钠离子电池碳基负极材料研究进展-胡明祥2017

31120172JOUＲNALOFQILUUNIVEＲSITYOFTECHNOLOGYVol．31No．1Feb．20172016－08－122017－01－01973－2015CB9325002014CB9324011993—．*1980—[e-mail]．1004－4280201701－0001－08DOI10．16442/j．cnki．qlgydxxb．2017．01．001，*100084。。、、。TQ035AＲecentProgressonCarbon-basedAnodeMaterialsforSodium-ionBatteryHUMing-xiangLVＲui-tao*KeyLaboratoryofAdvancedMaterialsMOESchoolofMaterialsScienceandEngineeringTsinghuaUniversityBeijing100084ChinaAbstractAsanimportanttypeofthenext-generationenergystoragedevicessodium-ionbatteriesSIBsareattractingincreasingresearchattentions．ComparedwiththecathodematerialsofSIBsdevelopinghigh-performanceanodematerialsisbecomingabottleneckissuewhichwilllimitthepracticalapplicationsofSIBs．ThisarticlesummarizestheresearchprogressesondifferentanodematerialsforSIBsincludingalloysmetaloxidesmetalsulfidesandcarbon-basedmaterials．Inparticulartheapplicationsofcarbon-basedstructureswithdifferentdimensionalitiesasanodematerialsforSIBsarediscussedindetail．Basedoncurrentachievementstheperspectivesandfutureresearchalongthislineareproposed．Keywordssodium-ionbatteryanodematerialscarbon-basedmaterialshierarchicalstructures、。、、1。30、、、。EV。SIBs6012LIBs。。311．060．760．3VSIBs。1/2034。15、678。NaxCoO2NaxMnO219－10。11－14、15、16－17。11811988Mireille1930mAh·g－1NaC64。0．42nm18。。20“—”NaC6LiC6+0．03eV/atom＞0－0．01eV/atom＜0。＞0。DFT＜020。、、。2000。StevensDahn9300mAh·g－1。1．1/。。。SIBs“”houseofcardsstructure21。。SIBs。。sp、sp2、sp321－24。。18。、、。25。、。14。26－28。1229。。Hou30、21。0．42nm。2．5A·g－1200150mAh·g－1。7。。Wang31、44－。5A·g－17000200mAh·g－1。15A·g－1175mAh·g－1。。。Wang14CTAB50～70nm2。600℃50mA·g－1180mAh·g－1150。Na+14。aPPybc50mA·g－1d2141．2/。HummersGOSIBs。Wang27KOH。50mA·g－1349．7mAh·g－1260155．2mAh·g－120A·g－150mAh·g－127。。331。Wang28rGO、rGO。0．61nm150mAh·g－11h300mAh·g－15h100mAh·g－1。Na+5h0．37nm1h0．42nm“”。。、“—”、。。。。。200nm～5μm。。Tang12。、、13nm。100mAg－1100200mAh·g－1。Wenzel290．2C130mAh·g－1。。1。。。。10．10A·g－1100380mAh·g－1。1mAh·g－1mAh·g－1320．05Ag－1100243mAh·g－10．20Ag－1210mAh·g－10．50Ag－1175mAh·g－15．00Ag－1100mAh·g－1310．10Ag－1100380mAh·g－10．50Ag－1320mAh·g－11．00Ag－1280mAh·g－115．00Ag－1150mAh·g－1330．10Ag－1100298mAh·g－10．20Ag－1290mAh·g－11．00Ag－1155mAh·g－15．00Ag－170mAh·g－1280．10Ag－1300127mAh·g－10．20Ag－1145mAh·g－11．00Ag－1128mAh·g－1340．10Ag－1100160mAh·g－10．20Ag－1168mAh·g－11．00Ag－1120mAh·g－15．00Ag－175mAh·g－11．3。41。Yan21“”。。。50mA·g－1450mAh·g－1。。。Xu35。3。1C0．02～3．00V852．6mAh·g－1150594mAh·g－1。、。abcd3352IVV。Sb36Na3Sb660mAh·g－1、Sn37Na15Sn4847mAh·g－1、Ge38NaGe369mAh·g－1、PNa3P2596mAh·g－139。Pblackphosphorene。Cui390～1．5V0．05A·g－12440mAh·g－110083%。