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339硅酸盐通报Vol．33No．920149BULLETINOFTHECHINESECEＲAMICSOCIETYSeptember2014张万友，李瑶，郗丽娟132012。。TB332A1001-1625201409-2249-05ＲesearchProgressonHydrotalcite-LikeCompositeMaterialinIndustrialWastewaterTreatmentZHANGWan-youLIYaoXILi-juanSchoolofChemicalEngineeringNortheastDianliUniversityJilin132012China1957-．．AbstractHydrotalcite-likecompositematerialhasdrawnwidespreadconcernrecentlybecauseoftheperfectadsorptionperformanceandthephysical/chemicalproperties．Thispaperintroducedthepreparationofhydrotalcitecompositematerial．Ｒeviewdtheresearchsituationandapplicationsofhydrotalcitecompositematerial．Simultaneouslythefutureresearchonindustrialwastewaterofcompositematerialwasprospected．Keywordshydrotalcite-likecompositematerialindustrialwastewateradsorption1。、、1。、、。、、。、。、、。HTLCs、“”2-6。、、、、、3。225033。、、。。22．1、、。7。、、、、78。、。9。10。2．22．2．1、1112。Yamada13pH1024h150℃、、、MgAl-HTLCs、。MgAl-HTLCsMgAl-HTLCs。、C60、CNT14。。。Meng15CNTsZnAl-HTLCsZnAl-LDO/CNTs。。、。16MgAl-HTLCs/。153．6mg/g。2．2．2CO2。TiO2、ZnO、SnO2、CdS。1718。、。TiO2、、。TiO217-21TiO2TiO292251。Huang18TiO2500℃SDSSDS-HTLCs/TiO2、DMP1∶1。22HTLCs。23。Bi24HB-HTLCsMBHB-HTLCs30．87mg/g。33．1。Cd2+、Pb2+、CrⅥ25Citrate/HTLCsEDTA/HTLCsXＲDIＲC6H5O3－7、edta4－Cu2+Cd2+95%。pH。Yuan26/C/MgAl-HTLCsCrⅥMgAl-HTLCs1．0g/LCrⅥ172．55mg/g。3．227。Zhang28/MgAl-HTLCsSEMLDHs1h410mg/g。Kostas29MgAl-HTLCs350mg/g。3．3301．0mg/L。Zhang31CeO2/MgFe-HTLCsMgFe-HTLCs60．4mg/g。Mandal32HTLCs2～4。3．4、、36。37ZnFe-HTLCs。1～2mg/LWu38/646．7mg/g。3．5、、225233。Valente39CeO2MgAl-HTLCs50%Seftel40CeO2/ZnTi-HTLCs750℃90%。4041。41、。、、2、、3、。1ZhaoMQZhangQHuangJQetal．Hierarchicalnanocompositesderivedfromnanocarbonsandlayereddoublehydroxides-propertiessynthesisandapplicationsJ．Funct．Mater20111-20．2GohKHLimaTTDongZL．ApplicationoflayereddoublehydroxidesforremovalofoxyanionsAreviewJ．WaterＲesearch2008421343-1368．3．J．20123811256-259．4LiFDuanX．ApplicationsoflayereddoublehydroxidesJ．StructureandBonding2006119193-223．5GohKHLimTTDongZL．ApplicationoflayereddoublehydroxidesforremovalofoxyanionsAreviewJ．WaterＲesearch2008421343-1368．6WangQDermotO＇Hare．ＲecentadvancesinthesynthesisandapplicationoflayereddoublehydroxideLDHnanosheetsJ．ChemicalＲeviews201117-26．7SunYYLiuYQZhaoGZetal．AssemblyofsilvernanoparticlesintohollowspheresusingEuIIIcompoundbasedontrifluorothenoyl-acetoneJ．NanoscaleＲesLett2008382-86．8YuanYJPyatenkoATSuzukiM．Self-assemblyofmicellesintodesignednetworksJ．NanoscaleＲes．Lett．20072119-122．9．J．2013327121-126．10ZhangTZhouYMBuXHetal．Bio-inspiredfabricationofhierarchicallyporousMg-AlcompositesforenhancedBSAadsorptionpropertiesJ．MicroporousandMesoporousMaterials201418837-45．11ＲustamovSM．Dealuminatedzeolitesinsorptiontreatmentofindustrialliquidwastestoremovealkylbenze-nusulfonatesJ．ＲussianJ．Appl．Chem．200881146．12BarbaraMetteHennerKerskesHaraldDrücketal．Experimentalandnumericalinvestigationsonthewatervaporadsorptionisothermsandkineticsofbinderlesszeolite13XJ．InternationalJournalofHeatandMassTransfer201471555-561．13HirohisaYamadaYujiroWatanabeTadashiHashimotoetal．SynthesisandcharacterizationofLindeAzeolitecoatedwithalayereddoublehydroxideJ．JournaloftheEuropeanCeramicSociety201426463-467．14．J．．201332728-32．15LanMFanGLSunWetal．SynthesisofhybridZn-Al-Inmixedmetaloxides-carbonnanotubescompositeandenhancedvisible-light-inducedphotocatalyticperformanceJ．AppliedSurfaceScience2013282937-946．16．/D．2012．17SeftelEMMertensMCoolP．TheinfluenceoftheTi4+locationontheformationofself-assemblednanocompositesystemsbasedonTiO2andMg/Al-LDHswithphotocatalyticpropertiesJ．AppliedCatalysisBEnvironmental2013134-135274-285．18HuangZJWuPXLuYHetal．Enhancementofphotocatalyticdegradationofdimethylphthalatewithnano-TiO2immobilizedontohydrophobic92253layereddoublehydroxidesAmechanismstudyJ．JournalofHazardousMaterials2013246-24770-78．19ZohraBouberkaKhalilA．BenabbouAichaKhenifietal．DegradationbyirradiationofanAcidOrange7oncolloidalTiO2/LDHsJ．JournalofPhotochemistryandPhotobiologyAChemistry201427521-29．20XuXLuＲJZhaoXFetal．FabricationandphotocatalyticperformanceofaZnxCd1-xSsolidsolutionpreparedbysulfurationofasinglelayereddoublehydroxideprecursorJ．AppliedCatalysisBEnvironmental．SCI2011102147-156．21HwangSJGunjakarJLKimTWetal．Mesoporouslayer-by-layerorderednanohybridsoflayereddoublehydroxideandlayeredmetaloxidehighlyactivevisiblelightphotocatalystswithImprovedchemicalstabilityJ．J．Am．Chem．Soc．201113314998-15007．22JaouadAMarionEBenoitL．SynthesisofV-containingKegginpolyoxometalatesVersatilecatalystsforthesynthesisoffinechemicalsJ．CatalysisToday2008138117-122．23．D．2012．24BiBXuLXuBBetal．Heteropolyblue-intercalatedlayereddoublehydroxidesforcationicdyeremovalfromaqueousmediaJ．AppliedClayScience201154242-247．25D．2011．26YuanXYWangYFWangJetal．Calcinedgraphene/MgAl-layereddoublehydroxidesforenhancedCrVIremovalJ．ChemicalEngineeringJournal2013221204-213．27YangKYanLGYangYMetal．AdsorptiveremovalofphosphatebyMg-AlandZn-AllayereddoublehydroxidesKineticsisothermsandmechanismsJ．SeparationandPurificationTechnology201412436-42．28ZhangMGaoBYaoYetal．Phosphateremovalabilityofbiochar/MgAl-LDHultra-finecompositespreparedbyliquid-phasedepositionJ．Che