20101922010Vol.19No.2GANSUGEOLOGY:1004-4116(2010)02-0018-0009,,,,,,,(,730000):,。,:、、TTG、、,、—。、、。:;;;—:P588.1:A:2009-10-26:(1984~),,,,、、。E-mail:ouyj03@lzu.cn1。、、、、。、、,。,,。、-,,,、。,,,(1)。21(TatsumiandEggins,1995)Fig.1Schematiccross-sectionthroughasubductionzone,showingthevariousregionalandstructuralfeatures(afterTatsumiandEggins,1995)2,,。,、。,(),,,,,,,。,(),,;,(),,。2.12.1.1,——,:TiO2(0.82wt%),Al2O313wt%;K2O,K2ONa2O。MORB,TiO2MORB(=1.5wt%)[1]。①Ti(OIB);②,,Ti。2.1.2REE(LILE)(Sr、Rb、Ba),(HFSE)(Nb、Ta、Ti)。REE,(LREE),(HREE)[(HREE)N10,Yb≥2×10-6,Y≥25×10-6]。,LILE,HFSETi、Nb、Ta,(、)。Ce,[2]。,,,,,Sr、Eu。,:Nb≤12μg/g,Ta≤0.7μg/g;Nb/La≤1,Hf/Ta≥5,La/Ta15,Ti/Y350,Ti/V≤30,Hf/Th8,Th/Yb0.1,Th/Nb0.07,Zr/Y3,Ta/Yb≤0.1[3]。,Nb/Y(0.15)Zr/TiO2(0.01)[4],Ba/La30[5]。2.1.3(Sr87/Sr86)I0.7027~0.709,εNd(t)-2.50~-3.47[6]。(Sr87/Sr86)I,,,,,。,(Ni90~130μg/g,Cr251~411μg/g),Ni,Cr(Ni50μg/g,Cr160μg/g)[7]。,,Ni,Cr。2.2,。,,、,,。,,,(boninite)。,,。,,,(,),K、Sr、Rb、Ba、Zr、Th、U、K/Rb、Fe/Mg87Sr/86Sr、143Nd/144Nd、Pb。,。2.3,。,,(Kurokodeposite)。,,,,,Cu、Fe,Au、Mo、Ag。:19192、bajaite(Kameietal.,2004)Fig.2ComparisonofsanukiticHMAtoadakiticHMA,boniniticHMAandbajaiticHMA.(Kameietal.,2004)3Nb1978Adak,。DefantandDrummond(1990)[8],adakite,,≤25Ma、;,、。Defant(2002)[9],adakite,adakite,。(2003)[10],,“”,,[11]。Kay(2001)[11],()adakite。,[12~13],[10],、[14]。1993Sajona[15]MindanaoZamboanga。NEB(Nb)(Defantetal.,1991[16],DefantandDrummond,1993[17],Mauryetal.,1992[18]),NEB(Nb)[15,19,20,21],。MgO/(MgO+FeO)(La/Nb)NSr/YW(TiO2)/%YYbN/N-MORB202(—)、[22]。3.1,:SiO256%,Al2O315%,MgO3%(6%),NaK(K2O/Na2O0.42),Sr(Sr400×10-6,Sr/Y40),YYb(Y18×10-6,Yb1.9×10-6),LREE,EuEu,Cr(30~50)×10-6,Ni(20~40)×10-6[8,22]。(87Sr/86Sr)I0.704,εNd0[23](2)。Na。SrYHREE,,。Cr、Ni、Mg#,,Cr、Ni、Mg。:(Na2O/K2O1.0),,,Nb(7×10-6~16×10-6)、Ti(1%~2%)P,LILE/HFSE[15]。LREE/HFSE(La/Nb=0.7~2.0)[24],(La/Nb0.7~2.0)。(87Sr/86Sr)I0.70291~0.70369,εNd0.512987~0.513035,MORBSr、Nd[25]。,Nb,Nb、Ta,OIBNb;,HFSE,HFSEOIB。3.2,(),,[26]。,“”,“”[27],“()”[11,28~33],“”[34~36])。,(40Ma)200km[22,37])。[38]。,Nb(HFSE),。Nb。3.3Thieblemontetal.(1997)[39]43(),。43,38,:①,;②,Cu-Au-Ag。[40~41]。,(fO2),Fe2O3,Fe2O3,fO2,,(Au,Cu),[41]。4TTG(Sanukitoid)TTG、、,。TTG,90%[42],,TTG[43][44]。[22,45~53]。Sanukite(11~14Ma)Setouchi,Si、Mg#、Ni、Cr、LILEK/Na(0.33~0.52),TTG。Sanukite。ShireyandHanson(1984)[54]SuperiorProvince,:2119(Sanukite),Sanukite(Sanukitoid)。4.1,TTGBarker(1979)[46],(SiO264wt%,70wt%),Al2O315%,NaK(3.0wt%≤Na2O≤7.0wt%),Na2O/K2O1,Fe、Mg,Yb1μg/g,LaN/YbN30,SrBa500μg/g[55]。,。TTGMg#0.45,(La/Yb)N5~150[56~57]。,TTGHREE[58]。