玻璃纤维概述材料分类

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一、什么是玻璃纤维I.Whatisfiberglass?1.材料分类MaterialCategory2.产品品种Productcategory3.主要性能Mainproperties4.主要产品Mainproducts1、材料分类Materialcategory—Steel钢铁—Metal金属—Nonferrousmetals有色金属—Organicmaterials有机材料Materials—Fiberglass玻璃纤维材料FRP/Highperformancecomposites—NonmetalSpecialglass/deep-processedglass非金属—InorganicSpecialceramicmaterialsArtificialcrystal无机材料SyntheticmicaLasercrystal—Specialcementingmaterial2、产品品种Productcategory—Medium-Alkalifiberglass(C)中碱—ContinuousfiberglassAlkali-freefiberglass(E)无碱连续玻璃纤维—High-Alkalifiberglass(A)高碱Staplefiberglass&glasswool玻璃棉Fiberglass玻璃纤维—High-strengthfiberglass(S)高强High-modulusfiberglass(M)高模量High-silicafiberglass高硅氧—SpecialfiberglassAlkali&corrosionresistantfiberglass抗碱特种玻璃纤维Opticalcommunicationfiberglass光通信—Light-guidefiberglass光导3、玻璃材料Glass-makingmaterialsa)中碱玻璃原料C-glassrawmaterials中碱玻璃球C-glassmarble中碱玻璃粉料C-glassbatch中碱废丝C-glassrecycledwastefiberb)无碱玻璃原料E-glassrawmaterials无碱玻璃球E-glassmarble无碱玻璃粉料E-glassbatch无碱废丝E-glassrecycledwasterfiber3.1中碱玻璃粉料C-glassRawmaterialsa)石英砂Quartzsand:SiO2b)钠长石Albite:AL2O3、Na2Oc)白云石Dolomite:CaOMgOd)石灰石Limestone:CaOe)莹石Fluorspar:CaF2f)纯碱Sodaash:Na2CO3g)硝酸钠Sodiumnitrate:NaNO3h)无水硫酸钠Anhydroussodiumsulfate:Na2SO4i)氧化铈Ceria:CeO23.2无碱玻璃粉料E-Glassrawmaterialsa)高岭土/叶腊石Clay/Pyrophyllite:AL2O3、SiO2b)硼钙石Colemanite:B2O3、CaOc)石灰石Limestone:CaOd)莹石Fluorspar:CaF2、SiO2、CaCO3e)石英砂Quartzsand:SiO2f)纯碱Sodaash:Na2CO3g)无水硫酸钠Anhydroussodiumsulfate:Na2SO43.3玻璃成分Glasscomposition3.3成分与作用Componentsandtheirfunctions氧化硅SiO2:物质基础、骨架Basisandmatrix氧化铝Al2O3:降析晶和膨胀系数,提高稳定性和强度toreducerecrystallizationandexpansioncoefficientandincreasestabilityandstrength氧化钙氧化镁:降低高温时粘度,促进熔化、澄清、提高拉丝速度CaO/MgO:Toreduceviscosityathightemperatureandpromotemelting,refiningandincreasewindingspeed.氧化硼B2O氧化铁Fe2O3碱金属;助熔,提高流动性Na2O/K2O;Toaidmeltingandincreasefluidity4、主要产品Mainproducts合股无捻粗纱直接无捻粗纱短切原丝无捻粗纱布缝编短切毡短切原丝毡缝编复合毡细纱4.1主要产品——合股无捻粗纱Mainproducts–Assembledrovinga)喷射SprayupRoving(SP)b)缠绕Filamentwindingroving(FW)c)拉挤Pultrusion(PL)d)SMCroving(RovingforSMC)e)HOBAS管道RovingforHOBASpipes(HS)f)膨体Texturedroving(BY)g)透明板材Panelroving(TS)h)热塑性增强Rovingforthermoplastics(RP)i)RovingforGMT(GMT)4.2主要产品——直接无捻粗纱Mainproducts-directrovinga)缠绕Filamentwindingroving(FW)b)拉挤Pultrusionroving(PL)c)织布Rovingforwovenroving(WR)4.3主要产品——短切原丝Mainproducts–Choppedstrandsa)团状模塑料Bulkmoldingcompound(BM)b)热塑性增强Thermoplasticreinforcement(TP)c)湿法短切Wetchop(WS)d)增强水泥Reinforcedcement(RC)4.4主要产品——布毡Mainproducts–fabric&mata)无捻粗纱布Wovenroving——EWRb)缝编短切毡Stitchedchoppedstrandmat——EMKc)短切原丝毡Choppedstrandmat——EMCd)缝编复合毡Stitchedcombomat——EMK(0,90)4.5主要产品——其它Mainproducts-Others细纱Continuousfilamentyarn一般指单纤维直径9微米以下的玻璃纤维纱,包括G75纱、D450纱、E225纱等,织成7628布、2116布、1080布等。