吉林省沸石的性质与应用

©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[]2004O03O04;[]2004O05O18[](1954-),,,11,2(1.,130061;2.,130061)[],(),,,,[];;;[]P578.974[]A[]1001O2427(2004)03O0072O112050,,1978,,3,641111,11111,,60%90%30%70%,,,NH+470199ml/100g;37166ml/100g11112,23320049JILINGEOLOGYVol123,No13Sep1,2004©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:,;112Na[AlSi5O12]4H2O:,01020105mm3154,2115,,Ng=11476,NP=11472(-)2V=60070Na+K+,Ca+Si/Al=41255125(CaNa2K2)[AlSi5O12]27H2O:01010103mm34,2115()2V=70104b,219517Na+,Ca+K+Si/Al=41175100Na[AlSi2O6]H2O:,5515,212421292110Na+AgTiPb,Si/Al=21002190,,:a.50%80%,,5%10%,5%10%,5%b.40%50%,10%20%,5%10%,1%,c.30%50%,5%10%,5%10%,20%30%X,,1NH4+,34%70%,80%:NH4+150ml/100gNH4+115ml/100g,NH4+21138ml/100g113:SiO26618%,71153%373:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.()Fig11X-raydiffractogramofzeoliteSiO274145%,4%K2O+Na2O5194%,K2O+Na26109%7119%1%,,,11411411,3:K+\Na+,CaAl\NaSi,Ca2+\2Na+NH4+K+,,,,,,K+,K+19117mg/100g,23100mg/100g,K+18180mg/100g,20140mg/100g;K+13158mg/100g,18180mg/100g,K+(142018mg/100g),2160ÜANH4+2186ÜA,NH4+2160ÜACuCrCd,11412,811910142,,:90430;510686,,842916,472004©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.()Fig12Differentialthermalanalysispatternofzeolite700,750,800,(2)114135001000m2/g,,,,,,100m2/g,100m2/g317506m2/g(),11414,,,,,,11415,,,81215216219,80%2,,:211,,:573:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:X30%40%:a.b.11Table1ChemicalcompositionsofsoilpH(%)N(%)NPmg/100gP(%)PPmg/100g101450101515187015421889115211401027718501830175:22Table2Solublesaltmeancontentofsoil(%)CO2-3(/100)HCO-3(/100)SO2-4(/100)Cl-(/100)K+(/100)Na+(/100)Ca2+(/100)Mg2+(/100)016721053801062113690108441802012301378010130119201001814010119301594010010111880100101320168501021114830109021573101124011134010040102201001211136010490121780100401158401002:21111a.:111512kg,313g,616g120,550g310%(450g550g),39,317,330,10,62033Table3Testingresultofwheat(g)(g)(g)(g)17120172661670170183618119141162101710132145212310182155:672004©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(cm)()(g)CK161131CK210162217CK3131331216931(71)6514018184142911482(59)6019663118811141411524159312713(29)63118161326138:b1:10,412g,314g,114g101710%,99,16,1029,12,55Table5Testingresultofcorn(cm)(cm)(g)(g)CK12515012CK222152418301150114CK326150107134015247154116701650178334315112:21112,621113,,,CO2-3,Cl-SO2-4,Ca2+Mg2+K+,Na+773:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(%)(%)/100%(%)/100%(%)1715135159131921165103126631043114566130411531221826218319710653138515211150104521330109121050108041350117102122112150:21114,90%,1%5%,1%4%,1%85%,2%,1%3%,2%3%,1%330150150900,21115pHpH,pH(7)7pHTable7pHchangingofsoiladdedzeolite1025pH1027pH111pH91158148131%81958128112%91008117193%910071971755%910071871610%817071571415%816071371320%8160713712:,,,,872004©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:6101cm2,510cm2,410,,:a1,,28(20130)1011325kPa,325,286131011325kPab12341min,2344min,c13514%5913%7714%100%6416%,100%,,15%25%,,117%120%,15%35%,112%45%129%139%45%33%34%;45%26%36%,,,28:30%,3001011325kPa,2071011325kPa40%,3251011325kPa,1401011325kPaNH+4100mg/100g,30%,4251011325kPa,40%3251011325kPaNH+4100mg/100g,30%,400,NH+4100mg/100g,,,15%25%25%40%,40%55%21212,,,,,,973:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(300),,388Table8Testingoftheproducedgasvolumeofconcreteafteraddedzeolitemg/100g15711513319497193ml/100g4434133301344162818:,,NH+499Table9TestingresultoftheproducedgasvolumeofconcreteafteraddedSantaizeolite,JilinProvince(g)(g)(g)(g)(g)(kg/m3)(kg/m3)450450181901424312013571090540360290142391601300101063027038170142261451320103072018047130142101501300:2132070,,,,,,,,WFD-7G:0180(2151146m),0185(3)214082004©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.()Fig13Clinoptiloliteinfraredradiationpattern21411;,,;;21412,,,4,,,,,:,,[1].[M].:,1980.[2].[R].1983().[3],.[M].().[4].[R].1988.ThepropertiesofthezeoliteofJilinProvinceanditsapplicationZHANGNingOke1,WEIWei2(1.GeologyDataMuseumofJilinProvince,Changchun130061,China;2.BureauofGeologicExplorationandMineralDevelopmentofJilinProvince,Changchun130061,China)[Abstract]Thezeoliteisakindofnonmetallicmineralasmulti-purposeutilizationrecent2ly,throughthemeasurementforzeolitetype,mineralcharacteristics,chemicalcombination,183:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(thermalstability,specificsurfacearea),explainingitsappliedpossib