化学常用术语

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BET公式BETformulaDLVO理论DLVOtheoryHLB法hydrophile-lipophilebalancemethodpVT性质pVTpropertyζ电势zetapotential阿伏加德罗常数Avogadro’number阿伏加德罗定律Avogadrolaw阿累尼乌斯电离理论Arrheniusionizationtheory阿累尼乌斯方程Arrheniusequation阿累尼乌斯活化能Arrheniusactivationenergy阿马格定律Amagatlaw艾林方程Eryingequation爱因斯坦光化当量定律Einstein’slawofphotochemicalequivalence爱因斯坦-斯托克斯方程Einstein-Stokesequation安托万常数Antoineconstant安托万方程Antoineequation盎萨格电导理论Onsager’stheoryofconductance半电池halfcell半衰期halftimeperiod饱和液体saturatedliquids饱和蒸气saturatedvapor饱和吸附量saturatedextentofadsorption饱和蒸气压saturatedvaporpressure爆炸界限explosionlimits比表面功specificsurfacework比表面吉布斯函数specificsurfaceGibbsfunction比浓粘度reducedviscosity标准电动势standardelectromotiveforce标准电极电势standardelectrodepotential标准摩尔反应焓standardmolarreactionenthalpy标准摩尔反应吉布斯函数standardGibbsfunctionofmolarreaction标准摩尔反应熵standardmolarreactionentropy标准摩尔焓函数standardmolarenthalpyfunction标准摩尔吉布斯自由能函数standardmolarGibbsfreeenergyfunction标准摩尔燃烧焓standardmolarcombustionenthalpy标准摩尔熵standardmolarentropy标准摩尔生成焓standardmolarformationenthalpy标准摩尔生成吉布斯函数standardmolarformationGibbsfunction标准平衡常数standardequilibriumconstant标准氢电极standardhydrogenelectrode标准态standardstate标准熵standardentropy标准压力standardpressure标准状况standardcondition表观活化能apparentactivationenergy表观摩尔质量apparentmolecularweight表观迁移数apparenttransferencenumber表面surfaces表面过程控制surfaceprocesscontrol表面活性剂surfactants表面吸附量surfaceexcess表面张力surfacetension表面质量作用定律surfacemassactionlaw波义尔定律Boylelaw波义尔温度Boyletemperature波义尔点Boylepoint玻尔兹曼常数Boltzmannconstant玻尔兹曼分布Boltzmanndistribution玻尔兹曼公式Boltzmannformula玻尔兹曼熵定理Boltzmannentropytheorem玻色-爱因斯坦统计Bose-Einsteinstatistics泊Poise不可逆过程irreversibleprocess不可逆过程热力学thermodynamicsofirreversibleprocesses不可逆相变化irreversiblephasechange布朗运动brownianmovement查理定律Charle’slaw产率yield敞开系统opensystem超电势overpotential沉降sedimentation沉降电势sedimentationpotential沉降平衡sedimentationequilibrium触变thixotropy粗分散系统thickdispersesystem催化剂catalyst单分子层吸附理论monomoleculelayeradsorption单分子反应unimolecularreaction单链反应straightchainreactions弹式量热计bombcalorimeter道尔顿定律Daltonlaw道尔顿分压定律Daltonpartialpressurelaw德拜和法尔肯哈根效应DebyeandFalkenhageneffect德拜立方公式Debyecubicformula德拜-休克尔极限公式Debye-Huckel’slimitingequation等焓过程isenthalpicprocess等焓线isenthalpicline等几率定理theoremofequalprobability等温等容位Helmholtzfreeenergy等温等压位Gibbsfreeenergy等温方程equationatconstanttemperature低共熔点eutecticpoint低共熔混合物eutecticmixture低会溶点lowerconsolutepoint低熔冰盐合晶cryohydric第二类永动机perpetualmachineofthesecondkind第三定律熵third-lawentropy第一类永动机perpetualmachineofthefirstkind缔合化学吸附associationchemicaladsorption电池常数cellconstant电池电动势electromotiveforceofcells电池反应cellreaction电导conductance电导率conductivity电动势的温度系数temperaturecoefficientofelectromotiveforce电动电势zetapotential电功electricwork电化学electrochemistry电化学极化electrochemicalpolarization电极电势electrodepotential电极反应reactionsontheelectrode电极种类typeofelectrodes电解池electrolyticcell电量计coulometer电流效率currentefficiency电迁移electromigration电迁移率electromobility电渗electroosmosis电渗析electrodialysis电泳electrophoresis丁达尔效应Dyndalleffect定容摩尔热容molarheatcapacityunderconstantvolume定容温度计ConstantvoIumethermometer定压摩尔热容molarheatcapacityunderconstantpressure定压温度计constantpressurethermometer定域子系统localizedparticlesystem动力学方程kineticequations动力学控制kineticscontrol独立子系统independentparticlesystem对比摩尔体积reducedmolevolume对比体积reducedvolume对比温度reducedtemperature对比压力reducedpressure对称数symmetrynumber对行反应reversiblereactions对应状态原理principleofcorrespondingstate多方过程polytropicprocess多分子层吸附理论adsorptiontheoryofmulti-molecularlayers二级反应secondorderreaction二级相变secondorderphasechange法拉第常数faradayconstant法拉第定律Faraday’slaw反电动势backE.M.F.反渗透reverseosmosis反应分子数molecularity反应级数reactionorders反应进度extentofreaction反应热heatofreaction反应速率rateofreaction反应速率常数constantofreactionrate范德华常数vanderWaalsconstant范德华方程vanderWaalsequation范德华力vanderWaalsforce范德华气体vanderWaalsgases范特霍夫方程van’tHoffequation范特霍夫规则van’tHoffrule范特霍夫渗透压公式van’tHoffequationofosmoticpressure非基元反应non-elementaryreactions非体积功non-volumework非依时计量学反应timeindependentstoichiometricreactions菲克扩散第一定律Fick’sfirstlawofdiffusion沸点boilingpoint沸点升高elevationofboilingpoint费米-狄拉克统计Fermi-Diracstatistics分布distribution分布数distributionnumbers分解电压decompositionvoltage分配定律distributionlaw分散系统dispersesystem分散相dispersionphase分体积partialvolume分体积定律partialvolumelaw分压partialpressure分压定律partialpressurelaw分子反应力学mechanicsofmolecularreactions分子间力intermolecularforce分子蒸馏moleculardistillation封闭系统closedsystem附加压力excesspressure弗罗因德利希吸附经验式Freundlichempiricalformulaofadsorption负极negativepole负吸附negativeadsorption复合反应compositereaction盖·吕萨克定律Gay-Lussaclaw盖斯定律Hesslaw甘汞电极calomelelectrode感胶离子序lyotropicseries杠杆规则leverrule高分子溶液macromolecularsolution高会溶点upperconsolutepoint隔离法theisolationmethod格罗塞斯-德雷珀定律Grotthus-Draoer’slaw隔离系统isolatedsystem根均方速率root-mean-squarespeed功work功函workcontent共轭溶液conjugatesolution共沸温度azeotropictemperature构型熵configurationalentropy孤立系统isolatedsystem固溶胶solidsol固态混合物solidsolution固相线solidphaseline光反应photoreaction光化学第二定律thesecondlawofactinochemistry光化学第一定律thefirstlawofactinochemistry光敏反应photosensitizedreactions光谱熵spectrumentropy广度性质extensiveproperty广延量extensivequantity广延性质extensiveproperty规定熵stipul

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