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30320096SpecialPurposeRubberProductsVol.30No.3June2009,,,(,510006):,:;;;:TQ33011:A:1005-4030(2009)03-0079-05:2009-01-27:2006(2006168303):(1983-),,,,,[1,2],,CC,,,,,,;,:(MVQ)(EPDM)(NBR)(HNBR)(CM)(TPV)(CR),,;,[35]1:,,CC3:(1),2;(2);(3)2,OO,5::(DCP)(BPO)1,13,3,5(BPMC)2,52,5()(DBPMH)1,3()(BIPB)1,,,,,[6],,,,,,,,,80303,10,1/31(1)(2)DCP270.4143182,,160,1.251.75BIPB338.5142180,DCP,,,DCP,175,11.5BPMC302.5112155,,DCP,145,24,,DBPMH290.4138177,,,,,170,12:(1)1h();(2)1min()2,,,,,,,,2:1,,(TMPTA)(TMPTAMA)(EGDA)(EGDMA)N,N-(PDMHVA2)(ZDA)(ZDMA),TMPTMATMPTA,,11;PDM,,2,,,(TAC)(TAIC)1,2(1,2PBR)TACTAIC,50%100%;EPDM,,2:2,,,,,;,;2[7,8],Grima[9,10]DCP[N,Nm(BMIMP)][(DPTT)],,N,Np(BMI-PP)BMIMP;4,0.70.9,[11]N,N-(VP4)DCPEPDMVP4(0.52),,;VP4,200981,(150)Jelencic[12]TACEPDMTACEPDM,,TAC[13]CM,TACTAIC,,TACTAIC,2,[14]DCPTAICEPDM,EPDMDCP,TAIC;,[15]EPDM/(1,2PBR)EPDM/BREPDM1,2PBRBR,100%A,;,EPDM/1,2PBREPDM1,2PBR:1,2PBRBREPDM,1,2PBRBREPDM,EPDM/1,2PBREPDM/BR[16]EPDMTPV,1,2-PBR;EPDMTPV,1,2PBRPP,EPDMTPV[17]TMCH[11()3,3,5](VP4),TAIC,TMPT2MA,HV2268(),HV2268(1.2,TAIC1),,;,,,(15020min),33.1,,,EPDMDCP,DCP/;NBRHNBRDCP,BIPB,BPMC,3m,DBPMH;,BRSBR,DCP,DCP():SBR,12.5;BR,10.5;NR,1;NBR,1;CR,0.5;EPDM,1;(IIR)DCP,NBR,,,,DCPNBR18,NBR26,NBR402,1.75,1.5,[18]DCPCM135BDCP3.54.5,DCP,,,,,,,(Mc),;,,,,,;,823033.2,BPO1h92,,;,DCP,DBPMH,,Nakason[19]NR/PP(TPV),PP,,2,52,5()3(DTBPHY)2,52,5()(DTBPH),()(DTBPIB)DCPNR/PP(60/40)TPV160C180C,DCPDTBPIB160C,2180C,DCPDTBPIB,2DTBPHYDTBPH,,NR/PPTPVGonzalez[20]NBRHNBR,,,DCP,,,3.3,,,,,BPO,,,DCP(),(DCP),,,,,:,:,,(2)0.51,(ZnO,MgO)0.51ZnO(DCP),RD(2,2,41,2)MB(2)DCP,DCP:2(MBT)(HMT)(ZEPC)(ZDEC)(DPG)N2(CBS)(TMTD)(ETU)3.422,,,,[21](DCP)EPDM/NR,,;DCPTAIC2EPDM/NR/ENR()30/68.5/1.5,200983;NRDCPTAIC12,[22]DCPNBR/(ZDMA),DCPNBR/ZDMA,;DCP1.50.6,,,,,,,,[23]HVA2,,HVA2,;DCP,():,0.7;DCP,1.5;HVA2,2.5;CZ,0.7,[24]HNBRDCP,DCP/,DCP/(TAIC)3,,DCP,HNBR,41.9%;DCP/,HNBR,DCP4.51,22.0%;DCP/TAIC,,TAICHNBR,TAIC1,28.9%3.5,,,,BIPB,BPMCDCP,,,[25]1,4,DCP,Naskar[26]PP/EPDMTPV,,,,2,461,3,5,/4,,,,,,,,,,:[1]ValentinJL,Fernandez-TorresA,PosadasP,etal.Measurementsoffreezing-pointdepressiontoevaluaterubbernetworkstructureCrosslinkingofnaturalrubberwithdicumylperoxide[J].JournalofPolymerScience,2007,45(5):544561.