超共轭效应-大学化学-2001-51-552202897

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2020-02-25

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165200110周公度(100871),:CH3CC,CH,,1(a);,1(b),12.1kJ/mol,CH227pm,H(240pm),,CH250pm,H,,,1936,,1:(a),(b),V.PophristicL.GoodmanNature,,,:,Pauli,,(R)(1/R)CH3CC,H,,,0,,60,,CC51,,,,,:,,;,(),;,,,CCCH3CC*,,232,CHCH*31PophristicV,GoodmanL.Nature,2001,411:5652WeinholdF.Nature,2001,411:5392002,1984,(ISSN10035249/CN111835/O6)300,3000:12,:;;;20024()2002,,,16,12.00,60.00()2002:1,:100044;:(010)68333366-341552