主要用于电子行业,增强覆铜板基板,部份为工业用布。二、玻璃纤维行业的历史II.Historyoffiberglassindustry1.国际发展Internationaldevelopment2.国内发展Domesticdevelopment3.市场竞争Marketcompetition4.行业现状Industrycurrentstatus1、国际发展Internationaldevelopment2000多年前,古埃及手工拉制玻纤做装饰材料;Over2000yearsago,Egyptiansmanuallymadefiberglassasornamentmaterial20世纪30年代,美国发明了铂坩埚拉制工艺技术;Inthe1930s,Americansinventedthetechnologyofproducingfiberglasswithplatinumcrucibles1938年美国成立OWENSCORNING,具有工业性规模,用于绝缘材料;In1938OwensCorningCowasestablishedinUSAwhichhadaindustrialscaleoffiberglassproductionforinsulationapplication.二战后工业普及,成立了圣哥本(法)、皮尔金顿(英)、日东纺(日)等;AfterWorldWarII,theindustrialproductionoffiberglassbecamepopularandSt.Gobain(France),Pilkington(GreatBritain),Nittobo(Japan)startedtoproducefiberglass.1959~1960年,OWENSCORNING和PPG公司相继建成了玻璃纤维池窑。In1959and1960,OwensCorningandPPGbuiltfiberglassfurnaces.2、国内发展Domesticdevelopment20世纪50年代后期,我国玻璃纤维工业诞生,采用陶土坩埚法和镍铬合金孔板法生产;Inlate1950s,thefiberglassindustrystartedinChinaandthefiberglassthenwasproducedwithclaycruciblesandnickel-chromealloynozzleplates20世纪60年代中期,研制成功代铂坩埚法生产工艺;Inthemiddleof1960s,theplatinum-substitutecrucibleprocesswasinvented20世纪90年代初,池窑法开始在中国普及。Inthe1990s,thefiberglassfurnacesbecamepopularinChina3、市场竞争Marketcompetitors国际竞争对手——欧文斯.康宁(美)、PPG(美)、圣哥本(法)Internationalcompetitors–OwensCorning,PPG,St.Gobain国内竞争对手——巨石、泰山、重庆Domesticcompetitors:Jushi,Taishanfiberglass,CPIC4、行业现状Industrycurrentstatus奠基于上世纪30年代末,已成独立工业体系。Theindustryestablisheditselfin1930sandhasformedintoanindependentindustrysystem.目前有数千个品种与规格、5万多种用途,成为现代工业材料家族中重要的一员。Atpresenttherearethousandsofproducttypesandspecificationsandover50,000applicationsandfiberglasshasbecomeanimportantmemberinthemodernindustrialmaterialfamily.三、玻璃纤维有什么用处?III.Whatisfiberglassfor?1.交通运输Transportation2.建筑建材Construction3.电气工业Electrical4.机械工业Engineering5.石油化工Petroleum&chemical6.休闲文化Leisureandsports7.国防科技Defence四、玻璃纤维怎么做出来的?IV.Howisfiberglassproduced?一、代铂炉生产工艺四、玻璃纤维怎么做出来的?IV.Howisfiberglassproduced?二、波歇炉生产工艺四、玻璃纤维怎么做出来的?IV.Howisfiberglassproduced?配料Batch熔化Melting拉丝Fiberforming烘干Drying络纱Roving织布Weaving制毡Matproduction捻线Twisting短切Chopping三、单元窑生产工艺

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