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Electrochemicaldepositionofone-dimensionalaluminumphthalocyaninenanomaterialscontent1.Introduction2.Preparation3.Resultsanddiscussion4.ConclusionIntroduction•Theone-dimensional(1D)nanomaterialshavereceivedagreatdealofattentionduetotheiruniqueoptic,magnetic,andelectronicproperties.Greateffortshavebeenplacedonthesynthesisof1Dnanomaterials,andvariousmethodshavebeenexploited.•Incontrasttoinorganicmaterials,organicmaterialshavepeculiarelectronicandopticalproperties.Theyarereadilysynthesized,andcanbepolyfunctionalizedtoallowfortailoringtheiroptical,electronic,andchemicalproperties.However,thepreparationoforganic1Dnanomaterialsremainspoorlystudied,andonlyafewsuccessfulexampleshavebeenreported.Introduction•Wereporthereafacilemethodtofabricate1Daluminumphthalocyaninenanomaterialsviaelectrochemicaldepositionmethod.Thestructuresoftheresulting1Daluminumphthalo-cyaninenanomaterialswerecharacterizedandtheirelectricalandopticalpropertieswerestudied.Preparation铝酞菁（10mg）溶解于二甲亚砜和三氟乙酸（25:1，V/V）的混合物中(二甲亚砜中的铝酞菁溶液的浓度分别为1/9，1/6或1/3mg.ml-1），铝酞菁薄膜通过垂直浸渍到ITO玻璃板上从铝酞菁溶液中沉积出来（电压范围从0.1至10伏，电流范围为0.1和10毫安）。铝酞菁九个薄膜电化学沉积后，在85摄氏度条件下在真空下过夜退火。ResultsanddiscussionPreparationandcharacterizationof1DaluminumphthalocyaninenanomaterialsTheseresultscanbeexplainedbythefollowingconsiderations.Aluminumphthalocyaninecanbeprotonizedbystrongacid,suchasconcentratedsulfuricacidortrifluoroaceticacid(三氟乙酸)Asaresult,1Dnanomaterialsfabricationduringreducingtheconcentrationofaluminumphthalocyaninesolutionappearstobepossible.UV–visspectrathemorphologyofresultingaluminumphthalocyanineatavoltageof0.5Visnearlynanodotornanowire.Whenthevoltageisfurtherincreasedto20V,themorphologyofresultingaluminumphthalocyaninematerialswouldbegreatlychanged,anditisalmostirregularaggregationanditssizeisabout200–300nm.Asaresult,1Dnanomaterialsfabricationduringreducingthevoltageappearstobepossible.•Conductivityof1DaluminumphthalocyaninenanomaterialsConclusion第二篇文献introduction•Inthelastdecade,manyfundamentalresearcheshavebeendevotedtolowdimensionalsystems,butone-dimension(1D)nanostructures,inparticular,attractedconsiderableattentionduetotheirpotentialmagnetic,optical,electrical,andcatalyticproperties.Sofar,therearevariousmethodsinthesynthesisof1Dnanomaterials(wires,rods,andtubes).However,thesemethodsexistmanylimitations,suchasexcessiveprocess,complicatedoperationandseverereactioncondition.Here,wedemonstrateachemicalsolutionmethodforthesynthesisof1Dnanostructures.Chemicalsolutionmethodisamorepotentialmethod,whoseadvantageslieinmild,simpleandlow-cost.Morphologyandsizecontrolcanbeachievedbyadjustingthekindofthereactants,theconcentrationofreactants,ratioofmodifiedreagent/surfactanttoreactantsandrefluxingtime.WehavesuccessfullypreparedZnO,Ninanomaterialsviathisversatilemethod.Herein,wepresentanovelchemicalrouteofmicroemulsionstowardthegrowthofwell-proportionedandcrystallizedZnOnanorodsusingdodecylbenzenesulfonicacidsodiumsalt(DBS)十二烷基苯磺酸钠asthemodifyingandprotectingagent.Thenoveltyofthisprocedurecanbecharacterizedbythesuccessfullywell-orderedgrowthofperfectcrystallizedZnOnanorodsundereasilycontrolledandmildconditions.•One-dimensionnickelnanomaterials(includingnickelmagneticnanochain,nickelnanorodandnickelcomplexnanotube)modifiedbypolyvinylpyrrolidone(PVP)weresynthesizedviaaseriesofnovelandmildchemicalmethodsinanethyleneglycolsystem.NiCl2·6H2OwasdeoxidizedbyN2H4·H2OinthepresenceofPVP.Byadjustingtheratioamongthesolvent,modifyingagentandmetalsalt,wesucceedincontrollingtheshapeandthedimensionoftheproducts.•insummary,chemicalsolutionmethodhasgreatadvantages.Morphologyandsizecontrolcanbeachievedbyadjustingthereactionconditions.Therefore,itoffersanovelandattractivepathtothepreparationof1Dnanomaterialswithdifferentshapesandcontrollablesizes