSpectrometryafterPrecipi2tationofLeadSulfate[J].AnalChimActa,1969,44(1):2392241.[4]VARLEYJA,CHINPY.Determinationofwater2solublesulphateinacidicsulphatesoilsbyatomicabsorptionspec2troscopy[J].Analyst,1970,95:5922595.[5]MANAHANSE,KUNKELR.AnAtomicabsorptionanalysismethodforcyanide[J].AnalLett,1973,6(6):5472553.[6],.[J].,1996,16(3):93298.[7],,.(III)[J].,1995,16(4):5362539.[8]YEBRAMC,GALLEGOM.IndirectFlow2injectionDeterminationoftannisinwinsesandteabyatomicabsorptionspectrometry[J].AnalChimActa,1995,308:3572363.[9]LAHUERTZZL,MARTINEZCJ.Contiousflow2injectionatomicabsorptionspectrometricmethodforthedetermina2tionofondansetron[J].AnalChimActa,1995,300:1432148.[10]SARASWATIR,VETTERTW.Determinationofarsenic,seleniumandmercuryinanestuarinesedimentstandardreferencematerialusingflowinjectionandatomicabsorptionspectrometry[J].MikrochimActa,1995,118:1632175.[11]SALEMH,KHEIRA.Aatomicabsorptionspectrometryofflufenamicacid[J].AnalLett,1995,28(10):183321843.[12]DIAZFJ.Determinationofcyanominbyatomicabsorptionspectrophotometrywithapremixair2acetyleneflame[J].AnalChimActa,1972,58:4552458.221171()20041©1995-2006TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.[13]PECKE.TheapplicationofflamelessatomicabsorptiontotheanalysisofvitaminB12[J].AnalLett,1978,11(2):1032117.[14].[M].:,1992.890.[15],,,.[J].,1997,14:59260.[16].[J].,2002,28:34236.[17],.[J].,1999,15:1112113.[18].[J].,2002,17:36238.[19],.[J].,2000,16:76281.[20].[J].,2000,16(1):55257.[21],.[J].,2002,22(5):8472849.[22],,,.10[J].,2002,22(1):1522153.[23],,,.[J].,2003,23(4):7972799.[24],,.[J].,2002,(3):29230.[25],,,.[J].,2002,15(2):1902191.[26],.[J].,2003,16(2):1692171.[27],,,.[J].,2002,15(4):4112412.[28],,.41[J].,2002,22(1):1592160.[29],,.[J].,2002,22(2):3232324.[30],.CaMgFeCuZnCaöMg,CuöZn[J].,2002,22(3):4782479.[31],,,.[J].,2002,22(5):8532855.[32],,,.[J].,2002,22(3):4832484.[33],,,.[J].,2002,34(1):65268.[34],,,.FAAS[J].,2002,19(1):1272130.[35],,.[J].,2001,20(4):87289.[36].[J].,2003,15(4):5672568.[37],,[J]1,2003,23(3):6172618.[38].[J].,2000,20(3):3732375.[39],,,.[J].,2004,24:.[40].2FAAS[J].,2002,21(6):56258.[41],,,.-AAS12[J].,2003,23(1):81283.[42],,.-[J].,2003,23(2):3802382.[43],,,.-[J].,2002,22(5):8562858.[44],,,.-[J].,2001,20(4):90291.321,:©1995-2006TsinghuaTongfangOpticalDiscCo.,Ltd.Allrightsreserved.[45],,.-[J].,2002,(5):50252.[46],,.-[J].,1999,18(6):59261.[47],,,.-[J].,2002,21(1):9212.[48],,,.2[J].,2002,22(1):23227.[49],,,,2[J],,2002,22(6):104524047.[50],,,.--[J].,2002,30(9):114321146.[51]JACKSONSC.Atomicabsorption,atomicemission,andflameemissionspectrometry[J]1AnalChem,1996,68(12):231R2256R.[52],.[J].,1994,14(2):1132120.[53],,,.-B6[J].,1997,25(8):9842984.[54],,,.22[J].,2002,22(6):104321044.[55],,,.[J].,2002,22(5):22224.[56],,.[J].,2002,18(2):1452148.[57],.[J].,2002,30(7):8902890.[58],,.FeZn[J].,2002,19(3):3322334.[59],.Fe[J].,2003,23(1):75277.[60],.[J].,2002,19(5):6652667.[61],,,.[J].,2002,38(1):80283.[62],,.[J].,2002,30(1):72274.[63],,.[J].,2002,32(1):23225.[64],,,.[J].,2002,30(2):1652168.[65],.[J].,2003,23(4):8252826.Progressofatomicabsorptionspectrometryinpharmaceuticalanal