费托合成技术应用现状与进展-周从文

1。1923FischerTropsch400℃~455℃10~15MPaCOH2。19251926250℃~300℃。[1]。159411。[1]。70。。22.1SASOL50SASOL。SASOL。SASOL、、、1。SASOL。SASOLOryx。。Oryx20062008。2.2Shell[4]ShellF-TShell。。1993ShellBintulu12500/d4017209。,、。。TQ531674-8492201004-093-04220CARGE19550%23%7%70%、。SasolburgSasolI2500/d250℃SSPD1993、。SasolburgSasolI2500/d230CSSPD20062%0%8%90%、80%C5+。RusLaffanOryx34000/d340CSynthol19556%56%25%10%。。SasolburgSasolI1500/d340℃SAS1995SecundaSasolIISasolIII150000/d1SASOL[2-3]2615026mm。1997Bintulu2003BintuluShell14700/dShell。ShellRusLaffanPearl140000/d242938626mm。ShellGTL。ShellH2S。2a。2.3RentechRentech1981。Rentech。RentechH2/CO0.67~3.5、、、、1。Rentech。Rentech610/d。Rentech。494··2.4SyntroleumSyntroleum1984“”。ATR1997。2005SyntroleumEastmanChemical200711Syntroleum2500h。2。2008Syn-troleum。SyntroleumBio-SynfiningTM。2.52006、、、。70219971997。1997、、、[7]。1997。ICCIICCII[8]。ICCIFe-Cu-KICCIIFe-MnICCIICC-IICC-II。2000200242005ICC-IICC-II。2006、16～18t/a。2009－18t:;;;;;。。ICC-IIIA、ICC-IIIB、ICC-IIIC。2009。Rentech＇slronCatalystvsCobaltFeedstocksCatatystsPetreumCokeOrimutionCoalNaphthaVacuumRosidFuelOilAsphaltindustrialOff-GasNaturalGas+SteamNaturalGaslowBTUNaturalGaslronCobalt3.53.50.60.81.01.21.41.61.82.0H2:CORatio1Rentech[5]42[6]4.03.02.01.0CatalystAcivityOn-StreamTimeDays2030405060708090100LowerOpetatingRangeUpperOperatingRangeOppbContaminationBaselineContamination100XBaselineContamination10XBaselineContamination95··2.6200212[9-10]200420075000t/a。SASOLSASOL。2.72006、、、80t/a20103“”。18t/a2009。3、、。。。1.[J].2003.2M.E.Dry.Fischer-TropschTechnology[J].In:A.P.Steynbergeds.Studiesinsurfacescienceandcatalysis152.Elsevier2004.3AndreSteynberg.SasolCTLdevelopment[J].-MTSymposium10-18-05.4://[J].22(4)2003.8.[J].20022.9://。TheStateoftheartreviewofFischer-TropschSynthesisTechnologyZHOUCongwenLINQuanShenhuaOrdosCoalLiquefactionCorporationOrdosInnerMongolia017209ChinaAbstractThecurrentapplicationanddevelopmentofFischer-Tropschsynthesistechnologieswerereviewedinthispaper.BycomparingthedifferenttechnologiesitwasfoundthattheprevailingFischer-Tropschprocessesarehightemperaturefixedfluidizedbedreactorwithiron-basedcatalysttechnologylowtemperatureslurryreactorwithiron-basedorcobalt-basedcatalysttechnologyandlowtemperaturetubularreactorwithcobalt-basedcatalysttechnology.Nowindustrialapplicationsofiron-basedcatalystusinglowtemperatureslurryreactortechnologyaremainlyinChinaforthistechnologyissuitablefortheproductionoffueloilbycoal-basedsynthesisgas.KeywordsFischer-TropschsynthesisIndustrialapplicationDevelopment2010-07-28496··