拉曼分析

4.8.:[215-217][14]1332cm-1T2g1580cm-1GE2g42cm-1E2g1580cm-1G1350cm-1DA1gK[218]sp1C-C2100-2200cm-1219GD[219]sp3121100-1200cm-11400-1500cm-1[220]χ0()(,)dkQdqχχχ=+kq(39)kχQq(,)wk(,)wk′′ww′2()Ckχω∂=∂40E(virtualstate)realstate[220]kVDOSG()matrixelementC(()1()()()nICωωωω+=GωSi[221-223]a-C12GDGDDDinterference3D[229]GDDTuinstraKoenig[218]DGI(D)/I(G)La35()()aIDcIGL=42I(D)/I(G)0aL=ta-C35nmaL[219230]2()()aIDcLIG=43GI(D)/I(G)Tuinstra-Koenig4336GDC-HC-HLorentzianBreit-wigner-FanoBWFGLorentzianD[219]BWF20020[12()]()1[2()]IQIωωωωω+−Γ=+−Γ44I0LorentzianQ=∞max02QωωΓ=+(45)Ferrari[219]12sp23sp2sp31confinement1aqL∆=381580cm-1LaTuinstra-Koenig12[232]392sp2[233]G37aLnmI(D)/I(G)02a-C[234]3sp30100%sp2[219233]1640cm-1121580-1600cm-1[235]3GD0[219]]40sp3G[236]GGsp3G[236]3I(D)/I(G)0Gsp3sp3GDG50nmnmaL41GLaKnight[215]Lespade[237]Schwan[238]C-H[4239-244]42a-C:H5PECVDa-C:HHsp3HC=Csp2Csp3=CH2CHC-Csp2a-Csp3ta-Csp2sp2[219]a-C:Hsp2[14]a-C:Hsp2DHa-C:Hsp33eVDsp2a-C:H23a-C:Hsp3sp3GGHG43a-C:Hsp3Gta-Csp3GTamorVassell[240]G44a-C:Hsp3[151]a-C:Hsp3I(D)/I(G)Gsp3a-C:Hsp3GI(D)/I(G)43a-C:Hsp3EELSsp3[219]ta-C:Ha-C:Hsp3ta-C:HGa-C:Hta-C:Hsp2C=Ca-C:HG45Dta-C:Hta-C:Hta-Csp3ta-Csp2NMRsp3ta-C:Ha-C:Hsp3