[2]GonzalezL,RodriguezA,etal.Effectofnetworkheteroge2neitiesonthephysicalpropertiesofnitrilerubberscuredwithdicumylperoxide[J].JournalofAppliedPolymerSci2ence,2007,103(5):33773382.[3]NaskarK.ThermoplasticelastomersbasedonPP/EPDMblendsbydynamicvulcanization[J].RubberChemistryandTechnology,2007,80(3):504519.[4],.EPDM[J].,2008,24(9):3940.[5],.[J].,2007,28(1):69.[6].[J].,2003,31(4):3638.84303[7],,,.CM[J].,2007,54(7):412414.[8],,.[J].,2004,51(7):440443.[9]AlvarezGrimaMM,ErikssonJG,TalmaAG,etal.Propertyimprovementinperoxidevulcanization[J].Kaut2schukGummiKunststoffe,2007,60(5):235240.[10]GrimaMM,Alvarez,TalmaAG,DattaRN,etal.Newconceptofco-agentsforscorchdelayandpropertyimprovementinperoxidevulcanization[J].RubberChem2istryandTechnology,2006,79(4):694711.[11],,,.N,N-EPDM[J].,2006,27(3):1316.[12]MurgicZH,JelencicJ,MurgicL.Mechanismoftriallyl2cyanurateasacoagentinEPDMperoxidevulcanization[J].PolymerEngineeringandScience,1998,38(4):689692.[13],,.[J].,2007,28(6):3033.[14],,,.[J].,2008,31(1):7071.[15],.1,2-PBRBREPDM[J].,2000,47(12):707710.[16]ZhangHongmei,DeRisiFR,NoordermeerJWM.Effectsof1,2-polybutadieneascrosslinkingagentinethylenepropylenedienemonomer/polypropylenether2moplasticvulcanizate[J].,2005,28(3):228.[17],.TMCH[J].,2006,33(11):810.[18],.(CM135B)[J].,2005,26(4):1922.[19]ThitithammawongA,NakasonC,SahakaroK.NR/PPthermoplasticvulcanizatesSelectionofoptimalperoxidetypeandconcentrationinrelationtomixingconditions[J].JournalofAppliedPolymerScience,2007,106(4):22042209.[20]GonzalezL,RodriguezA,Marcos-FernandezA,etal.Effectofnetworkheterogeneitiesonthephysicalproper2tiesofnitrilerubberscuredwithdicumylperoxide[J].JournalofAppliedPolymerScience,2007,103(5):33773382.[21],,,.EPDM/NR[J].,2006,53(2):8084.[22],,./NBR/ZDMA[J].,2005,52(1):2326.[23],,.S/DCP/HVA-2/CZNR/EPDM[J].,2006,27(5):2225.[24],.DCPHNBR[J].,2007,28(1):2426.[25],,,.[J].,2007,17(2):4649.[26]NaskarK,NoordermeerWM.DynamicallyvulcanizedPP/EPDMblends:Multifunctionalperoxidesascrosslinkingagents-PartI[J].RubberChemistryandTechnology,2004,77(5):955971.2010,,,2010,,2010(6);2010,50%,7840,!ht2tp;//:33620118E-mail:xinxi@fastrubber.com:12:712023::::2604020609024914847