毛细管电泳在农药分析中的应用

[e-mail]0106822459610003950O658A1000-8713200105-0417-061capillaryelectrophoresisCE1981JorgensonLukacs1～31984Terabe4MECCMEKC1988～1989DNACE5～112CZECaiElRassi12paraquatdiquatpH3.5～9.52×105/m～3×105/mCZEGalceran135LazerLee14TOF-MS10-17mol/LKaminasky153Schmitt1611min19pHClOHOCH3SCH3pHpKa-2～pKapH80.05mg/LGarrison1715min4245242424-3Garcia1819520019CHINESEJOURNALOFCHROMATOGRAPHYVol.19No.5Sept.200185minCE-MS-MS30pmol19Whang205mmol/L3mmol/L2110mmol/L24-2450%-15min22-Foret23pH3-20mmol/L3CD-CZECDCDD-α-1-4αβγ-CDFarran2224-24α-CDβ-CDγ-CDα-CD24-24β-CDα-CDβ-CDγ-CDγ-CDPenmetsa24-β-CDDM-β-CD-β-CDTM-β-CD-γ-CDHP-β-CD33pHCDCD1Garrison1724-32452424CZE4CD-CZE325mmol/LTM-β-CDDM-β-CDα-CD24-24245β-CDγ-CD1.3%～4.6%1.6%～17.9%Nielen25CZECD-CZE6α-CDDM-β-CDTM-β-CDβ-CD926Desiderio279-β-SBE-β-CD5g/LSBE-β-CD44.181419MECCHe28OADSSDSpH662OA934943330min15Dinelli29MECCSDS3SPECEµg/LCarabias-Martínez30SPEMECC0.2µg/L7pH0.5µg/L611%～23%79%～130%Hinsmann31C1812SDS13min7Leinweber327SDSHPLCMECCMECCWuLee33SDS15134mol/L4αβγ-CDHP-β-CDHP-β-CD15SDSHeLee34610-12mol/LMECCAguilar354SDSElvacite2669SDSElvacite2669Farran2224-245minCaiElRassi363ElRassi37-N-MEGA10SDSSDSSmith38MEGA-10-89MEGA8MEGA105.54×105/m8.45×105/mOMOSOGMEGA94OGOMKarcher39OMMECC4.2Zeta9145Lin40TTAB13pHpKaTsai4150mmol/L0.7mmol/LCTAB8Nejad42-DTAB20mmol/L10mmol/LpH6.47525%αβγ-CDHaynes43β-CD630minDesiderio446mmol/L4.5min～8.4min0.5µmol/LZerbinati458αβγ-CDCDCDβ-CDCDSchmitt46CDSDS3β-CD-β-CDγ-CDIsofenfosFenamifosmγ-CD3245CD2424γ-CD6DDTDDDDDEMechref476pH16HPCECECE10-14g10-15gCE-MSCE-NMRCE-MS-MSHPCEMSNMRCECE024191HPCETable1TheapplicationsofHPCEintheanalysisofpesticidesPesticidespeciesOperatingmodelBufferpHColumncm×µmi.d.Volt-agekVλDnmQuaternaryammoniumparaquatdiquatCZE12100mmol/Lphosphate3.5-9.550×5015254UreamonuronfluometuronmetobromuronsiduronterbacildiuronlinuronneburonchloroxuronMECC38100mmol/Lborax+100mmol/LMEGA10orMEGA810.050×5015240Sulfonylureaschlorsulfuronchlorimuronmetsul-furonMEKC2930mmol/Lborax+80mmol/LSDS+20%iso-propanol+14%methanol7.050×7525214Phenoxyaciddichlor24-Dmecoprop23-CPPA24-CPPAsilvex245-D22-CPPA2-PPACD-CZE48200mmol/Lborax+5mmol/Lα-CD10.050×5029LIFPhenoxyacidmecopropfenopropdichlorprop2-PPA23-CPPAetc.MEKC47orCZE200mmol/LNa3PO4+10mmol/L-150mmol/LNGor10mmol/L-150mmol/LOG6.550×5020230Phenoxyalkylacids24-D245-Tdiuronetc.MEKC4920mmol/Lphosphate+50mmol/LSDS+8%n-butylalcohol7.040×5027.5225Trazinessimazinecyanazineametrynepropazineprometryneterbutryneetc.MECC3060mmol/Lborax+60mmol/LSDS9.250×7522214Carbamatebaygoncarbarylcarbofuronetc.MECC3340mmol/Lphosphate+50mmol/LSDS+23mmol/LHP-β-CD53×5018214PyrethroidPermethrinphnotrincypermethrinsanmartonfenpropathrinMECC39100mmol/LNa3PO4+40mmol/LOG25mmol/LOM+0-10%acetonitrile6.550×5019LIFFungicidescarbendazinemetalzxylvinclozolinpropiconazoleMEKC5010mmol/LNaH2PO4+30mmol/LSDSor10mmol/LNaCh+5%-15%methanol7.050×5028214Prophamdiurondesmetrynchlorfenvinphosetc.MECC65mmol/Lborax+30mmol/LSDS8.063×7520214Isoprothiolaneasulanfenobucarbchloronebhiobencarbterbutolbutamifosiprodineetc.MECC2825mmol/Lborax+30mmol/LSDS+15%methanol+8.0mmol/Lβ-CD9.565×5025220Dimethoateazinphos-methylchlorpyriphos-methylchlorpyriphos-ethylMEKC4920mmol/Lphosphate+50mmol/LSDS+0-40%methanol9.040×5027.5200Simazineatrazineametrynprometrynter-butrynetc.MEKC3110mmol/LNa2HPO4+60mmol/LSDS+8%acetonitrile9.547×7525226MalathionruelenedialifosfenamifosisofenfosMEKC4620mmol/Lborax+100mmol/LSDS+20%methanol+40mmol/LDM-β-CDTM-β-CD9.050×5015-30200Prometryneterbutrynedesmetrynemethoxysimazineetc.CZE2320mmol/LTris+30%ethanol3.035×7515254SimazineatrazineprometonametrynpropazineprometrynterbutrynMEKC3220mmol/Lphosphate+100mmol/LSDS9.1456×5030214Ruelenedialifospp-DDTop-DDEmeto-lachlordichlorpropmethylesteretc.MEKC4320mmol/Lborax+100mmol/LSDS+methanol9.047×5030-55214Dhaloxyfopfluazifopflampropfenoxapropetc.MEKC4450mmol/Lborax+50mmol/Laceticacid+50mmol/Lphosphate+vancomycin5-733×5020205Fenopropmecopropdichlorprop24-DCD-CZE2450mmol/Lacetate+40mmol/LTM-β-CD4.4550×7520214or230NapropamideethofumesateflampropfreeacidCD-CZE275mmol/L-25mmol/Lborax+5g/L-30g/LSBE-β-CD+10%methanol9.050×5020205TristrihydroxymethylaminomethaneSDSsodiumdodecylsulfateNaDChsodiumdeoxycholateNaChsodiumcholateDM-β-CDdimethyl-β-cyclodextrinCDTM-β-CDtrimethyl-β-cyclodextrinCDHP-β-CDhydroxypropyl-β-CDSBE-β-CDsulfobutylether-β-CD.LIFlaserinducedfluorescence.1JorgensonJWLukacsKD.AnalChem19818531298-13022JorgensonJWLukacsKD.ClinChem1981271551-15543JorgensonJWLukacsKD.Science1983222226-2294TerabeSOtsukaKIchikawaKetal.AnalChem1984561111-1135BurgiDS.AnalChem199365243726-37296SüsseHMüllerH.JChromatogrA1996730337-3437HsiehYZHuangHY.JChromatogrA1996745217-2238ChienRLBurgiDS.AnalChem1992648489A-496A9ChienRLBurgiDS.AnalChem19926491046-105010ZhangCXThormannW.AnalChem199668152523-253211TomkinsBAGriestWH.AnalChem199668152533-254012CaiJElRassiZ.JLiqChromatogr1992151193-120013GalceranMTCarneiroMCDiezMetal.JChro-matogrA1997782289-295124514LazerLMLeeML.JMicrocolSep199911117-12315KaminaskyD.AnalChem1994661817-182416Schmitt