药分实验讲义精选

160%405021233.13..23..33.43.533.63.73.83.93.104-------------------------------------------------------------6HPLCTLC-------------------------------9------------------------------------------------------------12------------------------------------------------16------------------------------------------------------------195122.12.020ml30.02mol/L0.20ml2.25g10ml12000IXB3ml3ml6ml50ml1.0ml10ml2.30.6g25ml10ml50ml40ml1ml50ml510gCl/ml6.0ml50ml10ml40ml1ml40ml1ml50ml50.01%2.42.0g40ml50ml2ml25%5ml50ml10100gSO4/ml2.0ml50ml40ml2ml25%5ml50ml100.01%2.51.0g90%30ml10[1]2.61.0g10ml1[2]2.71059.5%2.81~2g60.5~1ml700~800700~8000.1%2.92.0g20ml3545ml301003ml2.0ml0.001%2.1025ml10gPb/ml2.0mlpH3.5[3]2ml25ml4.0g23mlpH3.52ml2ml25ppm2.112.0g5ml5ml0.5ml205ml28ml5ml5102g[4]254040451gAs/ml0.0001%1gAs/ml2ml2.121.0g10ml153ml3[1][2][3]pH3~3.5PbS[4]44.12000755.12000815811.11.21.322.1COOHOCOCH3+H2OCOOHOH+CH3COOH6COOHOH+4Fe3+Fe(COOO--)23Fe++12H+2.20.10g1ml50ml1ml300.1g1ml1000ml1ml1ml48ml1ml0.1%91001ml2ml100ml33.1G4.518ml5cm2030.2~0.3mm10513.2911ml3.0mg911ml60µg2000VB5µlG38560302105109341ml0.8mg11ml0.016mg22000101710µl1210µl1.51421/23/47030254nm20003.0%1ml0.8mg1ml0.8mg2ml10ml10l5920001ml2.0mg2000IVA310nm0.0566.12.5cm6.21cm6.3106.46.577.17.2Ecm%11310nm=45388.120003278.220004808.3200010178.420003841111.11.2210mg5%2mg2%10100XXS(S=()12−−∑nXX)AA=100-XA+1.80S15.0A+S15.0A+1.80S15.0A+S15.02030XSAA+1.45S15.0A+1.45S15.0±20%15.020.010YY100XA,XAYKK=XA/YYK10012%X(X=KY),XSA31A0.254mm0.425mm22.2mm±1.0mmB9.410.1mm2.0mm120°±1.0mm21000ml98~106mm160~175mm2370.525mm2mm3502004%46610mm900ml370.566450.8µm306QQ70%61Q-10%136Q-10%6122Q-10%22(Q)44.120210.3g0.3g0.3g±7.5%±5%4.2202110.3g0.3g0.3g±10%±7.5%5110mg100mlpH4.513.6g1000ml14pH4.540mlpH4.5pH4.51ml10g804pH4.51ml10gIVA266nm2nmXEXCpH4.5900ml1003010ml1ml10g80%66.12000XE786.22000XC756.32000IAIB586.420004251511.11.2277220g150g35g1000C9H8O40.2090.231gC10H13O2N0.1430.158C8H10O2N4·H2O31.538.5mg3203.10.4g15ml420101010ml10ml20ml30.1mol/L1ml0.1mol/L18.02mgC9H8O43.20.3g25ml40(12)40ml5ml3g2/3200.1mol/L31ml0.1mol/L17.92mgC10H13O2N3.350mg165ml50ml35ml0.1mol/L25ml251525ml0.05mol/L1ml0.1mol/L2.653mgC8H10O2N4·H2O44.10.1mol/LCOOHOCOCH3+NaOHCOONaOCOCH3+H2O4.2NHOC2H5COCCH3+H2Od.H2SO4NH2OC2H5+CH3COOHNH2OC2H5+NaNO2+2HClN+OC2H5NCl-4.3[B]17CH3NCOCCNNOCNCH3CH3CHH2O2[B]+4I2+2KI+H2SO42[[B]•HI•I4]+K2SO4I2+2Na2S2O32NaI+Na2S4O655.15.25.35.40.0250.035mol/L5mlH2SO45.51015ml66.16.2KBrKBr6.377.133633819587.2D.CGarrattTheQuantitativeAnalysisofDrugsP12(Thirdedition1964)7.3T.HiguchiPharmaceuticalAnalysis1961p5631811.11.22A1000ml0.51mm2/3CD[1][2]12[3][4]33.1O2/PtRII2+H2O+CO2+NaI+NaIO3NaOH·H2OI2+5Br2+6H2O2HIO3+10HBrIO3+5I+6H+3I2+3H2OI2+2S2O32I+S4O63.20.2g50ml5ml[5][6]219[7][8]1.0g0.005mol/L1ml1ml0.005mol/L0.1058mgI3.3[1][2][3]Pt[4][5][6]10g0.40ml100ml[7]Br2+HCOOH2HBr+CO2[8]3.43.53.5.12000VIIC493.5.2200014244.10.005mol/L20NSOClOOCH3O2/PtHCl+CO2+H2O+SO2+NO2HClNaOHNaClH2O2ClHg2HgCl2OCNNHNNH+1/2Hg2+OCNNNNHHg1/24.21050mg0.2mol/L10ml2020ml70.5mol/L0.05mol/L0.05mol/L0.5ml0.005mol/L1ml0.005mol/L2.737mgC11H12O3NSCl21