,Martin,TTG,SiO2、MgO[42],Mg#0.45(4.0Ga)0.65(2.5Ga),,Ni、Cr30μg/g、50μg/g70μg/g、200μg/g,Sr-550μg/g-1200μg/g[59]。TTG(2)TTG,。ShireyandHanson(1984)[54]sanukitoidsMg#0.6,NiCr100μg/g,SrBa500μg/g,LREE([Ce/Yb]=10~50,CeN100μg/g)LILE(K、Sr、ZrNb),HREE(YbN=6~12),EuEu(2)。εNd(t)(+2.0~-0.3,Kovalenkoetal.,2003)[60]、87Sr/86Sr(0.7000~0.7021,Kovalenkoetal.,2003)[60]Pb[61]。,(TTG)[54,62,63]。4.2TTG,TTG,Mg、Ni、CrSr、Si[58],(3.0Ga)MgSiTTG,;(3.0Ga),。,Smithies(2000)[62]TTG,TTG。Smithies(2000)[62]TTG,,TTG。,TTGSiO2Mg#、CrNi。TTGSrEu,。,,TTG[65]。,TTG,。。,,[66,70],TTG[34]。SiO2(),(),,。MgO(Mg#0.60)、CrNi,LILELREE,[54,62,66~69],SuperiorProvince、Baltic、Pilbara[42]。,,,[63,71]。4.390%TTG,TTG,TTG、()。,TTG、、。5(Boninite)Crawford[72]:“2223TiO2-La/Sm(Wyman,1999)Fig.3DiagramofTiO2vs.La/Smfortheboninite(Wyman.1999)w(SiO2)53%,(Mg#)0.60,”。Bonin。,、,,。,。[73]。,,。,。J2-K1,K1,J2-K1K1[72]。5.1、,SiO252wt%~60wt%,MgO(6%~25wt%),Mg#0.6,Al2O3/TiO2,LILE,Ti、P(HFSE),TiO2(0.5%,0.2%,3)。Cr、Ni,Cr300×10-6~900×10-6,Ni100×10-6~450×10-6。LREE,UREE。,[74-76]。5.2,[77]。,[78~80]。SSZ(supra-sub-ductionzone)[81]。,,—[64]。5.3(),,,,,,。,,[72,77~78,82~85]。6,,,。;;Nb;TTG(,,,)[22],(TTG),,TTG;Sanukitoid()TTG,(TTG)[54,62~63],Nb;Boninite()。,。,Cu-Au。:2319[1]PearceJA.Roleofthesub-continentallithosphereinmagmagen-esisatactivecontinentalmargins[A],1983.In:HawkesworthCJandNorryMJ(eds),ContinentalBasaltsandMantleXenoliths[C].Shiva,Nantwich,230-249.[2]ElliottT,PlankT,ZindlerA,WhiteWandBourdonB.ElementtransportfromslabtovolcanicfrontattheMarianaarc[J].Jour-nalofGeophysicalResearch,1997,102:14991-15019.[3]CondieKC.GeochemicalchangesinbasaltsandandsitesacrosstheArchaean-proterozicboundary:identificationandsignifi-cance[J].Lithos.,1989,23:1-18.[4]LentzDR.Petrogeneticevolutionoffelsicvolcanicsequencesas-sociatedwithPhanerozoicvolcanic-hostedmassivesulphidesys-tems:theroleofextensionalgeodynamics[J].OreGeol.Tev.,1998,12:289-327.[5]TamimountAjaji,DominiqueWeis,AndreGiretetal.Coevalpotassicandsodiccalc-alkalineseriesinthepost-collisionalHercynianTanncherfiintrusivecomplex,northeasternMorocco:geochemical,isotopicandgeochronologicalevidence[J].Lithos,1998,45:371-393.[6]HessPC.OriginofIgneousrocks[M].HarvardUniversityPress,Cambridge,Massachusetts.London,England,1989.[7].[M].:,1998,1-231.[8]DefantMJ,DrummondMS.Derivationofsomemodernarcmag-masbymeltingofyoungsubductedlithosphere[J].Nature,1990,347:662-665.[9]DefantMJ,XuJF,WangQ,XiaoL.Adakite:Somevariationonatheme[J].ActaPetrologicaSinica,2002,18(2):129-142.[10],,,.[J].,2003,10:385-400.[11]KaySMandMpodozisC.CentralAndeanoredepositslinkedtoevolvin