水基防锈剂的研究进展-李志林

51　　　1,1,2(1.,071002;2.,065000)　　[　]　金属因生锈每年造成巨大经济损失。目前的金属防锈技术存在很多缺点,相比之下,环保型水基防锈剂在金属材料保护方面有许多优点。综述了国内外近年来水基防锈剂的研究状况,重点介绍了几种新型水基防锈剂的防锈机理和性能,并简要概述了美国水基防锈剂的研究进展,最后提出了水基防锈剂的发展趋势,即利用丰富的自然资源或农副产品提取防锈剂的有效成分,经改性后制成高效低毒的复合水基防锈剂。[]　经济损失;水基防锈剂;防锈机理;性能;发展趋势[]TB304　　　[]A　　　[]1001-3660(2006)05-0051-03StudyAdvanceaboutAqueousRustInhibitorLIZhi-lin1,HANLi-xing1,CHENZe-min2(1.CollegeofChemistryandEnvironmentalScience,HebeiUniversity,Baoding071002,China;2.CollegeofChemistryandMaterialsScience,LangfangTeachersCollege,Langfang065000,China)[Abstract]　Tremendouseconomiclossesaresufferedeveryyearbecauseofmetalrus.tTheexistingan-tirusttechnologyhasalotofshortcomings,bycontrast,environmentalprotectiontypeaqueousrustinhibitorissuperiorinthefieldofmetalmaterialsprotection.Researchsituationaboutaqueousrustinhibitorathomeanda-broadinrecentyearsisoverviewed,andantirustmechanismandperformanceofseveralnewaqueousrustinhibi-torsareemphaticallyintroduced.Besides,researchadvanceaboutaqueousrustinhibitorinAmericaissummedupinbrief,anddevelopmenttrendofaqueousrustinhibitorisputforwardatlast,thatis,bydrawingeffectivecompositionsofrustinhibitorfromabundantnaturalresourcesoragriculturalby-products,andthroughchangingitsproperty,compoundaqueousrustinhibitorwithhigheffectivenessandlittlepoisonareprepared.[Keywords]　Economicloss;Aqueousrustinhibitor;Antirustmechanism;Performance;Developmenttrend0　　[]2006-06-12[](1956-),,,,,。,,20005000[1],,。,,,,,,。,,。,,。。1　1.1　、,。。[2],、,ATEA-1,0.25%48h。,,,[3],,35　5　　　Vo.l35　NO.5　200610SURFACETECHNOLOGYOct.2006　DOI牶牨牥牣牨牰牬牴牥牤j牣cnki牣issn牣牨牥牥牨牠牫牰牰牥牣牪牥牥牰牣牥牭牣牥牨牴52　　　。,d,、。1.2　,、。[4],,,,。24、12,,,,1a,,,[5]。,,。1.3　,、,、,,-[6],,。,SO2,。[7]MoS42-WS42-,。。Mo(W)S42-。1.4　:,Y—(CH2)n—Si—(OR)3(RO)3—Si—(CH2)n—Y—(CH2)n—Si—(OR)3,,Y,RO—。,,。,,Si—O—Me,Me,—SiOH[8]。:1,2-。,,,,pH,、,,,50～100nm[9],,,,,、[10],。1.5　,,,、,。,。、Z-55[11],,Z-55,1min,F-124,,Z-558,。1-,0.05%,[12]。4-(N,N-)-,[13]。,,,,,,。,、,[14]。2　[15-17]。[18],270g,180g,20g,30g,14g440g,50。,,,,,,。Hon-da[15],,,,。3　,。,、,、、、、、、、、,,,,,[19]。　53　　　,、“”,、、,,,。,,,,,,。[][1]　.[M].:,1997.22[2]　,,.[J].,2005,(2):72-74[3]　.[M].:,1999.167-168[4]　,,,.[J].,2002,22(5):282-285[5]　.[J].,2004,37(10):45-46[6]　,,,.STM[J].,2003,24(10):415-418[7]　,.Mo(W)-S[J].,2004,33(4):37-40[8]　,,,.[J].,2005,34(1):5-6[9]　,,.[J].,2001,13(2):96-100[10],.[J].,2005,34(1):66-72[11],.Z-55[J].,2001,22(6):246-247[12].[J].,2000,33(1):26-27[13],,.[J].,2004,24(4):245-248[14].[J].,2004,37(1):60-62[15]Honda.Processforimprovingthecorrosionresistanceofametalsurface[P].USPat:6395336,2002-05-28[16]YaSuo,FuKutani,Kanzaki-Gun.Water-solublecuttingfluid[P].USPat:6242391,2001-06-05[17]Graichen.Melamine-polycarboxylicacidamidesandtheiruseasan-ticorrosiveagents[P].USPat:6096244,2000-08-01[18]FuKutan.iRustpreventive[P].USPat:6488749,2002-12-03[19].[J].,2000,33(5):11-15(上接第11页)5　,,、、、。,,,,,。,。,,。[12]。3　　AgNO3,。,,8.2～12.4GHz。[][1]　JurgenBertling,JanBlomer,RolfKumme.lHollowMicrospheres[J].Chem.Eng.Techno.l,2004,27(8):829-830[2]　ShuklaS,SealS,RahamanZ,eta.lElectrolesscoppercoatingofcenospheresusingsilvernitrateactivator[J].MaterialsLetters,2002,57:151-156[3]　,,,.[J].,2003,29(1):108-111[4]　,,,.[J].,2003,9(1):67-70[5]　,,.[M].:,2004.[6]　,,,.[J].,2005,22(1):5-8[7]　ZengAixiang,XiongWeihao,XuJian.ElectrolessNi-Co-Pcoatingofcenospheresusing[Ag(NH3)2]+Activator[J].MaterialsLetters,2005,(59):524-528[8]　ZhangQiuyu,WuMin,ZhaoWen.Electrolessnickelplatingonhol-lowglassmicrospheres[J].SurfaceCoatingsTechnology,2005,(192):213-219[9]　ZengAixiang,XiongWeihao,XuJian.ElectrolessNi-Pcoatingofcenospheresusingsilvernitrateactivator[J].SurfaceCoatingsTech-nology,2005,197:142-147[10].[J].,2004,33(4):19-21[11],,,.[J].,2003,20(6):122[12].[M].:,2004.247-24835　5　　　Vo.l35　NO.5　200610SURFACETECHNOLOGYOct.2006