Xx4aNa3P531yz。4b10C500mAh·g－1。aNa+b－4－3938。。。＞600mAh·g－1Fe2O31007mAh·g－140CuO674mAh·g－141MoO31117mAh·g－142NiCo2O4890mAh·g－143。。Yuan41CuOCuOH2。200mA·g－1400mAh·g－120020%。CuO。。。3。。、。1。。61。。2。。。B、N、P、S。。3。。。。。。1MAＲCAMetal．ElectrochemicalinsertionofsodiumintocarbonJ．JournalofElectrochemistrySociety199314012169－170．2ASHEＲＲCBEＲKSD．ALamellarcompoundofsodiumandgraphiteJ．JournalofInorganicChemistry1959103－4238－249．3DELMASCBＲACONNIEＲJJFOUASSIEＲCetal．ElectrochemicalintercalationofsodiuminNaxCoO2bronzesJ．SolidStateIonics19813165－169．4DIPANKTVICTOＲTLINDAF．N．TheemergingchemistryofsodiumionbatteriesforelectrochemicalenergystorageJ．AngewandteChemieInternationalEdition2014543431－3448．5DELMASCBＲACONNIEＲJJHAGENMULLEＲP．AnewvarietyofLiCoO2withanunusualoxygenpackingobtainedbyexchangereactionJ．MaterialsＲesearchBulletin1982171117－123．6OHSMMYUNGSTHWANGJYetal．HighcapacityO3-typeNaLi0．05Ni0．25Fe0．25Mn0．50．95O2cathodeforsodiumionbatteriesJ．ChemistryofMaterials201426216165－6171．7ANANTHAＲAMULUNKOTESWAＲAＲKＲAMBABUGetal．Awide-rangingreviewonNasicontypematerialsJ．JournalofMaterialsScience20114692821－2837．8GONGZYANGY．Ｒecentadvancesintheresearchofpolyanion-typecathodematerialsforLi-ionbatteriesJ．Energy＆EnvironmentalScience2011493223－3242．9STEVENSDADAHNJＲ．Highcapacityanodematerialsforrechargeablesodium-ionbatteriesJ．JournalofTheElectrochemicalSociety200014741271－1273．10KIMHKIMDJSEODHetal．AbinitiostudyofthesodiumintercalationandintermediatephasesinNa0．44MnO2forsodium-ionbatteryJ．ChemistryofMaterials20122461205－1211．11XUCLIBDUHetal．EnergeticzincionchemistrytherechargeablezincionbatteryJ．AngewandteChemieInternationalEdition2012514933－935．12TANGKFULWHITEＲJetal．Hollowcarbonnanosphereswithsuperiorratecapabilityforsodium-basedbatteriesJ．AdvancedEnergyMaterials201227873－877．13ZHOUJSHENGZHANHetal．FacilesynthesisoffluorescentcarbondotsusingwatermelonpeelasacarbonsourceJ．MaterialsLetters2012661222－224．14WANGZHQIELYUANLXetal．FunctionalizedN-dopedinterconnectedcarbonnanofibersasananodematerialforsodium-ionstoragewithexcellentperformanceJ．Carbon201355328－334．15ZHUYHANXLIUYetal．ElectrospunSb/Cfibersforastableandfastsodium-ionbatteryanodeJ．ACSNano2013776378－6386．16LAMUELDBGUＲPＲEETS．MoS2/Graphenecompositepaperforsodium-ionbatteryelectrodesJ．ACSNano2014821759－1770．17QUBMACJIGetal．LayeredSnS2-reducedgrapheneoxidecomposite-ahigh-capacityhigh-rateandlong-cyclelifesodium-ionbatteryanodematerialJ．AdvancedMaterials201426233854－3859．18PANHUILINYONG-SHENGHULIQUANCHEN．Ｒoom-temperaturestationarysodium-ionbatteriesforlarge-scaleele