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-97-1.2L-FCCL3502.2L-FCCL-98-1.2.MPI3.MPIADABAMPI/DABA2L-FCCL2L-FCCL1.2.MPI3.MPI2L-FCCL-99-11.1.1Ø(1)Ø(2)1.11.1.2§1908BogertRenshaw4-4-2040§§“1.1-100-1.1.3§§(1)250250250300§(2)§(3)400500§(4)§(5)1.11.1.4§(1)§(2)KaptonUpilexApical§(3)§(4)§(5)§(6)§(7)§(8)///§(9)§(10)TN-LCDSTN-LCDTFT-LCD§(11)-1.1-101-1.1.5(1)(2)(3)1.11.21.2.1n250-270Diels-AlderLubowitznT.T.SerafiniPMRPMR-151.10PMR-15-102-COCCCCOOOOCH2H2NNH2CCOOCH3OHOCH3OHH3COHO2+3.087+2.087-H2O-CH3OH204,1hrCCOCCNOCH2CCNCCNCOOCH2n316,1hrPressPMR-15Polyimide1.10PMR-151.21.2.2§§1987M.A.ChaudharRD86§A.Mathur§3001h1.2N-103-1.21.2.3§Ø(1);Ø(2)n1.11.2-104-Ø1.2.3.2§§200Tg1.2Ø1.2.3.1§30§1974NormanBilow3-APAHR-600§A.L.Landis§N.BilowA.O.Hanky3-4-3-(3'-)1.2-105-1.2.4BMI§BMI§BMI2500.7MPa1.21.2.5§120-150§G.W.Meyer2.00Kg/mol-15.00Kg/mol200Tg5055001.2-106-1.2.72,2-§2,2-§Sutter2,2-6FDA2,2-T-40R(N-CYCAP)Tg3863711.21.2.6§BCBBMI§TLoonSend§1.2-107-1.2.8§§K.C.Chuang12FTg§NASAV-CAP-751.2l1.2.9§§4002001.2-108-1.2.10§GaetanoFrancisD‘AlelioDMAc250§1.21.2.11§RobertF1.2-109-1.2.12A-R-B§§MargaretKTg4001.21.2.13n1.2-110-CNHCSOSONNOOOOCOONHCONHNCH(CH2)nPOOSiOCH3CH3H2CCHOHCH2mR1R2CCH3CH3RCCH3CH3CCH3CCF3CF3CCF31.31.3.1nn---1.14n1.141.3-111-1.41.4.1nFCCL3L-FCCL2L-FCCLnFPC1.3.2§BMI§O,O'-A170-230-112-1.41.4.2§2L-FCCL15%-20%,3L-FCCL80%-85%2L-FCCL3L-FCCL1.5-22L-FCCLFPCCOFChiponFlexFPC2L-FCCL§2L-FCCL3L-FCCL200440%60%200652%48%2L-FCCL40%3L-FCCL25%1.4.3§FCCLFCCLFCCLFCCL§FCCLNipponSteelNikkan§FCCL§FCCL1.4-113-1.5§BMI§2.7kgf/10mm3001.4.4§FCCLPCBFCCL§FCCLFCCLFCCLFCCL1.4-114-§TakeshiHashimotoO,O'-A2.9-3.61.7kgf/10mm1.5§ShurFenLiuBMI//PPETg2003.83§OOTAKBMI§SUZUKIABMI1801.5h1.5-115-§BMI§TAKEOKAYOSHIKI§YAMASHITASHINSUKE5:955.8N/mm1.51.61.6.1§1,4-(4-)-2-BATB1,4-(4-)-2,5-BADTB1.16ab§-116-1.61.6.2MPI§§1.6-117-21.6.3§ADABA§§MPI/DABA2L-FCCL2L-FCCL1.6-118-2.22.2.1Ø(1)Ø(2)Ø(3)Ø(4)2.1(1)1,4-(4-)-2-BATB(2)1,4-(4-)-2,5-BADTBNO2ClOHCOH+K2CO3/DMF/NO2OCOH2NNH2·H2O/FeCl3·6H2O/CNH2OOCNO2NH22NO2ClOHCOH+K2CO3/DMF/NO2OCOH2NNH2·H2O/FeCl3·6H2O/CNH2OOCNO2NH22CCCBATBBADTB2-119-2.22.2.2(1)(2)(3)(4)2.3.1§BNTB148-149§BNTB154§BATB129-130§BATB1342.3BATB-120-2.3.2BNTB99.92BATB99.67%2.3BATB2.3.4BNTBFT-IRBATBFT-IR350030002500200015001000500-20020406080100%TransmittanceWavenumbers(cm-1)2960.852870.591591.791515.611480.391405.951341.531237.083111.843082.26847.571077.712.5BNTBFT-IR350030002500200015001000500-2024681012%TransmittanceWavenumbers(cm-1)3457.093370.163393.593308.793201.413042.892954.572867.861627.291504.891479.881404.941272.441206.561079.872.6BATBFT-IR