烯烃的环氧化反应

19994(GuangzhouChemistry)1999No.4X(510650):,:,,,:O6230,,,,,,,1N.Prilezhaer1908,1.1,[13](polymericperacid)[4][5][6],-,-2,4-[7]X:1999-03-30©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(orthovanadicacid,H3VO4)[8][9]-1,2-,,[10](benzeneperoxyseleninicacid,C6H5Se(O)OOH)[11]2(Dioxiranes),[12],,,-,,(pH=7.58.0),,(Dimethyldioxirane)(KHSO5)[13]33.1,,,N,N-,,C5C62-70%80%()[14],,,051999©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[15][16]3.2-[17]VBVBVBVB(Mo),[18]()(ORe(P)OMe;P=5,10,15,20-),()[19]4P-450,,()[Mn(TPP)OAc]/,,80%(pH=13)[20],,Burrows[21],,Ni(salen)(),,Yamazaki[22]Ni(),Ni(bpy)2Cl2Ni()[23],,,,(TO),(M=O),,,(),(),(),()()15No.4:©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(C6H4(CO)2NH)Mn()1,2-[24](NO2,NO+,NO),[25],401-,1,2-[26]5.2,,Co()Ni()V()Fe()Mn(),Ni()--,34atm75100,Ni()--Mn(),[27](RuRhPaTiSm)(Pd/HzTiO2KTiOPO4),(40),(P=0.1Mpa)-2-(1-)3-3-[28],(NH4)5H4PV6Mo6O40,,3--3--1-()24h94%[29]6,P-450,,()P-450P-450,,,P-450[30],Ru()-EDTA-Vc(C)-,O-O,O,251999©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[31]-2--1-(),Mn(),():,[32]7,,,,,,,,,1HildonAM,GreehalghPF.GerOffen,2,602,776.19762CaldwellAN.BP,1,589,066.19813BerkowitzS.GerOffen.2,812,573.19874HarrisonCR,HodgeP.ChemSoc,PerkinTrans,1976,1:6055PerchugovGY,SakolovNA,AleksandlovYA.USSR,620,484.19786OrekhovVM,RudenkBM.IzvVysUchebZaved,KhimTekhnol,1979,22:7277RastetterWH,RichardTJ,LewisMD.JOrgChem,1978,43:31638BegMA,AhmadI.IndianJChem,1979,15B:6569BadaryanGV,GabrielyanSM,KamalovGL,etal.ArmKhimZhur,1980,33:79410OgataY,TomizawaK,IkedaT.JOrgChem,1979,44:236211HoriT,SharplessKB.JOrgChem,1978,43:168912(a)MurrayRW.ChemRev,1989,89:1187(b)AdamW,CurciR,EdwardsJO.AccChemRes,1989,22:20513DenmarkSE,ForbesDC,HaysDS,etal.JOrgChem,1995,60:139114ItoiY,InoueM,EnomotoS.BullChemSocJpn,1985,58:319315VenturelloC,AloisioRD.JOrgChem,1988,53:155316MasakiY,MiuraT,MukaeI,etal.ChemLett,1991,11:193717FarberovMI,BobylevBN,EpshteinDI.GerOffen,2,300,204.197318ClarkeR,Cole-HarmiltonDJ.JChemSoc,DaltonTrans,1993,12:191319ShumWP,KeslingHS.USPatent,5,103,027.199220SamelEG,SrinivasanK,KovhiJK.JAmChemSoc,1985,107:760621YoonH,BurrowsCJ.JAmChemSoc,1988,110:408722YanazakiS,YamazakiY.BullChemSocJpn,1991,64:318535No.4:©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(1):495224MasuiM,TsuchidaK,KimataY,etal.ChemPharmBull,1987,35:307825BoschE,KochiJK.JAmChemSoc,1996,118:131926YamanakaI,NakagakiK,AkimotoT,etal.ChemLett,1994,9:171727YamadaT.Petrotech,1994,17:12128AtlamsaniA,PedrazaE,PotvinC,etal.CRAcadSci,Ser,1993,317:75729IshiiY.JPPatent,05,255,292.199330DaryoushM,ShahramT.JChemSocChemCommun,1993,3:24031TaquiKhanMM,ShuklaRS.JMolCatal,1992,72:36132FuHong,LookGC,ZhangWei,etal.JOrgChem,1991,56:6497EpoxidationReactionofAlkenesZhangNanyan,ChenLiban(GuangzhouInstituteofChemistry,ChineseAcademyofSciences,Guangzhou510650,China)Abstract:Inthispaper,severalkindsofepoxidationreactionsofalkeneswhichareclassifiedbyoxygenresourcesarediscussed.Theprogressinthestudyisreviewedandthetrendinthestudyispredicted.Keywords:alkene,doublebondofcarbon,epoxidation,epoxide451999©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.