天然橡胶纳米复合材料的研究进展

专论综述,20110625,21(3):70~74CHINAELASTOMERICS:2011-04-19:(1988-),,,,*:(50773013)***李乐凡1,李思东2,汪志芬1**(1.,570228;2.,524088):综述了天然橡胶纳米复合材料的研究进展,分别介绍了天然橡胶与纳米级二氧化硅有机蒙脱土碳酸钙氧化锌以及碳纳米管等物质组成的复合材料的研究现状纳米填料的应用不仅可以改善天然橡胶的性能,而且还赋予橡胶许多新的性质,提高了橡胶产品的性价比:天然橡胶;复合材料;纳米复合材料:TQ332.5:A:10053174(2011)03007005(NR),,,NR,,,NRNR1NR/[1]NR/,,-(MPS),,(MMA)MPS,,(PMMA)(TEM),PMMA,PMMA,SiO2-,MMASiO20.3,MMA,PMMA,MMASiO23100nm,,PMMA,,0.5%,30~60nm,,,3%,,,0.5%,,,[2]NR/,NR35%,[3](SDS)SiO220%,SiO2,,SiO23~4,,SiO2[4]SiO2,,SiO2/NR,2NR/[5]NR/(NR/OMMT),(FTIR),(OM)(MMT),,MMTNR(Ts)(T90),NR;TsOMMT,T90,OMMT[6],,NR,[7]NR/OMMT,TEM,MMTNR;,MMT12,MMT,[8],NR/OMMT,,NR3%~5%(),,[9]NR/OMMT,,[10]NR/OMMT,,NRMMT/NR,[11],(RH),NR/MMT,NR,NR[12]MMT(CAB),OMMT,OMMTNR,CABOMMTMMT;OMMTNR,;OMMT[13],NR/OMMT,2%~10%()OMMTNR/MMT40%()N770[14]NR/OMMT,,(3),,-,[15]4NR/MMT,[16],,NR/OMMTX-(XRD)TEM,(DMA),,60tan,;NR[17]/NR,,,,,3NR/[18]TEM,,[19](ENR),5,(G)(tan);MH,ts1,5~20ENR;ENR,20~40ENR713,.[20]NR/(CCR)NR/(M-CCR),CCR,M-CCRNR,;NR/M-CCR,M-CCR10,NR/M-CCR[21]M-CaCO3,,M-CaCO3NR,CCR[22](Ln)(Ln2O3)(TM)(TMO)[NCaCO3-Ln(OH)3][NCaCO3-TM(OH)2],NR(NR/NCaCO3),NR/NCaCO3-Sm(OH)3NR/NCaCO3-Zn(OH)2,[23]CaOCO2,CaCO3/NR,,C12H25NaO3S3.0%20(EDTA)0.65%Ca(OH)27.50%Na5P3O100.60%CaCO3CaCO3/NR[24](MG49),CaCO3/NRCaCO3NRCaCO3NR,CaCO3/NR[25]TSCCaCO3NR,CaCO35,17.4MPa19.4MPa4NR/[26]NR,,NR,NR,5[27],,,3%,30,90min,99.83%[28],/NR,,[29]NR,,3,5,[30]NR,100~400nm,;20~60nm,,,TsT90,[31],,,[32],,,,20%[33],80m2/g,,6.25%,6.26%[34],9.00-2016PR,,,7221H,[35],,,,,,NR5NR/[36](CNT)/NR,CNT,NR,CNT/NR,,,CNT;CNTCNT,CNTNR;CNT,CNT,CNT,CNTNR,,CNT,,,CNT,,,CNT,,[37,38]CNT,CNT,[39]CNT-,100NR,NR/CNT,CNTNR,NR,CNT,,CNT,,,-CNT,CNT,,A,300%[40][41](MWNTs),SDS(KH550)MWNTs,MWNTs/(SBR)/NR,MWNTsSBR/NR,,MWNTs,KH550SDSMWNTs,SDSMWNTs,,,,KH550MWNTsSDSMWNTs6NRNR,OMMTCNTNR,,,,NR,:[1],./[D].:(),2010.[2],,,./[J].,2010,(6):152~154,158.[3],,.SiO2[J].,2002,23(6):1~4.[4]./SiO2/NR[D].:(),2004.[5],,./[J].,2010,31(4):5~7,11.[6],,./[J].,2009,19(2):1~5.[7],,,./[J].,2009,30(6):24~27.[8],,,./()/[J].,2008,35(2):1~3.733,.[9],,,./[J].,2008,31(4):290~293.[10],,,./[J].,2007,(5):456~461.[11],,,./[J].,2006,20(1):99~103.[12],,./[J].,2006,29(4):280~283.[13],,./[J].(),2006,34(9):80~85.[14],,,.[J].,2006,26(10):46~48.[15],./SAS[J].,2005,26(1):109~114.[16],,,./[J].,2003,31(4):103~105.[17],,,./[J].,2002,21(2):199~202.[18],.[J].,2008,35(5):19~21.[19],,.[J].,2006,53(2):89~92.[20],,,./[J].,2005,28(5):374~377.[21],,.[J].(),2004,32(3):94~96.[22],,./[J].,2004,27(6):363~367.[23].CaCO3/NR[D].:(),2004.[24].CaCO3[J].,2000,6(3):74~81.[25],.[J].,2001,30(1):9~14.[26],,.[J].,2009,30(5):16~18.[27],,.[J].,2006,27(6):25~27.[28],,./[J].,2003,19(6):119~122.[29],,.[J].,2003,13(3):28~30.[30].(NR)[D].:,2007.[31],.[J].,2007,23(9):28~29.[32].ZnO[J].,2006,35(8):648~649.[33].[J].,2002,22(12):729~732.[34],,,.[J].,2001,48(9):534~537.[35],,.ZnO[J].,2002,19(12):1186~1188.[36],,,./[J].,2005,28(1):40~43.[37],,,./[J].(),2005,45(2):151~154,169.[38],,,./[J].,2005,15(2):5~9.[39],,,./[J].,2005,21(3):156~159.[40],,./[J].,2004,27(6):348~351.[41].//[D].:,2007.ResearchdevelopmentonnanocompositematerialsofnaturalrubberLILefan1,LISidong2,WANGZhifen1(1.CollegeofMaterialsandChemicalEngineering,HainanUniversity,Haikou570228,China;2.CollegeofScience,GuangdongOceanUniversity,Zhanjiang524088,China)Abstract:Theresearchdevelopmentonnaturalrubber(NR)nanocompositematerialspreparedbynaturalrubberwithnanoSiO2,nanoorganophilicmontmorillonite,nanoCaCO3,nanoZnOandcarbonnanotubeswasreviewed.AddingnanofillertoNRimprovedpropertiesandhadnewcharacteristicsofnanocompositematerials.Keywords:naturalrubber;compositematerials;nanocompositematerials7421