2.3BATB-121-2.3.51H-NMR§BNTB1H-NMR§BATB1H-NMR2.7BNTB1H-NMR2.8BATB1H-NMR2.3BATB2.4BADTB§BNDTB273-274§BNDTB274§BADTB247-248§BADTB247u2.4.1-122-2.4BADTB%TransmittanceWavenumbers(cm-1)3114.483088.912961.072869.461588.571517.131483.481399.031375.101341.051234.461025.27851.872.11BNDTBFT-IR350030002500200015001000500-6-4-202468101214161820%TransmittanceWavenumbers(cm-1)3406.323315.273210.992964.012867.791631.991493.451441.131396.811372.671202.852.12BADTBFT-IR2.4BADTB2.4.2§BNDTB99.67%§BADTB99.90%2.4.3§BNDTBFT-IR§BADTBFT-IR350030002500200015001000500-20020406080100-123-2.4.41H-NMR§BNDTB1H-NMR§BADTB1H-NMR2.13BNDTB1H-NMR2.14BADTB1H-NMR2.4BADTB3.1BMI§Ø(1)Ø(2)Ø(3)-Ø(4)3-124-3.1.1§OOO+OH2NNH2OOOOOOOOONH2COH2Nnn(n+1)2OONNOOOOOnNNOOOOOCOHOCCOOOHOOCOnNHOCOHOCCOONHOHOOOONHOHHONHAc2O/Et3N,6hRoomTemperature60RoomTemperatureNHNH3.1MPI3.1BMI3.1.2OOCH3CH3OOOOOONH2OOCNH2++OONMP/Toluene(2:1)N2,RoomTemperature12hOCH3CH3OOOOOHONHOHOOOOHONHOOCNHOONHOHnNMP/Toluene(2:1)N2,13024hOCH3CH3OOOOOOOCOOOOCNnNOO3.2MPI3.1BMI§-125-3.1.4§OCOOOOH2N+HNNHOOOOn2n(n+1)+R2R1OOOOOOR2NR1NOOOOR2NH2NMP/O-DCBROHR1OOOOOHHOROOR160180nR2NR1NOOOOR2H2NNH2OHHONMP/Toluene130NNOOOOnR2NR1NOOOOR2R1=OCOCH3CH3R2=3.3MPI3.1BMI3.1.3-§13013024h3.1BMI-126-Wavenumbers(cm-1)30983072177717131607150013781241745691745154817821718160413793063abc3.2(2)3.2.13.2-127-(3)GPCMn=0.87Kg/mold=1.623.2.13.23.2.25.50Kg/molMPIBPADA/BATB/MAFT-IR3500300025002000150010005000.300.350.400.450.500.550.600.65%TransmittanceWavenumbers(cm-1)3068.522964.232867.271777.991723.081378.04743.85692.083.7MPIFT-IR3.2-128-3.2.3-§(1)690cm-1C-H350030002500200015001000500-20246810121416182022%TransmittanceWavenumbers(cm-1)3375.783483.411777.271720.741379.32744.703.8-MPIFT-IR3.2(2)10-6=4.1ppm4.3ppm2:13.2.3-3.9-MPIODPA/ODA/MA1H-NMR3.2-129-Michael3.2.3-H2NR1NH2OOH2NR1NHOO3.10Michael3.2(3)ODA/MAFT-IR35003000250020001500100050050607080%TransmittanceWavenumbers(cm-1)3438.503352.092930.652879.171719.151673.441403.911300.17657.55845.933.11-ODA/MAFT-IR3.2.3-3.2-130-(4)DSCMPIODPA/ODA/MA=0.83Kg/molDSCTg221.883.2.3-3.12-MPIODPA/ODA/MADSC3.23.2.4(1)FT-IR35003000250020001500100050002468101214161820%TransmittanceWavenumbers(cm-1)3436.893359.881776.261719.30744.211379.813.13ODPA/ODAFT-IR3.2-131-(2)1H-NMR3.2.43.14ODPA/ODA1H-NMR3.2(3)FT-IR3.2.43500300025002000150010005000.350.400.450.500.550.600.650.70%TransmittanceWavenumbers(cm-1)3068.812964.252871.601778.121723.161377.51744.18694.333.15MPIBPADA/BATB/MAFT-IR3.2-132-3.3.1(1)10-6=12.335ppm-OH10.603ppm10.685ppm6.170ppm-6.238ppm3.3(2)3.3.13.3-133-3.3(3)3.3.13.3